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49results about How to "Achieve a high degree of dispersion" patented technology

Phosphor and rare earth modified molecular sieve

The invention relates to a phosphor and rare earth modified molecular sieve, which contains 15-30% of Zn or Mg, 0.1-10wt% of P and 0.1-10wt% of La and / or Ce. A aluminum source on the molecular sieve surface is used, Zn(Mg) / Al / La(Ce) ternary hydrotalcite of carbonic acid radical pillared is subjected to in situ synthesis, an ion exchange method is used for preparing hydrotalcite of phosphoric acid dihydro radical pillared, a program temperature-raising calcination method is used, P2O5, La2O3 or Ce2O3 is highly dispersed on the surface and tunnel of the molecular sieve, thereby the acidity of the molecular sieve is enhanced. A hydrotalcite precursor method is used for modifying the molecular sieve, high dispersion of an active group is realized, the acidity and the stability of the molecular sieve can be substantially improved, and the molecular sieve provides a material possessing practical application value for heavy oil catalytic cracking catalysts.
Owner:PETROCHINA CO LTD +1

Amino metal organic framework material containing active metal component as well as preparation method and application of amino metal organic framework material

The invention provides an amino metal organic framework material containing an active metal component. The amino metal organic framework material is used as a carrier; and the active metal component is dispersed in the carrier, wherein the weight of the active metal component is 0.05-15% of that of the amino MOFs material. According to the invention, a mixed solution is formed from the carrier and an active metal precursor containing a carbanyl group; amino in the MOFs material is reacted with the carbanyl group in the active metal precursor, so that the active metal precursor is connected to the MOFs material; then, the material is prepared through a reduction method; uniform dispersion of the active metal component in the MOFs material is realized; when the material is used as the catalyst, the catalytic effect is obvious because of high dispersion of the active component, for example, the amino metal organic framework material is used in a process for preparing aromatic amine by hydrogenation reduction of an aromatic nitro compound, etc.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI

Boron nitride composite mesoporous oxide nickel-based catalyst and preparation method thereof

The invention relates to a boron nitride composite mesoporous oxide nickel-based catalyst and a preparation method thereof. The nano-boron nitride as the carrier having high thermal stability and carbon deposition resistance is combined with active metal anchoring and dispersion based on mesoporous oxides so that the catalytic material having high resistance to sintering and carbon deposition is obtained. The preparation method comprises adding a surfactant and ammonia water into high thermal stability boron nitride and nickel precursors as reactants, carrying out ultrasonic agitation, loading active metal components to the boron nitride nanosheet layer, and carrying out in-situ coating on the surface with an oxide having a mesoporous channel structure. The coated mesoporous structure can realize high dispersion of the active nickel component. Through drying, high temperature calcination and programmed heating reduction, the nickel-based catalyst having high performances and a novel structure is prepared. The boron nitride composite mesoporous oxide nickel-based catalyst has the advantages of simple process, low production cost, no environment pollution and high catalytic efficiency.
Owner:SHANGHAI UNIV

Solid basic catalyst, preparation method of solid basic catalyst and application of solid basic catalyst in ester exchange reaction

The invention discloses a solid basic catalyst, a preparation method of the solid basic catalyst and an application of the solid basic catalyst in ester exchange reaction. The solid basic catalyst catalyzes the ester exchange reaction by the reaction of metal organic compound and hydroxyl on a carrier under the moderate conditions to synthesize dimethyl carbonate. The solid basic catalyst provided by the invention consists of metal organic alkali and the carrier. The metal organic alkali is linked to the carrier in bond-forming manner; the metal organic alkali is one or more of lithium methoxide, lithium ethoxide, lithium isopropoxide, lithium n-butoxide, lithium tert-butoxide, sodium methoxide, sodium ethoxide, sodium isopropoxide, sodium n-butoxide, sodium tert-butoxide, potassium methoxide, potassium ethoxide, potassium isopropoxide, potassium n-butoxide and potassium tert-butoxide; the carrier is one or more of silicon oxide, aluminium oxide, titanium oxide, zirconia, mesoporous silicon oxide synthesized by the template method, mesoporous aluminium oxide synthesized by the template method, mesoporous titanium oxide synthesized by the template method, and mesoporous zirconia synthesized by the template method.
Owner:NANJING UNIV OF TECH

