125 results about "Phenylglycidyl ether" patented technology

An epoxide-based composition comprising a combination of an epoxide and a curing agent, wherein the epoxide is selected from a phenyl glycidyl ether-based polyepoxide and the curing agent is a salt compound composed of a N-alkanol piperidine and a carboxylic acid.

The invention discloses a corrosion-resistant high-adhesive-force water-based metal paint which is prepared from the following raw materials in parts by weight: 20-30 parts of polyorthotoluene glycidol ether, 15-20 parts of bisphenol F epoxy resin, 10-20 parts of polyphenyl glycidyl ether, 20-30 parts of silica sol, 1-3 parts of iron oxide red, 1-2 parts of titanium white, 12-16 parts of mica powder, 15-30 parts of modified wollastonite, 2-6 parts of quartz powder, 1-3 parts of silicon oxide, 1-2 parts of zinc oxide, 5-10 parts of ground calcium carbonate, 1-3 parts of aluminum tripolyphosphate, 5-10 parts of zinc phosphate, 0.2-0.8 part of antimicrobial agent, 1-2 parts of mildew preventive, 1.5-3 parts of leveling agent, 1-2 parts of defoaming agent, 1-2 parts of wetting agent, 1-3 parts of dispersing agent, 2-6 parts of ethylene glycol, 20-30 parts of water and 2-5 parts of film-forming assistant. The metal paint has the advantages of favorable corrosion resistance, high adhesive force and excellent mechanical properties.

The invention provides a double-component, heat and humidity resistance epoxy architecture reinforcement glue, comprising first and second components. The preparation method of the glue comprises: 1) adding reactive toughening agent thiocol, fluid epoxy resin, reactive diluent C12-14 tertiary carbonic acid ethylene oxidic ester, reactive diluent phenyl glycidyl ether and antifoaming agent by weight portion, silane coupler, discharged gas phase white carbon black and uniformly stirring, standing and defoaming to obtain first compnent: 2) uniformly stirring the isophorone diamine, metaxylene diamine, aromatic alcohol, salicylic acid and epoxy resin E44 to obtain second component curing agent by weight portion; mixing the promoter and curing agent in proportion to obtain second component. The architecture reinforcement glue without solvent can be cured at room temperature and conveniently constructed, with fine viscosity, good thixotropy, excellent resistance to heat and humidity, mechanical property and adhesive property, without toxin and pollution.

The invention provides water-based anticorrosive paint. The water-based anticorrosive paint comprises, by weight, 82-95 parts of phenyl glycidyl ether modified polyaniline, 60-80 parts of epoxy resin, 30-60 parts of alkyd resin, 20-40 parts of modified polyurethane, 10-15 parts of modified nanometer titania, 5-12 parts of zinc phosphate, 6-18 parts of aluminum phosphate, 5-12 parts of imvite, 3-8 parts of mica powder, 2-9 parts of talcum powder, 4-14 parts of quartz powder, 8-18 parts of pigment, 2-8 parts of defoaming agents, 3-6 parts of dispersing agent, 1-5 parts of flatting agents, 4-9 parts of coalescing agents and 60-83 parts of water. The water-based anticorrosive paint is good in antiseptic property, excellent in waterproofness, long in service life and low in cost.

An epoxide-based composition comprising a combination of an epoxide and a curing agent, wherein the epoxide is selected from a phenyl glycidyl ether-based polyepoxide and the curing agent is a salt compound composed of a N-alkanol piperidine and a carboxylic acid.

The invention relates to the technical field of curing agents, particularly an epoxy resin curing agent. The epoxy resin curing agent comprises the following components in percentage by weight: 40-50% of acid anhydride, 40-50% of boron trifluoride, 5-10% of toughener and 5-10% of diluter. The components above are adopted in combination with any one toughener of carboxyl liquid nitrile-butadiene rubber, carboxyl-terminated liquid nitrile-butadiene rubber, polysulfide rubber, liquid silicone rubber and the like, or any one diluter of polypropylene glycol diglycidyl ether, phenyl glycidyl ether and ethylene glycol diglycidyl ether to further improve the toughness of the epoxy resin curing agent and enhance the bearing strength and temperature tolerance. Therefore, the prepared epoxy resin curing agent has the advantages of high reaction speed, low toxicity, high pressure resistance, corrosion resistance, small shrinkage deformation and the like, and can be widely used in the industries of electrical potting and packaging, electrical casting, electric apparatus impregnation, insulating composite material winding, pulling and extrusion, and the like.

