The invention provides a combustion improver for a boiler. The combustion improver is prepared from the following raw materials in parts by weight: 4 parts of sulfuric acid, 4 parts of hydrochloric acid, 4 parts of iron oxide, 4 parts of zinc oxide, 4 parts of copper oxide, 4 parts of calcium oxide, 4 parts of magnesium oxide, 4 parts of aluminum oxide, 16 parts of selenium dioxide, 16 parts of strontium oxide, 16 parts of difluorine monoxide, 16 parts of No. 97 gasoline, 16 parts of No. -20 diesel oil, 16 parts of ethanol, 16 parts of kerosene, 10 parts of paraffin, 10 parts of n-octane, 10 parts of nonane, 10 parts of decane, 10 parts of undecane, 10 parts of dodecane, 10 parts of eicosane, 10 parts of triacontane and 10 parts of tetracontane. The combustion improver provided by the invention can reduce pollution, improve combustion efficiency and prolong the service life of the boiler. The invention further provides a preparation method and application of the combustion improver.