Sandwich-structured nanometer catalytic material and preparation method thereof

The invention discloses a sandwich-structured nanometer catalytic material. The sandwich-structured nanometer catalytic material is characterized by taking magnetic Fe3O4 nanospheres as a core, nanometer noble-metal particles as an intermediate phase and cerium-titanium composite oxides as a shell, and the nanometer noble-metal particles are selected from one of Au, Pd and Pt. The invention further provides a preparation method of the sandwich-structured nanometer catalytic material. The preparation method includes sequentially preparing the magnetic Fe3O4 nanospheres, a magnetic noble-metal composite microsphere solution, a magnetic noble-metal composite noncrystalline cerium-titanium-silicon material and a magnetic noble-metal composite crystalline cerium-titanium-silicon material, removing SiO2 through an alkali liquor, separating, washing and drying so as to obtain the sandwich-structured nanometer catalytic material high in catalysis activity and thermostability and excellent in magnetic reclaim performance. Reactants can be in full contact with activated noble metal layers through porous passages in the outer oxide shell. The sandwich-structured nanometer catalytic material has a promising application prospect in the fields of biological target therapy, optical nanometer devices, water-gas shift and olefin gas-phase epoxidation.
Owner:南京工大环保科技有限公司

Phosphor and rare earth composite modification method of molecular sieve

A phosphor and rare earth composite modification method of a molecular sieve comprises that an aluminum source on the surface of the molecular sieve is utilized for in situ synthesis of carbonate-ion-pillared Zn (Mg) / Al / La (Ce) ternary hydrotalcite; that dihydrogen-phosphate-ion-pillared hydrotalcite is prepared by employing an ion exchange method; and that a program heating calcination method is used to make P2O5, La2O3 or Ce2O3 be highly dispersed in the surfaces and pores of the molecular sieve, thereby improving the acidity of the molecular sieve. According to the method of the invention, the molecular sieve modified by hydrotalcite precursor method not only realizes high dispersion of active components, but also greatly improves the acidity and the stability of the molecular sieve, thereby providing a material with practical application values for preparing catalyst for catalytic cracking of heavy oil.
Owner:PETROCHINA CO LTD +1

Mono-disperse noble metal-loaded single-layer hydrotalcite material as well as preparation method and application thereof

The invention discloses a mono-disperse noble metal-loaded single-layer hydrotalcite material as well as a preparation method and application thereof. A series of mono-disperse noble metal-loaded single-layer hydrotalcite materials are synthesized through adjusting and controlling the types of hydrotalcite main body laminates and noble metal ions by virtue of a one-step coprecipitation method. Thematerial presents excellent catalytic activity in dehydrogenation coupling reaction. A catalyst prepared according to the invention is easy to operate, noble metals are in a mono-disperse state, andthe catalyst is low in use cost and can be easily produced and used in large scale.
Owner:BEIJING UNIV OF CHEM TECH

In-situ sulfur-doped mesoporous carbon supported palladium metal catalyst, and preparation method and application thereof

The invention provides an in-situ sulfur-doped mesoporous carbon supported palladium metal catalyst, and a preparation method and application thereof. A required carrier material is directly obtainedby adopting a method of direct hydrothermal carbonization and calcination for further carbonization, so that sulfur can be doped into a skeleton of a carbon material and exists in a more stable form.In the sulfur-doped activated carbon supported noble metal catalyst, a large number of defects generated by doping are more beneficial to stable combination of palladium metal nanoparticles and the carrier, and strong interaction between sulfur and metal ensures high stability of the catalyst, so that metal nanoparticles are not easily agglomerated or lost in a hydrogenation reaction process, andthe service life of the catalyst is prolonged. Through the catalyst, halogenated nitrobenzene can be completely converted in a selective hydrogenation reaction of the halogenated nitrobenzene, and thehalogenated aniline selectivity can achieve 99.9%. In addition, the use condition is mild, stability is good, the use amount of the catalyst is less, and the service life of the catalyst is long.
Owner:ZHEJIANG UNIV OF TECH

Preparation method and application of Cu/N doped carbon nanosheet catalyst with high stability