Disclosed herein are a power module package and a method of manufacturing the same. According to a preferred embodiment of the present invention, the power module package includes: a lead frame on which a power device and a control IC electrically connected to the power device and controlling the power device are mounted; and a thermal sheet bonded to one surface of the lead frame, wherein the thermal sheet includes first and second resin layers which include a thermal conductive inorganic filler and are added with a mixture of phenyl glycidyl ether (PGE) and alkyl glycidyl ether (Alkyl (C12 to C14) glycidyl ether), and a thermal spreader of a metal material disposed at a bonded interface which is formed between the first and second resin layers. Therefore, it is possible to easily improve a thermal property of the power module package by a thermal spreading effect due to the thermal spreader.

The invention relates to a transparent, high-hardness and yellowing-resistant epoxy ornament glue and a preparation process thereof and provides a novel formula comprising an epoxy resin component labeled as a glue A and a curing agent component labeled as a glue B, wherein the glue A is prepared from epoxy resin 127, phemethylol, polymethyl methacrylate and nanometer titanium dioxide, the glue B is prepared by synthesizing diethylenetriamine, n-butyl glycidyl ether, phenyl glycidyl ether, 1,3-cyclohexanedimethanol methylamine and phemethylol as raw materials at a certain temperature to obtain the curing agent used in the epoxy ornament glue. The preparation process comprises the following steps of uniformly mixing the glue A and the glue B at a certain ratio; carrying out vacuum defoaming; and carrying out heating cure by using silica gel as a mold, namely, firstly curing at low temperature, and after a certain curing degree is reached, carrying out heating curing. The obtained cured product has colorless and transparent appearance, flat and smooth surface, Shore hardness which can reach 84 or more, excellent yellowing resistance and long operating time. The method has the advantages of easily available raw materials, simple process and low cost, and is easy to industrialize, and the epoxy ornament glue can replace the commercially available general formula of the epoxy ornament glue.

The invention discloses high-hardness ultraviolet-cured wood paint. Raw materials of the high-hardness ultraviolet-cured wood paint comprise, in parts by weight, 20-35 parts of epoxy acrylate, 15-28 parts of urethane acrylate, 15-26 parts of phenyl glycidyl ether acrylate, 3-9 parts of reactive diluent, 0.5-1.2 parts of photoinitiator, 3-15 parts of epoxy resin, 3-8.5 parts of alicyclic amine, 3-10 parts of epoxy curing agent, 3-8 parts of modified graphene oxide, 1-2 parts of nano-silica, 0.5-1.6 parts of montmorillonoid, 0.3-2 parts of pyrene-1-butyric acid, 1-3 parts of silane coupling agent KH-580, 2-5 parts of 3,9-diethyl-3,9-dihydroxytoluene-1,5,7,11-tetraoxaspiro-5,5-undecane and 0.1-1 part of assistant. The high-hardness ultraviolet-cured wood paint has high adhesion to a wood basematerial, good hardness and water resistance and excellent heat-resistant performance.

An epoxide based composition that can be cured at a temperature of less than about 70 C is disclosed. The composition is a liquid at ambient conditions and, therefore, can be used to rehabilitate the interior surfaces of pipelines. The epoxide-based composition comprises at least one epoxide component (component A) and at least one curing agent component (component B) wherein(A) the epoxide component comprises a phenyl glycidyl ether polyepoxide; and(B) the curing agent component comprises a mixture of two salt compounds formed, respectively, from an N-alkanol piperidine and a carboxylic acid bearing 7-12 carbon atoms, and N-cyclohexyl-N,N-dialkyl amine and a carboxylic acid bearing 7-12 carbon atoms.

