A method and
system for treating a
dielectric film includes exposing at least one surface of the
dielectric film to an
alkyl silane, an alkoxysilane, an
alkyl siloxane, an alkoxysiloxane, an
aryl silane, an acyl
silane, a cyclo
siloxane, a polysilsesquioxane (PSS), an
aryl siloxane, an acyl siloxane, or a halo siloxane, or any combination thereof. The
dielectric film can include a low dielectric constant film with or without pores having an etch feature formed therein following dry etch
processing. As a result of the etch
processing or
ashing, exposed surfaces in the feature formed in the dielectric film can become damaged, or activated, leading to retention of contaminants, absorption of
moisture, increase in dielectric constant, etc. Damaged surfaces, such as these, are treated by performing at least one of healing these surfaces to, for example, restore the dielectric constant (i.e., decrease the dielectric constant) and cleaning these surfaces to remove contaminants,
moisture, or residue. Moreover, preparation for
barrier layer and metallization of features in the film may include treating by performing sealing of sidewall surfaces of the feature to close exposed pores and provide a surface for barrier film deposition.