The invention discloses a preparation method and application of a Cu / N doped carbon nanosheet catalyst with high stability. The preparation steps include: first, weighing raw materials of magnesium citrate, potassium citrate and ammonium oxalate in a mass ratio of 1:(2-8):(1-16) to prepare an N-doped carbon nanosheet; and then, preparing a N-doped carbon nanosheet copper-carrying salt precursor, and finally, carrying high-temperature roasting to obtain the Cu / N doped carbon nanosheet catalyst with high stability. The obtained catalyst has multilevel pores in which micropores, mesopores and macropores coexist and has a nanosheet structure, and Cu nanoparticles are uniformly dispersed on the carrier; in addition, the multilevel porous nanosheet structure is rich in carbon vacancies, and at lower temperatures (70-300 DEG C), more carbon vacancies can be excited to anchor the Cu nanoparticles, so that the Cu nanoparticles are redispersed into single atoms and atomic clusters of -0.91 nm. The Cu / N doped carbon nanosheet catalyst can also be used in oxidative carbonylation of carbon monoxide to synthesize dimethyl carbonate.
Owner:TAIYUAN UNIV OF TECH

Catalyst slurry for fuel cell, preparation method thereof and membrane electrode

The invention relates to the field of fuel cells, and particularly discloses catalyst slurry for a fuel cell, a preparation method of the catalyst slurry and a membrane electrode. The preparation method of the catalyst slurry for the fuel cell comprises the following steps of S1) carrying out ultrasonic dispersion treatment on a perfluorosulfonic acid solution at 50-90 DEG C to obtain a perfluorosulfonic acid dispersion liquid; and S2) mixing the perfluorosulfonic acid dispersion liquid with a catalyst, a dispersing agent and deionized water, and emulsifying and dispersing to obtain the fuel cell catalyst slurry. By utilizing the preparation method, the problem of uneven dispersion of the proton conduction ionomer in the existing catalyst slurry can be solved, and the preparation method isused for improving the dispersity of the proton conduction ionomer in the catalyst slurry.
Owner:SHANGHAI ELECTRICGROUP CORP

Micro-capsule-structured carbon-sulfur compound and preparation method and application thereof

The invention relates to a micro-capsule-structured carbon-sulfur compound and a preparation method and an application thereof. The compound takes lithium sulfide as a capsule-core material, and takes a carbon material and a lithium ion conductor as a capsule-wall material; the capsule-core material is positioned in the hollow capsule-wall material, wherein the capsule-core material is 20-300nm in grain diameter; the capsule wall is 2-50nm in thickness; the content of the capsule-core material accounts for 20-80wt% of the carbon-sulfur compound; and the mass ratio of the carbon material to the lithium ion conductor in the capsule-wall material is (1:99) to (99:1). Based on the structural advantage of the "micro-capsule", a positive electrode material design thought of "capsule core sulfur-carrying, capsule wall sulfur-fixing, hole wall electric conduction and hole channel sold-state lithium conduction" is proposed, so that the utilization rate and the cycling stability of the active material sulfur in a lithium-sulfur battery are greatly improved.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Method for preparing carbon-loaded metal sulfide nanocomposite through electrostatic spinning

The invention belongs to the field of metal sulfide nano-materials, and particularly relates to a method for preparing a carbon-loaded metal sulfide nanocomposite through electrostatic spinning, whichcomprises the following steps: (1) preparing a spinning precursor solution: respectively dissolving a thiacalixarene metal cluster compound and a spinning aid in DMF (Dimethyl Formamide), and mixing;(2) preparing nano-fibers by electrostatic spinning: sucking the obtained spinning precursor solution into an injector, adjusting the pump flow rate and voltage of the injector and the distance between a spinning needle and a receiving plate, spinning, and receiving a nano-fiber felt by the receiving plate; (3) pre-oxidizing the nano-fiber felt: pre-oxidizing the collected nano-fiber felt; and (4) carbonizing in an N2 atmosphere: carbonizing the pre-oxidized nano-fiber felt, and naturally cooling to obtain the target product. The target product is ideal in electrochemical performance and goodin capacitance characteristic, the flaky carbon material is directly used as an electrode, additives or impurities such as a binding agent can be eliminated, and the energy capacity and performance are improved.
Owner:LIAONING UNIVERSITY OF PETROLEUM AND CHEMICAL TECHNOLOGY

