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Synthesis technique of dual-component wet and heat ageing resistant epoxy building structure strengthening adhesive

A technology for building structure and heat and humidity resistance, applied in the field of structural reinforcement adhesive, can solve the problems of low initial bonding strength, poor heat and humidity aging resistance, unfavorable reinforcement, etc., and achieve excellent heat and humidity aging resistance, wide applicable temperature range, waterproof good gas performance

Inactive Publication Date: 2008-09-03
上海华夏化工材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Imported structural reinforcement glue has a slow curing and cross-linking reaction, and the construction period is too long; low temperature does not cure, and additional insulation and heating measures must be taken when the weather becomes cold during the construction process; the initial bonding strength is low, which affects the bonding effect and on-site construction operations, and The price is expensive, and the cost of building reinforcement is high, which is unbearable for users
[0004] The domestic structural reinforcement adhesive has poor moisture and heat aging resistance, high brittleness, poor toughness, and its mechanical properties cannot meet the latest national A-level standard for building structural adhesives, and cannot meet the construction requirements of national key projects; the application period cannot be adjusted during use, and the summer The structural adhesive will gel in a short period of time, which is not conducive to large-scale reinforcement; when the temperature is lower than 10°C, the construction period will be too long, and it will not even gel below 0°C, which will affect the construction
[0005] Moreover, most of the structural reinforcement adhesives contain solvents that pollute the environment and curing agents that are harmful to the human body, which is not conducive to environmental protection and the health of construction workers.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] (1), the preparation of component A:

[0030] a. Add active toughening agent polysulfide rubber JLY-1211 parts and liquid epoxy resin E51100 parts by weight to the stirrer, and stir for 3 to 5 minutes at room temperature at 700 rpm.

[0031] b. Then add reactive diluent E-108 parts, PGE 6 parts and defoamer Defom 68000.3 parts in order by weight, and stir at room temperature at 700 rpm for 3 to 5 minutes until they are evenly mixed.

[0032] c. Add 1 part of silane coupling agent KH5601 parts by weight to the liquid described in step (1) b, and stir evenly at room temperature;

[0033] d. Add 1 part of hydrophobic fumed white carbon black in parts by weight to the liquid described in step (1) c, stir evenly until no visible powder, then stir at 1400-2000 rpm for 15 minutes at high speed, and let it stand for defoaming. A component;

[0034] (2), preparation of component B

[0035] a. In the reaction vessel, 90 parts by weight of IPDA and 10 parts of MXDA were mixed u...

Embodiment 2

[0041] In the first component of embodiment one, the liquid epoxy resin E-51 is changed into 12880 parts, the hydrophobic fumed silica is changed into 2 parts, the reactive diluent E-10 is changed into 6 parts, and the reactive diluent PGE is changed into 8 parts, The active toughening agent polysulfide rubber JLY-121 is changed to 0.6 parts, the silane coupling agent KH560 is changed to 1.5 parts; the materials and parts by weight in component B are changed to: 75 parts of IPDA, 25 parts of MXDA, 70 parts of phenylethyl alcohol, salicylic acid 10 parts of acid, 5 parts of epoxy resin E-4425.

[0042] The weight ratio of curing agent and accelerator DMP-30 in component B is 45:2.

[0043] All the other and preparation method are with embodiment one

Embodiment 3

[0045] In the component A of Example 1: liquid epoxy resin 128 is changed to 120 parts, defoamer Defom 6800 is changed to 0.8 parts, reactive diluent is changed to E10 7 parts, PGE 7 parts, active toughening agent polysulfide rubber JLY -121 is changed to 1.5 parts, the silane coupling agent KH560 is changed to 2 parts; the materials and parts by weight in component B are changed to: 95 parts of IPDA, 5 parts of MXDA, 85 parts of benzyl alcohol, 12 parts of salicylic acid, epoxy resin E-4425 copies. The ratio of accelerator DMP-30 and curing agent in component B is 3:80.

[0046] The rest and the preparation method are the same as in Example 1.

[0047] Performance test data of embodiment one, two, three and domestic and foreign similar products

[0048] actual project

actual conditions

foreign products

domestic product

Embodiment one

Embodiment two

Embodiment three

Tensile Strength

(MPA)

7 days at room temperature

...

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PUM

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Abstract

The invention provides a double-component, heat and humidity resistance epoxy architecture reinforcement glue, comprising first and second components. The preparation method of the glue comprises: 1) adding reactive toughening agent thiocol, fluid epoxy resin, reactive diluent C12-14 tertiary carbonic acid ethylene oxidic ester, reactive diluent phenyl glycidyl ether and antifoaming agent by weight portion, silane coupler, discharged gas phase white carbon black and uniformly stirring, standing and defoaming to obtain first compnent: 2) uniformly stirring the isophorone diamine, metaxylene diamine, aromatic alcohol, salicylic acid and epoxy resin E44 to obtain second component curing agent by weight portion; mixing the promoter and curing agent in proportion to obtain second component. The architecture reinforcement glue without solvent can be cured at room temperature and conveniently constructed, with fine viscosity, good thixotropy, excellent resistance to heat and humidity, mechanical property and adhesive property, without toxin and pollution.

Description

technical field [0001] The invention relates to a structural reinforcement adhesive used in the construction industry, in particular to an epoxy structural reinforcement adhesive resistant to humidity and heat aging. Background technique [0002] The national standard "Code for Design of Concrete Structure Reinforcement" (GB50367-2006) stipulates that the adhesive used for the reinforcement of reinforced concrete load-bearing structures, the shear performance of steel-steel bonding must pass the damp heat aging test, and meet the requirements of environmental protection construction colloid performance and other aspects , but the existing building structure reinforcement glue has the following deficiencies in the use process and its own performance: [0003] Imported structural reinforcement glue has a slow curing and cross-linking reaction, and the construction period is too long; low temperature does not cure, and additional insulation and heating measures must be taken wh...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/00C09J181/04
Inventor 李岿然周平张蕙兰李新军
Owner 上海华夏化工材料有限公司
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