The invention relates to a synthesis method of phenyl glycidyl ether, and is characterized in that phenyl glycidyl ether is generated with phenol and chloropropylene oxide as raw materials and under the action of a catalyst, wherein the reaction is carried out in a micro-reactor. The method can greatly shorten the reaction time, avoids a lot of side reactions, and can synthesize phenyl glycidyl ether with high efficiency and high yield of more than 98%.

The invention discloses a yellowing resistant and waterborne epoxy hardener and a preparation technology thereof, relates to the technical field of a hardener, and solves the problem of poorer integral application effect as a curing film generated by the waterborne epoxy hardener after use easily yellows. The yellowing resistant and waterborne epoxy hardener includes the following components in parts by weight: 40-50 parts of triethylene tetramine, 30-40 parts of polyorganic acid, 5-10 parts of polyether amine, 5-10 parts of BPA epoxy resin, 6-10 parts of polyamide, 5-9 parts of a modifying agent, 4-8 parts of an accelerator, 6-10 parts of a diluent, 4-7 parts of phenyl glycidyl ether and 6-8 parts of glycol diglycidyl ether. The yellowing resistant and waterborne epoxy hardener provided by the invention has integral good application effect as the curing film generated after use of the hardener is not easy to yellow.

The present invention relates to a compound which is a phenyl glycidyl ether adduct of maltodextrin and its method of preparation. The compound of the present invention is useful as an open time additive in paint formulations.

The present invention discloses a hydrolysis resistance polybutylene terephthalate, which comprises, by mass, 70-90% of PBT, 5-15% of glass fibers, 3-8% of MBS, 0.5-2% of a hydrolysis resistance agent, 0.1-1% of pyromellitic dianhydride, 0.5-1% of modified ethylene bis fatty acid amide, and 0.1-0.5% of an antioxidant, wherein the hydrolysis resistance agent is one selected from phenyl glycidyl ether, bisphenol A diglycidyl ether, carbodiimide, and 2-oxazoline. The hydrolysis resistance polybutylene terephthalate of the present invention has the beneficial effects that: with the glass fiber reinforcing and the proper addition of the MBS, the hydrolysis resistance agent, the pyromellitic dianhydride and other auxiliary agents, the mechanical strength, the impact toughness and the hydrolysis resistance of the polybutylene terephthalate are substantially improved, the material performance is well improved, and the application range is expanded.

The invention discloses a remoldable bismaleimide resin and an application thereof. The remoldable bismaleimide resin is prepared by the following steps: blending 2-allylphenyl glycidyl ether with terephthalic acid in acetonitrile, carrying out an esterification reaction with a quaternary ammonium salt as a catalyst to obtain a bis(3-(2-allylphenoxy)-2-hydroxypropyl)terephthalate containing a reversible dynamic group; and uniformly mixing the bis(3-(2-allylphenoxy)-2-hydroxypropyl)terephthalate with bismaleimide, and curing the obtained mixture to obtain the remoldable bismaleimide resin. Theremoldable bismaleimide resin prepared in the present invention has excellent heat resistance and excellent mechanical properties, and can be remolded under a hot pressing condition. The preparation method of the remoldable bismaleimide resin has the characteristics of wide sources of raw materials, and simple process, and the has remoldable bismaleimide resin broad application prospects in industrial fields of aerospace, transportation, electronic information, new energy and insulated electrics.

The invention provides a preparation method of a multifunctional mesoporous silicone solid-phase extraction agent. The preparation method of the multifunctional mesoporous silicone solid-phase extraction agent is characterized in that firstly, SBA-15 mesoporous silicone serves as a base material, 3-(2-aminoethylamino)propyl-trimethoxysilane or 3-[2-(2-aminoethylamino)ethylamino]propyl-trimethoxysilane which contains more than 2 amino groups serves a silylation reagent, multi-amino mesoporous silicone is obtained, then, ring-opening reaction of amino groups and epoxy groups is adopted, the multi-amino mesoporous silicone further reacts with excess phenyl glycidyl ether, and the mesoporous silicone extraction agent has high-density surface multifunctional groups is obtained. The mesoporous silicone extraction agent has high specific surface area of a mesoporous material, the high-density surface multifunctional groups and supramaximal extraction capacity and also has a reversed-phase adsorption effect of multiple phenyl groups and a powerful anion exchange function of quaternary ammonium groups, and therefore the mesoporous silicone extraction agent is a high-selectivity mixed-mode solid-phase extraction agent. The mesoporous silicone extraction agent is quite suitable for analyzing acid non-steroidal anti-inflammatory drugs in large-volume environmental water samples.