Cobalt-zinc bimetallic loaded nano carbon material and preparation method and application thereof in catalytic oxidation of magnesium sulfite

The invention discloses a preparation method of a cobalt-zinc loaded bimetallic nano carbon material with efficient oxidation performance on magnesium sulfite. The composite material is a cobalt-zincbimetal particle modified porous carbon material, and the preparation method comprises the following steps: mixing and stirring a self-made metal organic framework ZIF-8 and cobalt nitrate hexahydratein a methanol solution, heating, centrifuging, and calcining the dried mixture in a protective atmosphere to obtain the cobalt-zinc bimetal loaded nano carbon material. According to the method, a metal organic framework material containing cobalt and zinc is used as a precursor, modification of a porous carbon material by cobalt-zinc bimetal is completed by a one-step method, and the synthesis process is green and environment-friendly; the synthesized metal-modified porous carbon material can realize efficient catalytic oxidation of magnesium sulfite.
Owner:NORTH CHINA ELECTRIC POWER UNIV (BAODING)

Method for synthesizing electrolytic packing in iron carbon through in-situ carbothermic reduction

The invention relates to the field of electrolytic packing preparation, and provides a method for synthesizing electrolytic packing in iron carbon through in-situ carbothermic reduction. The method comprises the following steps of oxidization modification, wherein coal pitch is dispersed into a Fenton reagent, the mass ratio of the coal pitch to the Fenton reagent is 1:(5-100), after a hydrothermal reaction is performed for 3-12 h at the temperature of 150 DEG C-250 DEG C, an active regulator is added, the hydrothermal reaction is continuously performed for 3-10 h at the temperature of 150 DEG C-200 DEG C, centrifugal separation is performed, and drying is performed for 4-6 h at the temperature of 120 DEG C-150 DEG C; in-situ reduction, wherein the obtained modified matter is roasted for 2-8 h at the temperature of 500 DEG C-1200 DEG C. The method is low in cost and simple in preparation process, and the prepared iron carbon packing is developed in pore structure and high in metal active component dispersity and wastewater treatment capacity.
Owner:山西德恒机电科技有限公司

Preparation method of high-activity catalyst used for catalyzing isomerization of glucose

The invention discloses a preparation method of a high-activity catalyst used for catalyzing isomerization of glucose. The preparation method specifically comprises the steps that magnesium salt, niobium hydroxide and other active centers are evenly dispersed in a high-amylose hydrogel containing urea and thiourea, after freeze drying, high-temperature roasting is carried out under the inert gas atmosphere, and the MgO / Nb2O5 catalyst taking N and S doped activated carbon as a carrier is obtained. The catalyst can be uniformly dispersed in a solvent system, reduces the aggregation among the active centers, and can efficiently catalyze the glucose isomerization into fructose under the mild conditions. The provided catalyst has the advantages that the preparation process is simple, the catalytic efficiency is high, and reliable technical support is provided for the industrialized popularization of the high value-added fructose prepared by the glucose isomerization.
Owner:GUANGXI ACAD OF SCI

Method for modifying rare earth of molecular sieve

InactiveCN102744093AAct as a natural barrierHighly decentralized implementationCatalytic crackingMolecular sieve catalystsMolecular sieveMagnesium salt
The invention relates to a method for modifying rare earth of a molecular sieve, which is characterized in that an aluminum source on the molecular sieve surface is used, Zn(Mg) / Al / La(Ce) ternary hydrotalcite is subjected to in situ synthesis, The synthesized hydrotalcite material comprises the following components: (1-50)zinc salt(magnesium salt): (1-50)aluminum salt: (10-100)H2O: rare earth compound. A program temperature-raising calcination method is used, P2O5, La2O3 or Ce2O3 is highly dispersed on the surface and tunnel of the molecular sieve, thereby the acidity of the molecular sieve is enhanced. The USY molecular sieve modified by using a hydrotalcite precursor method is used to prepare a mode catalyst, compared with the mode catalyst prepared by the USY molecular sieve modified by using a dipping method, the MAT index is increased by 3.58%, the gas yield is decreased by 0.21%, the gasoline yield is increased by 1.59% and the carbon deposit is decreased by 0.63%.
Owner:PETROCHINA CO LTD +1

A kind of sandwich structure nano catalytic material and preparation method thereof

