The invention discloses a PVDC coating material with high barrier performance. The PVDC coating material comprises a modified PA membrane, wherein the outer side surface of the modified PA membrane iscoated with modified PVDC rubber latex, the inner side surface of the modified PA membrane is coated with modified PVDC nano rubber, the modified PVDC nano rubber is prepared from the following raw materials: ultrapure water, a PH value buffering adjusting agent, vinylidene chloride monomers, methyl acrylate monomers, an initiator, and a dispersion agent, the thickness of the modified PA membraneis 81 to 89 micrometers, the thickness of the modified PVDC rubber latex smeared on the outer side surface of the modified PA membrane is 1.5 to 1.8 micrometers, the oxygen permeation amount of the PVDC coating material at the standard conditions that the temperature is 23 DEG C, the relative humidity is 65 percent and the thickness is 25.4 micrometers is 1.18 to 2.12 ml / M<2>.24h.0.1MPa, and thehumidity permeation amount is 0.1 to 0.96 g / M<2>.24h.0.1MPa. By adopting the PVDC coating material with the high barrier performance, the technical problems that the PVDC rubber latex is poor in heatstability, the dual-bond conjugation easily occurs when the PVDC rubber latex is heated or stored for a long term at a normal temperature, hydrogen chloride is leaked, holes are formed among molecules and the barrier performance is in failure can be solved.