129 results about "Bromoacetic acid" patented technology

The invention discloses a modified alkali lignin chelated zinc fertilizer and a preparation method thereof. The preparation method comprises the following steps: adding alkali lignin powder into water, regulating the pH value, and dissolving to obtain a 30-40 wt% water solution; adding amino acid, dropwisely adding epoxy chloropropane, heating to 75-95 DEG C, and reacting for 2-3 hours; regulating the pH value to 10-12, dropwisely adding bromoacetic acid, and reacting at 70-90 DEG C for 1-2 hours; and finally, regulating the pH value of the system to 5-7 with a dilute hydrochloric acid solution, adding zinc sulfate, and carrying out chelation reaction at 50-70 DEG C for 0.5-2 hours, thereby obtaining the modified alkali lignin chelated zinc fertilizer after the reaction finishes. The chelated microelement fertilizer molecules have abundant hydroxy and carboxyl groups, and the N atom has lone electron pairs which can form composite coordination with metallic ions; and thus, the fertilizer has high chelation capacity, and the maximum complexation quantity for zinc ions is approximate to the level of EDTA (ethylene diamine tetraacetic acid); and the pot incubation test indicates that the fertilizer has an obvious yield increase action on crops.

The present invention discloses a method for preparing 5-bromo-2-hydroxy-3-nitrophenylethanone. The method comprises that: (1) in the presence of an alkali, tetrachloroethylene is adopted as a reaction solvent, bromophenol completesly reacts with an acetylation reagent to obtain a tetrachloroethylene solution of bromoacetic acid phenolester; (2) Lewis acid is added to the resulting solution from the step (1) to completely carry out a Fries rearrangement reaction to obtain a tetrachloroethylene solution of 5-bromo-2-hydroxy acetophenone; (3) a nitration reagent is added to the resulting solution from the step (2) in a dropwise manner to completely carry out the reaction to obtain the 5-bromo-2-hydroxy-3-nitroacetophenone. According to the preparation method provided by the present invention, the three-step reaction is adopted, the tetrachloroethylenes having the same batch are adopted for purifying the final product, such that the solvent consuming is reduced, the cost is reduced, the post-processing time is shortened and the operation steps are simplified; the toxicity of the tetrachloroethylene is far less than the toxicities of chloroform and carbon tetrachloride, such that the hazards on the human body and the environment are less; the tetrachloroethylene is easy to reclaim; the industrialization is easy to realize.

The invention discloses a method used for preparing a ZnO / SiO2 nano composite material. The method comprises following steps: (1) produced zinc bromoacetic acid is dissolved in a mixed solution of water and ethanol so as to obtain a zinc bromoacetic acid solution, a mixed solution of TEOS which is taken as a silicon source and APTES which is used for providing amino group is dissolved in absolute ethyl alcohol, an obtained mixture is added into the zinc bromoacetic acid solution dropwise, and reaction is carried out for 4 to 6h; (2) an obtained product is subjected to centrifugation, is washed with ethanol for 2 to 3 times, and is subjected to drying in a vacuum oven so as to obtain a white powder; and (3) the white powder is delivered into a muffle furnace for roasting so as to obtain the ZnO / SiO2 nano composite material. According to the method, amino group in APTES is taken as a catalyst, silicon dioxide is obtained via catalysis of the silicon source, silicon dioxide particles are generated in roasting at last, no extra catalyst is needed in the reaction process, and the method is harmless for the environment, and is a green synthetic method.

The invention relates and belongs to the field of pesticide chemistry, and in particular relates to a method for synthesizing L-glufosinate-ammonium intermediate (S)-3-amino-gamma-butyrolactone hydrochloride, and application of the method. The method takes L-methionine, concentrated hydrochloric acid and chloroacetic acid or bromoacetic acid as raw materials, and the L-glufosinate-ammonium intermediate (S)-3-amino-gamma-butyrolactone hydrochloride is obtained by a one-pot reaction. The method is simple in operation process and purification process, and high in yield; after the method is adopted, the production cost of L-glufosinate-ammonium is remarkably lowered.