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53 results about "Titanium(III) oxide" patented technology

Titanium(III) oxide (Ti₂O₃) is a chemical compound of titanium and oxygen. It is prepared by reacting titanium dioxide with titanium metal at 1600 °C. Ti₂O₃ has the Al₂O₃, corundum structure. It is reactive with oxidising acids. At around 200 °C there is a transition from semiconducting to metallic conducting. Natural titanium(III) oxide is known as the extremely rare mineral tistarite.

Promoter for generation of gas hydrate, and preparation method and application thereof

The invention discloses a promoter for generation of gas hydrates, and a preparation method and application thereof. The promoter for generation of gas hydrates is a dry powdery solution formed after high speed shearing and dispersion of a surfactant solution and strong hydrophobic solid particles in a high intensity stirrer, wherein the surfactant solution is an aqueous solution of one or more anionic surfactants, cationic surfactants or nonionic surfactants, and the strong hydrophobic solid particles are one or more selected from the hydrophobically modified particles consisting of silica, titanium dioxide, titanium sesquioxide, alumina, zinc oxide, calcium carbonate, montmorillonite, diatomite, fly ash, zeolite, talcum and mica particles, etc. The promoter provided by the invention is highly dispersed solution microdroplets and has a great gas-liquid contact area, the dispersed microdroplets contain surfactants, which enables gas-liquid contact during growth process of hydrates to be further reinforced, and therefore, a generation rate of gas hydrates and gas storage amount in a static system are substantially improved; meanwhile, the promoter has the advantages of low cost, no pollution and convenient preparation and usage.
Owner:SOUTH CHINA UNIV OF TECH

Chromic oxide-titanium oxide based high-temperature and high-emissivity coating and preparation method thereof

InactiveCN105861972AGood sphericityMeet the requirements of plasma sprayingMolten spray coatingThermal sprayingStructural phase
The invention discloses a preparation method of a chromic oxide-titanium oxide based high-temperature and high-emissivity coating and belongs to the technical field of thermal spraying. According to the preparation method, compound powder which is subjected to doping modification with rare earth oxide and contains multiple uniformly distributed oxides is prepared through agglomerating granulation; the compound powder is put in a muffle furnace and subjected to high-temperature sintering densification, dense organic-solvent-free powder with a spinel structural phase is obtained, and the advantageous feature of oxygen cavity defect filling of the rare earth oxide is played. The chromic oxide-titanium oxide based high-temperature and high-emissivity coating is prepared through plasma spraying, the generation of the spinel structural phase in the powder is promoted, and the stability of the coating keeping higher emissivity at the high temperature is improved. The compound powder has better degree of sphericity, the flowing property is 30-60 s/50 g, and the apparent density is 1.0-3.0 g/cm<3>; the bonding strength of the prepared chromic oxide-titanium oxide based high-temperature and high-emissivity coating is higher than or equal to 20 MPa, and the emissivity at the temperature of 400-600 DEG C is higher than or equal to 0.88.
Owner:AEROSPACE RES INST OF MATERIAL & PROCESSING TECH +1

Method for producing inorganic film central layer

InactiveCN101371972ASmall apertureThe pore size is as small as 50-2nmSemi-permeable membranesMetallic materialsComposite oxide
The present invention discloses a method for preparing for inorganic membrane interface layer and belongs to the technical field of chemical engineering. The present invention is characterized by developing a heat coating method, carrying out two separated traditional processes of coating and drying instantly and synchronously and overcoming the disadvantages that the traditional coating method for manufacturing membrane is chapped easily, has disadvantage and has thick membrane layer; the present invention prepares the inorganic membrane interface layer that the aperture can be adjusted within the range between 50 and 2nm and mainly relates to the preparation of sol gel, a new method for coating the sol gel and the adjustment and control of the aperture of the interface layer. The method has very strong popularity and is used for preparing the adaptive interface layer which synthesizes chemical atmosphere such as alkalescence or acidity towards a separation layer by selecting suitable ceramic material, and the method can meet the requirement of the preparation of the separation layer by adjusting and controlling the aperture. The present invention can be used for preparing the interface layer of the materials such as disilicon trioxide, dizirconium trioxide, dititanium trioxide, the composite oxide thereof, and the like, by dense or porous ceramic, quartz, glass, silicon chip or metal material substrate.
Owner:DALIAN UNIV OF TECH

