The invention provides an organic conductive coating and a preparation method thereof, wherein the organic conductive coating comprises the following components in parts by weight: 8-15 parts of graphite, 1-6 parts of titanium dioxide, 0.05-0.15 part of antimony trioxide, 0.3-1.2 parts of magnesium oxide, 0.5-1.8 parts of lead oxide, 1-5 parts of titanium sesquioxide, 10-30 parts of alkyd resin, 0.2-0.8 part of silicone oil, 0.05-0.12 part of xylene, 0.1-0.8 part of epoxy resin and 0.3-0.7 part of barium carbonate. The preparation method comprises the following steps: firstly uniformly mixing the graphite, the titanium dioxide, the antimony trioxide, the magnesium oxide, the lead oxide, the titanium sesquioxide and the barium carbonate, then adding the alkyd resin, the epoxy resin and the silicone oil, uniformly stirring, further adding the xylene and uniformly mixing for preparation. The organic conductive coating provided by the invention has high adhesion force of above 98%, which is better than similar products; and furthermore, the electric conductivity is good, and the electric resistance is less than 60 ohm.