The invention discloses water-based insulating paint which comprises water-based epoxy resin, a polyol-modified waterborne epoxy curing agent and auxiliaries, wherein polyols comprise neopentyl glycol and 1,3,5-tris(2-hydroxyethyl)cyanuric acid; the weight ratio of the water-based epoxy resin to the polyol-modified waterborne epoxy curing agent is (2.5-3):1. The invention further discloses a preparation method for the water-based insulating paint. The preparation method comprises the following steps: enabling epoxy resin to react with polyols so as to obtain a prepolymer with epoxy-terminated functional groups; mixing polyamine with the prepolymer; dropwise adding epoxy resin, reacting completely, dropwise adding phenyl glycidyl ether and reacting to a final point; cooling, adding water and emulsifying so as to obtain the waterborne epoxy curing agent; weighing and uniformly mixing the waterborne epoxy curing agent, water-based epoxy resin, a defoaming agent, a levelling agent and a dispersing agent, baking and cooling. The water-based insulating paint is not added with a cosolvent, and free of VOCs and potential safety hazards, conforms to environmental protection requirements, and is high in electric strength and heat resistance.

The invention discloses a high-flame-retardance epoxy resin adhesive, which comprises the following raw materials: fluorene structure-containing epoxy resin, polytetrahydrofuran, dio-diphthalene, PMDETA, curing accelerator, 1,4-butanediol, nano-silica, nano calcium carbonate, magnesium oxide, expansible graphite, Phosphorous nitrogen flame retardant, boric acid, diammonium hydrogen phosphate, amino silicon oil, PEEK, carbon fiber, chlorite, aluminum silicate, carboxymethylcellulose, a solvent and coupling reagent. The high-flame-retardance epoxy resin adhesive is excellent in flame retardance performance, good in heat insulating property and high in adhesion strength.

The invention discloses a low-temperature water-based corrosion-resistant metal coating which comprises the following components in parts by weight: 10-15 parts of polyo-toluene glycidyl ether, 15-20 parts of bisphenol F epoxy resin, 10-20 parts of polyphenyl glycidyl ether, 20-30 parts of silica sol, 3-10 parts of a coloring pigment, 1-5 parts of a curing agent, 30-60 parts of water, 6-10 parts of dibutyl ester, 8-10 parts of salicylic acid, 1-6 parts of propiconazole, 0.6-1.6 parts of chromium oxide green, 15-20 parts of benzoic acid and 30-60 parts of a styrene-acrylic emulsion. The coating disclosed by the invention is good in film-forming property and high in film strength, and selects a natural and pollution-free corrosion-resistant agent from a water-based epoxy resin coating; the natural corrosion-resistant agent is bonded with a special emulsion for the water-based corrosion-resistant coating, so that the corrosion resistance is good and superior to that of a traditional water-based coating.

The invention discloses a preparation method for a modified water-borne epoxy resin curing agent and belongs to the technical field of a curing agent. The method comprises the following steps: firstly, using a sodium hydroxide solution for activating a regenerated cellulose fiber; grinding and then bonding with triethylene tetramine and performing addition reaction with ethylene glycol diglycidyl ether; adopting epoxy resin for performing chain extension; lastly, using phenyl glycidyl ether for blocking the terminal, thereby acquiring the modified water-borne epoxy resin curing agent. The modified water-borne epoxy resin curing agent acquired according to the invention has excellent mechanical properties and durability, is non-toxic and harmless, is free from volatile organic solvent, is pollution-free to ecological environment, is free from organic acid, is impossible to corrode metal parts, is high in alkali resistance, is free from instable phenomenon under the condition of use together with alkaline filler and is non-irritant to the skin of the user.