Titanium oxide and alumina alkali metal compositions

The invention relates to Group 1 metal / porous metal oxide compositions comprising porous metal oxide selected from porous titanium oxide and porous alumina and an alkali metal or an alkali metal alloy. The compositions of the inventions are described as Stage 0 and I materials. These materials differ in their preparation and chemical reactivity. Each successive stage may be prepared directly using the methods described below or from an earlier stage material. Stage 0 materials may, for example, be prepared using liquid alloys of Na and K which are rapidly absorbed by porous metal oxide under isothermal conditions, preferably at or just above room temperature, to form loose black powders that retain much of the reducing ability of the parent metals. When the low melting Group 1 metals are absorbed into the porous metal oxide at about 150° C., an exothermic reaction produces Stage I material, loose black powders that are stable in dry air. Further heating forms higher stage materials of unknown composition. It is believed that Stage I higher materials represent reductions of the porous metal oxide after absorption of the Group 1 metal. Preferred Group 1 metal / porous metal oxide compositions of the invention are those containing sodium, potassium, or sodium-potassium alloys with sodium and sodium-potassium alloys being most preferred. Each stage of the Group 1 metal / porous metal oxide composition of the invention may be used as a reducing agent reacting with a number of reducible organic materials in the same manner known for alkali metals and their alloys.
Owner:BOARD OF TRUSTEES OPERATING MICHIGAN STATE UNIV +1

Titanium oxide/tungsten oxide nano-composite film on surface of metallic titanium, preparation and application

The invention relates to a titanium oxide / tungsten oxide nano-composite film on the surface of metallic titanium, preparation and an application. The metallic titanium is cleaned and etched, then the metallic titanium is impregnated in an oxidation liquid containing peroxotungstic acid sol and hydrogen peroxide and is kept for a period of time at a certain temperature, a titanic acid and peroxotungstic acid containing nano-film formed through crystal in-situ growth and deposition is obtained, and finally, the titanium oxide / tungsten oxide nano-composite film on the surface of the metallic titanium is obtained through calcination; the film mainly comprises a titanium dioxide and tungsten trioxide compound with a nanobelt structure, the nanobelt width is in a range from 10 nm to 150 nm, and the length is in a range from 0.5 mu m to 20 mu m; the mass percentage of titanium oxide is in a range from 1% to 99.5%, and titanium oxide mainly adopts a rutile or anatase crystalline phase; the mass percentage of tungsten oxide is in a range from 0.5%-99%, and tungsten oxide mainly adopts a hexagonal or monoclinic crystal phase. Compared with the prior art, the preparation is simple and easy and is suitable for large-scale industrial production; the prepared titanic oxide film has important application value in the related fields of photoelectrocatalysis, metal corrosion prevention, electrochemical sensing and the like.
Owner:SHANGHAI JIAO TONG UNIV

Rutile crystal form titanium oxide having hierarchical structure, and preparation method and use thereof

