The invention discloses a low-separation bonding shining silver powder coating. The low-separation bonding shining silver powder coating is prepared from, by weight, 25-35 parts of epoxy resin, 25-35 parts of carboxyl-terminated polyester resin, 10-15 parts of hydroxyl polyester resin, 1-3 parts of polyacrylate, 0.3-0.5 part of benzoin, 1-1.5 parts of silane coupling agent, 10-15 parts of barium sulfate, 5-10 parts of light calcium carbonate, 0-3 parts of titanium dioxide, 1-6 parts of surface-coated aluminum powder and 1-2 parts of bonding additive. The invention further provides a preparation method of the low-separation bonding shining silver powder coating. Through ingredient weighing, premixing, melting extrusion, grinding, screening, bonding, screening and finished product packaging, the low-separation bonding shining silver powder coating is obtained; through adjustment of the melting viscosity, glass transition temperature, bonding temperature and bonding time of the powder, the powder fully bonds with particles of the aluminum powder, so that the bonding rate reaches 98-100%, the separation rate of the aluminum powder is reduced, and the service life of coating film is prolonged.