The invention relates to a halohydrin dehalogenase mutant for improving enantioselectivity and application thereof, and belongs to the technical field of enzyme engineering and biocatalysis. The halohydrin dehalogenase mutant is obtained by carrying out single-point mutation or combined mutation on 89th arginine, 137th valine, 178th proline, 179th asparagine and 187th phenylalanine in a sequence as shown in SEQ ID NO.1. Compared with wild type halohydrin dehalogenase, the mutant obtained by the invention obviously improves enantioselectivity (E value) during the preparation of (S)-o-nitrophenyl glycidyl ether, (R)-benzyl glycidyl ether and (R)-phenyl glycidyl ether, the maximum improvement is 44.6, 2.9 and 9.4 times of the original enzyme respectively, and has good industrial application prospect.

The invention relates to a synthetic method of phenyl glycidyl ether. The method comprises the following steps: carrying out ring-opening reaction; carrying out ring-closure reaction; washing; refining; and recovering excessive epoxy chloropropane in vacuum from a phenyl glycidyl ether coarse to obtain a phenyl glycidyl ether finished product, wherein the recovered epoxy chloropropane is directly reused in next batch. The method comprises the following steps: by taking phenol and epoxy chloropropane as raw materials, firstly, carrying out ring-opening reaction under the action of a ternary compound catalyst comprising N,N-dimethylethanolamine, tetrabutylammonium hydrogen sulfate and quaternary ammonium salt-7 to prepare an intermediate phenyl chlorhydrin; and then carrying out ring-closure reaction with a sodium hydroxide solution to prepare the phenyl glycidyl ether, wherein the recovered epoxy chloropropane can be directly reused. The method provided by the invention has the advantages of simple process, short production cycle, high final product yield, high epoxide number, small color number and the like and is easily industrialized.

The present invention discloses an oil tank inner wall oil-resistant epoxy paint and a preparation method thereof, and the paint is prepared from the following raw materials by weight: E-20 epoxy resin, maleic anhydride, butyl alcohol, diatomite, nano bentonite, phenyl glycidyl ether, pigments and additives including a dispersing agent, an anti rust agent, a flame retardant agent, an initiator, a defoaming agent, an antioxidant and a solvent. The oil tank inner wall oil-resistant epoxy paint not only improves the compactness of a paint film, enhances the anti oil permeability performance of the paint film, also has the advantages of very strong acid and alkali resistance, corrosion resistance, rust resistance, flame resistance, strong adhesion, high hardness, scratch resistance, quick drying, simple preparation process, low cost and the like, is especially suitable for anticorrosion coating of oil tank inner wall of mechanical and electrical equipment and power plant equipment, and is very obvious in effect.

The invention discloses a water-borne epoxy resin curing agent. The water-borne epoxy resin curing agent is prepared from, by mass, 43-48 parts of polyethylene polyamine, 40-45 parts of bisphenol A epoxy resin, 2.5 parts of glycol ether, 1 part of butyl glycidyl ether, 1 part of phenyl glycidyl ether, 1 part of benzyl glycidyl ether, 1 part of alkyl glycidyl ether and 0.5 part of acetic acid. The water-borne epoxy resin curing agent is prepared through the steps of a, addition, b, end sealing, c, salifying, and d, dissolution. In this way, the water-borne epoxy resin curing agent has good water solubility and curing performance, and the VOC content meets the environment protection requirement.