The invention discloses a rutile crystal form titanium oxide having a hierarchical structure, and a preparation method and a use thereof. Titanium oxide is many rutile phase titanium oxide micrometer hollow balls with the surfaces being standing mono-crystalline nanorods and the side surfaces being open, wherein the specific surface area of the micrometer hollow balls is not less than 224.4m<2>/g, the ball diameter is 2-3mum, the diameters of the mono-crystalline nanorods are in a range of 5-8nm, and the rod length is not less than 200nm. The preparation method comprises the following steps: mixing titanyl sulfate hydrate, ethanol, glycerin and deionized water according to a molar ratio of the titanyl sulfate hydrate to ethanol to glycerin to the deionized water of 1:16-26:10-15:15-20, stirring for at least 1h to obtain a mixed solution, placing the mixed solution in a closing state, reacting at 140-160DEG C for at least 30h to obtain a reaction mixture, removing the supernatant of the reaction mixture, cleaning the obtained sediment by industrial alcohol at least 3 times, and drying the cleaned sediment at 75-85DEG C for at least 1h to obtain the rutile crystal form titanium oxide having a hierarchical structure. The rutile crystal form titanium oxide having a hierarchical structure can be widely used in chromium polluted solutions for photo-catalytic degradation adsorption.
Owner:HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI

Titanium oxide production process

A process for producing a titanium oxide is provided which comprises the steps of (i) reacting a titanium compound with ammonia in an amount exceeding the stoichiometric amount necessary to convert the titanium compound to a titanium hydroxide or reacting a titanium compound with a base at pH of from about 2 to about 7, to obtain a reaction product and (ii) calcining the obtained product. The titanium oxide exhibits a high photocatalytic activity by visible light radiation.
Owner:SUMITOMO CHEM CO LTD

Method for preparing titanium oxide through reducing titanium-containing complexes at normal temperature

The invention discloses a method for preparing titanium oxide through reducing titanium-containing complexes at normal temperature. The method is characterized in that reduction reaction occurs in a normal temperature liquid phase; the potential safety hazards due to mixing of reducing agents and air are eliminated; the reduction is performed in the liquid phase, the microscopic uniformity is high; the firing temperature is low; the time is short. The method has the following principle and steps that titanium sulfate or titanium tetrachloride and ammonium hydroxide or sodium hydroxide take a reaction to obtain titanic acid; the titanic acid reacts with oxalic acid or citric acid to form an oxalate oxytitanate complex-ion or oxytitanate citrate complex-ion solution; next, reaction is performed with zinc powder; the complex ions are reduced into low-valent titanium complex ions; the pH value of the solution is regulated to 12 by ammonium hydroxide; precipitates of dark brown color to dark violet color are generated; washing is performed for 3 to 5 times by 3 to 5 times of deionized water; the zin is washed away in an ion ZnO2<2-> form to obtain pure titanium hydroxide precipitates; oxalic acid is added until the pH is 0.5 to 1.5; drying is performed to 2 to 5 hours at 120 to 180 DEG C; the temperature is raised from room temperature to 820 to 950 DEG C by a muffle furnace; roasting is performed for 2 to 6 hours; titanium oxide spherical powder with the Ti4O7 content being 90 percent or higher is obtained.
Owner:CHENGDU UNIVERSITY OF TECHNOLOGY

A method for preparing pure phase bismuth titanate and titanium oxide composite material by alcohol thermal method

The invention discloses a method for preparing a pure phase bismuth titanate and titanium oxide composite material by using an alcohol heat method. The method comprises the following steps: adding a bismuth nitrate solid in a mixed solvent of glycerin and ethyl alcohol the volume ratios being (0.05-0.2) to 1, fully dissolving the bismuth nitrate solid in the mixed solvent, dropwise adding tetrabutyl titanate in the solution, stirring and carrying out ultrasonic treatment on the solution, transferring the mixed solution in a reaction kettle, arranging the reaction kettle in a 110-150 DEG C constant temperature oven and reacting for 18-24h, cooling, filtering and drying a mixture in the reaction kettle, burning the mixture in a procedure temperature control furnace for 1-3h under 500-600 DEG C, and preparing the pure phase bismuth titanate and titanium oxide composite material. The method provided by the invention has the advantages that the bismuth titanate and titanium oxide composite material with different types and shapes are obtained by controlling, bismuth titanate comprises a pure phase Bi4Ti3O12, Bi2Ti2O7 or Bi2TiO32, and the shape of the composite material comprises a globular shape, a petal shape, a three-dimensional layer shape and a piece shape and the like.
Owner:NANJING NORMAL UNIVERSITY