The invention discloses a sandwich structure nano-catalytic material. The core of the material is magnetic Fe3O4 nanospheres, the intermediate phase is nano-noble metal particles selected from Au, Pd and Pt, and the outer shell is cerium-titanium composite oxide. The invention also provides a method for preparing the nanocatalytic material, which sequentially prepares magnetic Fe3O4 nanomicrospheres, magnetic noble metal composite microsphere solutions, magnetic noble metal composite amorphous cerium titanium silicon materials, and magnetic noble metal composite crystalline cerium titanium silicon materials. Finally, SiO2 is removed through alkaline solution, separated, washed, and dried to obtain a nanocatalytic material with strong catalytic activity, high thermal stability, and excellent magnetic recovery performance. The pores in the outer oxide shell of the material can promote Full contact between the reactants and the active precious metal layer. This material has excellent application prospects in biological targeted therapy, optical nanodevices, water gas shift, olefin gas phase epoxidation, etc.
Owner:南京工大环保科技有限公司

Method for Synthesizing Fe-Carbon Internal Electrolytic Filler by In-Situ Carbothermal Reduction

The invention relates to the field of electrolytic packing preparation, and provides a method for synthesizing electrolytic packing in iron carbon through in-situ carbothermic reduction. The method comprises the following steps of oxidization modification, wherein coal pitch is dispersed into a Fenton reagent, the mass ratio of the coal pitch to the Fenton reagent is 1:(5-100), after a hydrothermal reaction is performed for 3-12 h at the temperature of 150 DEG C-250 DEG C, an active regulator is added, the hydrothermal reaction is continuously performed for 3-10 h at the temperature of 150 DEG C-200 DEG C, centrifugal separation is performed, and drying is performed for 4-6 h at the temperature of 120 DEG C-150 DEG C; in-situ reduction, wherein the obtained modified matter is roasted for 2-8 h at the temperature of 500 DEG C-1200 DEG C. The method is low in cost and simple in preparation process, and the prepared iron carbon packing is developed in pore structure and high in metal active component dispersity and wastewater treatment capacity.
Owner:山西德恒机电科技有限公司

Preparation method of catalyst for environmentally-friendly efficient conversion of furfural into 2-methylfuran

The invention provides a preparation method of a catalyst for environmentally-friendly efficient conversion of furfural into 2-methylfuran, and relates to a catalyst preparation method. According to the present invention, the high dispersion of active components, rare earth and other modification components is achieved through the precipitation and hydrothermal synergetic preparation method; the catalyst comprises 20-50% of a copper oxide, 40-70% of silicon oxide, 0-8% of alumina, and 1-6% of a rare earth oxide of La, Ce, Pr, Nd, Sc, Y and other rare earth elements, and is a regulated modifiedCu catalyst; and with the application of the synthesized environmentally-friendly catalyst in the preparation of 2-methylfuran through gas phase hydrogenation of furfural, the furfural conversion rate is 100%, the 2-methylfuran selectivity is more than 90%, and the performance is stable after the continuous operation for 500 h.
Owner:SHENYANG INSTITUTE OF CHEMICAL TECHNOLOGY

Residue-free instant marinating material and preparation method thereof

The invention relates to a residue-free instant marinating material. The residue-free instant marinating material is characterized by being prepared from the following spices in parts by weight: 10-17parts of star anise, 5-8 parts of rhizoma kaempferiae, 2-3 parts of villous amomum fruits, 3-5 parts of radix angelicae, 3-5 parts of white peony roots, 2-5 parts of cloves, 5-7 parts of cinnamon bark, 8-10 parts of fennel fruits, 1-3 parts of bay leaves, 1-3 parts of fructus tsaoko, 5-8 parts of ligusticum chuanxiong, 3-7 parts of licorice roots, 3-6 parts of dried orange peel, 1-3 parts of murraya paniculata, 3-6 parts of nardostachys jatamansi roots, 1-3 parts of rhizoma polygonati fruits, 1-2 parts of rhizoma alpiniae officinarum, 6-8 parts of Chinese prickly ash, 1-2 parts of fructus piperis, 5-8 parts of old ginger, 4-7 parts of scallions, 8-14 parts of white granulated sugar, 2-3 parts of chicken essence, 1-3 parts of monosodium glutamate, 20-30 parts of table salt and 1-2 parts ofethyl maltol. The residue-free instant marinating material disclosed by the invention not only has the same fragrance as that of a conventional marinating material, but also is free from precipitateor residues in the marinating process, and marinating liquid can be quickly made.
Owner:SOUTHWEST UNIVERSITY +1