The present invention discloses a motor slot wedge high-performance epoxy resin insulating material preparation method, which comprises: uniformly mixing naphthenic acid, zinc oxide, phenyl glycidyl ether and pyromellitic dianhydride, carrying out a reaction at a temperature of 120-135 DEG C, adding 2,4,6-tris(dimethylaminomethyl)phenol to obtain a component A, mixing nanometer silicon nitride, nanometer titanium dioxide, polypropylene staple fibers, nanometer mica, nanometer aluminum hydroxide, nanometer zinc oxide, a coupling agent, a bisphenol A epoxy resin, a o-methyl phenolic epoxy resin, chlorinated polyethylene, a bisphenol A type polycarbonate, polytetrafluoroethylene, epoxy-terminated polydimethylsiloxane, phenyl glycidyl ether, ethylene glycol diglycidyl ether, polysulfide rubber, tricyclodecane dimethanol diacrylate and diphenylsilanediol to obtain a material A, uniformly mixing methyl tetrahydrophthalic anhydride, N-phenyl-2-naphthylamine, 1,4-phenylene diamine and the component A to obtain a material B, and curing the material A and the material B.

The invention relates to a synthesis method of a 1-arylacetylene seleno-3-phenoxy-2-propanol compound. The method comprises the following steps of: under air conditions, reacting acetylenic acid, selenium powder and phenyl glycidyl ether as the reaction raw materials with water used as a reaction solvent under the joint promotion actions of a copper catalyst, a ligand, a phase transfer catalyst and alkali, and carrying out a cascade reaction to obtain the 1-arylacetylene seleno-3-phenoxy-2-propanol compound. The method has the advantages of mild and simple reaction conditions, cheap and easilyavailable substrate, and high yield and purity of the product, opens up a new synthetic route and method for the 1-arylacetylene seleno-3-phenoxy-2-propanol compound, and has good application potential and research value.

The invention discloses a method for preparing an insulating material for wires and cables. The method comprises the following steps: performing ball milling and granulating on high abrasion furnace carbon black, zinc borate and silicon carbide, and smelting with an epoxy resin together; adding tetrahydrofuran for stirring in vacuum, adding polyamide wax micro powder and a vacuum reactant obtained by performing dehydration, heating and vacuum reaction on ethylene propylene rubber, polyetherimide and phenyl glycidyl ether, performing a series of specific processes such as plastifying, feeding, ultrasonic treatment, reduction vaporization, screw extrusion, high pressure reaction, secondary plastifying, compression molding, dicing and the like, thereby obtaining the finished product. The prepared insulating material is abrasion-resistant, ageing-resistant and excellent in insulating effect and has excellent application prospects. Meanwhile, the invention further discloses application of the insulating material prepared by the preparation process in the power industry.

The invention provides a preparation method of a water-based orange peel epoxy curing agent. The water-based orange peel epoxy curing agent is prepared from the following raw materials in parts by mass: 10-20 parts of vinylamine, 2-6 parts of neopentyl glycol diglycidyl ether, 25-40 alicyclic amine, 15-25 parts of epoxy resin, 15-25 parts of propylene glycol monomethyl ether, 8-10 parts of phenylglycidyl ether, 2-6 parts of fumed silica and 20-50 parts of deionized water. The invention further provides an epoxy resin flat coating agent which is matched with the epoxy curing agent for use according to the mass ratio of 1: 5 and is prepared from the following raw materials in parts by mass: 300-400 parts of epoxy resin, 25-32 parts of an active diluent, 1-5 parts of a dispersing agent, 1-3parts of an antifoaming agent, 305-320 parts of ground calcium carbonate, 160-200 parts of silica powder, 15-20 parts of wax powder, 80-120 parts of talcum powder, 1-5 parts of leveling agent and 2-8parts of color paste. The water-based orange peel epoxy curing agent prepared by the invention is clear and transparent in appearance, uniform in coating orange peel texture, high in hardness, good inadhesive force, high in acid resistance, alcohol resistance and water resistance, strong in flexibility, high in impact resistance and excellent in comprehensive performance.

The present invention disclosed novel epoxy novolac composite comprising environmentally friendly toughening agents based on bio-derived chemicals namely, Difunctional glycidyl ether epoxy resin (Cardolite NC-514) and Polyglycidyl ether of an alkenyl phenol formaldehyde novolac resin (Cardolite NC-547) used for the toughening of epoxy novolac resin namely Poly[(phenyl glycidyl ether)-co-formaldehyde] [PPGEF].