The invention relates to a preparation method of copolyether ester, belonging to the field of
thermoplastic block copolyether ester elastomers. The copolyether ester contains a short-chain
polyester hard segment and a long-chain polyether ester
soft segment, wherein the short-chain
polyester hard segment comprises repeating units of a
dicarboxylic acid component and a dihydric
alcohol component, and the long-chain polyether ester
soft segment comprises repeating units of a
dicarboxylic acid component and a poly alkylene
ether glycol component. The
polyester hard segment comprises a polyester segment (A) and a polyester segment (B), wherein the polyester segment (A) comprises repeating units of an aromatic
dicarboxylic acid component and a 1,4-
butanediol component, and the polyester segment (B) comprises repeating units of an aromatic dicarboxylic acid component and a 1,4-
cyclohexanedimethanol component; and the polyether ester
soft segment is a polyether ester segment (C) which comprises repeating units of an aromatic dicarboxylic acid component and a poly alkylene
ether glycol component. The product has excellent comprehensive performance, the
melting point is 160-220 DEG C, the elongation at break is 500-1400%, and the
thermal decomposition temperature is 360-450 DEG C.