Preparation and application of bismuth titanate-coated NH2-MIL-125 photocatalyst

On the basis of previous research work accumulation, an MOFs photocatalyst with a titanium-based metal cluster as a central node and an amino-containing photosensitive matrix as a ligand is designed, a novel efficient bismuth titanate-coated NH2-MIL-125 composite catalytic catalyst is prepared by using an in-situ etching regeneration strategy, a novel stable, green and efficient photocatalytic NO elimination way is developed, and the photocatalytic NO elimination effect is improved. The basic relationship between the structure and the performance is deeply studied, and diversified MOFs photocatalyst molecular libraries are constructed. Meanwhile, on the basis of reasonable molecular structure design, basic laws between in-situ etching of bismuth nitrate pentahydrate with different contents and the structure and catalytic performance of the MOFs material are deeply explored, and the application prospect of the MOFs material in the heterogeneous catalysis field of visible light catalysis NO elimination and the like is developed. By adjusting the mass of bismuth nitrate pentahydrate, it is found that when the mass ratio of bismuth nitrate pentahydrate to NH2-MIL-125 is 4: 10, the in-situ etching effect is the best, and the NO elimination effect is the best.
Owner:CHONGQING TECH & BUSINESS UNIV

Method for degrading polycyclic aromatic hydrocarbon wastewater based on layered titanium lanthanum niobate as catalyst

The invention discloses a method for degrading polycyclic aromatic hydrocarbon wastewater based on layered titanium lanthanum niobate as a catalyst. Precursors such as a lanthanum salt, niobium hydroxide and a titanate are uniformly dispersed, and are calcined at a high temperature to obtain the layered titanium lanthanum niobate catalyst. The degradation of polycyclic aromatic hydrocarbons such as naphthalene, acenaphthene, acenaphthylene and fluorenes in wastewater is efficiently catalyzed under the action of ultraviolet light and the catalyst. The method provided by the invention has the advantages of simple process, high catalysis efficiency and low energy consumption, and provides reliable technical support for promoting pollutant treatment and environmental restoration.
Owner:GUANGXI ACAD OF SCI

CNTs/Fe3O4/melamine composite carbon foam as well as preparation method and application thereof

The invention provides CNTs / Fe3O4 / melamine composite carbon foam as well as a preparation method and application of the CNTs / Fe3O4 / melamine composite carbon foam. The preparation method comprises the following steps: by taking melamine sponge as a raw material, sequentially carrying out a carbonization process and a carbon nanotube in-situ growth process to prepare a flexible carbon matrix material, then carrying out in-situ growth of an iron-based MOFs crystal material on the surface of the flexible carbon matrix material to obtain a CNTs / Fe-MOFs / melamine composite material, and carrying out carbonization treatment to obtain the flexible CNTs / Fe3O4 / melamine composite carbon foam. According to the composite carbon foam prepared by the method, high dispersion of Fe3O4 nanoparticles is realized, so that the electromagnetic shielding performance of the composite foamy carbon can be improved. The material is used in the field of electromagnetic shielding and shows excellent electromagnetic shielding performance.
Owner:河北中煤旭阳能源有限公司

Preparing method for range limiting type nanometer zero-valent iron-nickel composite

The invention relates to a preparing method for a range limiting type nanometer zero-valent iron-nickel composite, and belongs to the technical field of environmental protection. Iron salt and nickelsalt are firstly dissolved in an organic solvent to obtain a solution A, and an organic ligand is dissolved in a same organic solvent to obtain a solution B; then the solution A is quickly added intothe solution B, centrifugal separation is carried out after even stirring, solid obtained after centrifugal separation is washed with DMF, and then vacuum drying is carried out on the solid to obtainan iron-nickel complex; and finally the iron-nickel complex is calcined at high temperature in an inert gas atmosphere and is then cooled to room temperature to obtain the iron-nickel composite. The method is simple, the prepared range limiting type nanometer zero-valent iron-nickel composite has the obvious and enhanced dechlorination performance on organic chloride pollutants, agglomeration passivation can be avoided, and the problem of agglomeration passivation of nano-bimetallic particles in the prior art is solved.
Owner:YANCHENG INST OF TECH