Photothermal directional control elastic superhydrophobic surface liquid drop migration device and using method thereof

The invention discloses a photothermal directional control elastic superhydrophobic surface liquid drop migration device and a using method thereof. The photothermal directional control elastic superhydrophobic surface liquid drop migration device comprises a substrate, and is characterized in that the substrate is formed by mixing polydimethylsiloxane and heat absorbing material titanium dioxidepowder or ferroferric oxide powder, a transparent superhydrophobic layer is etched or sprayed on the surface of the substrate, and a green laser is arranged above the transparent superhydrophobic layer. According to the photothermal directional control elastic superhydrophobic surface liquid drop migration device and the using method thereof, the green laser is utilized to heat the substrate, titanium dioxide in the substrate is subjected to photo-thermal conversion and heat is transferred to polydimethylsiloxane, the polydimethylsiloxane is heated to generate deformation protrusions, and whenliquid drops arranged on the surface of the transparent superhydrophobic layer reach rolling angles on slopes formed by the deformation protrusions, the liquid drops roll downwards, so that the rolling migration of the directionally controlled liquid drops is realized, the precise control of micro-fluid is realized, and the photothermal directional control elastic superhydrophobic surface liquiddrop migration device can be widely applied to the fields of fluid transportation, chemical analysis, medical detection and the like.
Owner:CHONGQING UNIV

Novel glass curtain wall sealant

The invention discloses a novel glass curtain wall sealant which comprises the following components in parts by weight: 5-8 parts of methyltrimethoxy silane, 10-20 parts n-butyl borate, 3-6 parts of gas phase white carbon black, 1-3 parts of copper oxide, 1-3 parts of titanium sesquioxide, 3-6 parts of titanium white, 10-20 parts of ethyl orthosilicate and 4-8 parts of phthalate. A preparation method of the novel glass curtain wall sealant comprises the following steps: proportionally mixing the components, and uniformly stirring and dispersing to obtain the finished product. Compared with the prior art, the novel glass curtain wall sealant has favorable properties such as heat resistance, aging resistance, water resistance and the like, and has low-temperature flexibility and favorable elasticity, thus being a sealant which can be widely used.
Owner:江华瑶族自治县金牛开发建设有限公司

Ore reduction process using carbon based materials having a low sulfur content and titanium oxide and iron metallization product therefrom

The present invention is one or more processes for producing separable iron and titanium oxides from an ore comprising titanium oxide and iron oxide, comprising: (a) forming agglomerates comprising carbon-based material and the ore, the quantity of carbon of the agglomerates being at least sufficient for forming a ferrous oxide-containing molten slag, at an elevated temperature; (b) introducing the agglomerates onto a bed of carbon-based material in a moving hearth furnace, wherein the carbon-based materials used for both the agglomerates and the bed have a low sulfur content; (c) heating the agglomerates in the moving hearth furnace to a temperature sufficient for liquefying the agglomerates to produce a liquid comprising ferrous oxide-containing slag; (d) metallizing the ferrous oxide of the slag by reaction of the ferrous oxide and the carbon of the carbon bed at a furnace temperature sufficient for maintaining the slag in a liquid state; (e) solidifying the slag after metallization of the ferrous oxide to form a matrix of titanium oxide-rich slag having a plurality of metallic iron granules distributed there through; and (f) separating the metallic iron granules from the slag, the slag comprising greater than 85% titanium dioxide based on the entire weight of the matrix after separation of the metallic iron.
Owner:THE CHEMOURS CO FC LLC

