The leadless tellurate low melting glass is used as binder phase for preparing electron paste. Said glass is mixed with functional powder to produce composite powder, which is then dispersed in organic solution to prepare thick paste, i.e. electron paste, used for making various kinds of electron devices. Said low melting glass, during sintering, melts-out and takes effect of adhering. The sintering temperature is between 350-600deg.C when making electron device. The components of the glass are (mass percentages): TeO2 10-90%,V2O5 0-40%,SiO2 0-5%,B2O3 0-5%,ZnO 0-10%,Bi2O3 0-20%,Sb2O3 0-8%,Al2O3 0-4%,SnO2 0-6%,Ag2O 0-10%,BaO 0-5%,MgO+CaO 0-5%.