A kind of nano-carbon material supporting cobalt-zinc bimetal, its preparation method and application in catalytic oxidation of magnesium sulfite

The invention discloses a preparation method of a supported cobalt-zinc bimetallic nano-carbon material with high oxidation performance to magnesium sulfite. The composite material is a porous carbon material modified by cobalt-zinc bimetallic particles. The preparation steps include: self-made The metal-organic framework ZIF-8 and cobalt nitrate hexahydrate are mixed and stirred in methanol solution, heated and centrifuged, and the dried mixture is calcined in a protective atmosphere to obtain a cobalt-zinc bimetallic nanocarbon material. The method of the invention uses a metal-organic framework material containing cobalt and zinc as a precursor, the modification of the cobalt-zinc bimetal to the porous carbon material is completed in one step, and the synthesis process is green and environmentally friendly; Efficient catalytic oxidation of magnesium.
Owner:NORTH CHINA ELECTRIC POWER UNIV (BAODING)

Preparation method of procaine

The invention discloses a preparation method of procaine, which comprises the following steps: (1) sequentially adding xylene, 4-nitrobenzoic acid and N, N-diethylethanolamine in a certain proportion into a reaction container in a stirring state, controlling the temperature at 140-150 DEG C, reacting and refluxing for 12-36 hours, stopping heating, and cooling to room temperature to obtain a nitrocaine solution, extracting with a 3-10% hydrochloric acid aqueous solution to obtain an upper layer which is a xylene solution and a lower layer which is a hydrochloride aqueous solution of nitrocaine; and (2) adding a hydrochloride aqueous solution of nitrocaine into a reaction kettle, adding the supported palladium-ruthenium bimetallic catalyst, introducing hydrogen until the hydrogen pressure is 0.5-2.0 MPa, controlling the reaction temperature to be 60-100 DEG C, carrying out water-phase hydrogenation reaction, and carrying out post-treatment after full reaction to obtain procaine. The method disclosed by the invention is simple in process, green and environment-friendly, and high in product yield.
Owner:ZHEJIANG UNIV OF TECH

Preparation method of D2 structure hexafluoropropylene dimer

The invention relates to the technical field of chemical processes, in particular to a preparation method of a D2 structure hexafluoropropylene dimer. According to the preparation method of the D2 structure hexafluoropropylene dimer, 5-bromine-6-sulfydryl pyridine and vinyl trifluoroborate are subjected to a sulfydryl-alkene reaction, the prepared auxiliary is added into metal fluoride, the valence state of metal can be stabilized, the catalytic activity can be improved, and high dispersion of active components in a fluorine-containing catalyst is achieved.
Owner:ZHEJIANG JUHUA HANZHENG NEW MATERIAL

A short-contact cyclone reactor integrated with liquid-liquid heterogeneous mixing, reaction and separation

The invention relates to a liquid-liquid heterogeneous mixing-reaction-separation integrated short-contact cyclone reactor, belongs the field of liquid-liquid heterogeneous mixing equipment, and particularly relates to a short-contact cyclone reactor integrating mixed reaction and separation. The reactor is characterized in that a light phase liquid inlet pipe (3) is arranged at one side of an outer barrel (4), a material circulating structure (9) for communicating an inner cavity of an inner barrel (5) with an annular cavity is arranged on the wall of the inner barrel (5); a light phase overflow outlet pipe (1) is arranged on the inner upper part of the inner barrel (5) in a sleeving manner, an annular mixing cavity is formed between the light phase overflow outlet pipe (1) and the inner barrel (5), the upper part of the light phase overflow outlet pipe (1) extends out of the inner barrel (5), and a heavy phase underflow out pipe (7) is fixedly arranged on the lower part of the inner barrel (5) in a sleeving manner by a conical pipe (6). According to the invention, the integrated process of quick mixing, quick reaction and quick separation of heterogeneous liquid is realized, the equipment structure is compact, the handling capacity is large, continuous operation is realized, and the reactor has the advantages of being low in maintenance cost and strong in adaptability.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA) +1
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