Method for preparing porous titanium with titanium sesquioxide

ActiveCN109807330AMeet the needs of multi-scale holesArgon atmosphereSesquioxide
The invention relates to a method for preparing porous titanium with titanium sesquioxide and belongs to the technical field of porous titanium preparation. According to the method, titanium sesquioxide powder and calcium chloride are mixed evenly to obtain Ti2O3/CaCl2 mixed powder; the Ti2O3/CaCl2 mixed powder is subjected to pressing formation to obtain a preformed body; the preformed body is put in a vacuum or argon atmosphere to be sintered for 30-120 min under the condition of the temperature of 850-1000 DEG C, and a porous precursor is obtained; under the conditions that pressure intensity is 10<-1>-10 Pa and temperature is 900-1200 DEG C, and calcium vapor is adopted for reducing the porous precursor for 4-12 h; dilute hydrochloric acid solution is adopted for immersing reduction products for 30-240 min, and solid-liquid separation is conducted to obtain a solid A and pickle liquor; deionized water and absolute ethyl alcohol are used for alternately washing the solid A, and thenvacuum drying is conducted to obtain sheet porous titanium; and the sheet porous titanium is put at the temperature of 1200-1400 DEG C, vacuum sintering is conducted for 2-4 h, and the porous titanium is obtained. The porous titanium prepared by the method has two pore diameter distributions which are large pores of the pore diameter of 50-200 [mu]m and micropores of the pore diameter of 4-15 [mu]m correspondingly.
Owner:KUNMING UNIV OF SCI & TECH

Honeycomb structure

Provided is a honeycomb structure which uses a TiO2 / V2O5 / WO3 catalyst, and which has excellent NOX conversion efficiency and thermal durability. This honeycomb structure is provided with a honeycomb unit in a shape in which multiple cells are partitioned by cell walls, said cells containing at least titanium oxide, vanadium oxide, tungsten oxide and an inorganic binder and extending in the longitudinal direction from one end surface to the other end surface, and is characterized in that the hydrogen consumption from vanadium reduction in temperature-programmed reduction with hydrogen (H2-TPR) is 0.6mmol or more per 1g of the honeycomb structure, and the molar ratio (W / V) of tungsten atoms to vanadium atoms is 0.8-1.2.
Owner:IBIDEN CO LTD

Concrete additive and preparation method

The invention discloses a concrete additive. The concrete additive contains the following raw materials in parts by weight: 40-50 parts of bentonite, 20-35 parts of coal gangue, 10-15 parts of calciumchloride, 15-20 parts of polydimethylsiloxane, 8-15 parts of melamine, 5-10 parts of methyl silicone oil and 2-6 parts of titanium sesquioxide. A preparation method of the concrete additive comprisesthe following steps: (1) mixing bentonite, coal gangue and calcium chloride, sieving by virtue of a 200-mesh sieve, and baking at 200-400 DEG C for 30-40 minute; and (2) adding polydimethylsiloxane,melamine, methyl silicone oil and titanium sesquioxide, and adequately stirring and mixing. According to the concrete additive, the freezing resistance of the concrete can be effectively improved, thestrength of the concrete in a low-temperature environment is improved, and the service life of the concrete in the low-temperature environment is prolonged.
Owner:徐州和合新型建材有限公司

Titanium sesquioxide and preparation process and application thereof

The invention relates to the field of inorganic material preparation, in particular to a preparation method of titanium sesquioxide. The titanium sesquioxide preparation process comprises the steps of step a, mixing titanium dioxide and silica fume in the weight ratio of 1:0.25-0.5, forming to obtain formed material; step b, making the silica fume cover the surface of the material obtained in step a, heating the material to 1400-1500 DEG C in an airy atmosphere, keeping the temperature for 5-25 minutes, cooling and ball-grinding the material to obtain an original product; adding alkaline solution into the original product obtained in step b, making the product soak in alkaline solution for 60-120 minutes, filtering the product to obtain the final product. The titanium sesquioxide and preparation process is simple in process, short in reduction time, capable of preparing middle product in the airy atmosphere, and low in the requirements of production equipment and production environment. The final product is high in titanium sesquioxide purity. The application scope is wide, and the preparation process has a big market potential and application value.
Owner:山东临港智能制造产业园有限公司
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