The present invention relates to a
fluorine-containing polyether
grafting modified waterborne
polyurethane, the preparation and the application thereof, a structural general formula of
polyurethane is as the formula, wherein, R1 is equal to a
polyurethane soft-segment
polyol structure, R2 is equal to a polyurethane hard-segment
isocyanate structure, R3 is equal to a polyurethane hard-segment chain
extender structure, R4 is equal to the
fluorine-containing polyether; X is equal to NH and O; the preparation is that: the
polyol and the
isocyanate react to compound the polyurethane
prepolymer, then the waterborne polyurethane are obtained through the
chain propagation of a chain
extender, then the waterborne polyurethane and the
fluorine-containing polyether are carried out a
grafting reaction in the big molecules, so as to synthesize the fluorine-containing polyether
grafting modified waterborne polyurethane; the application is that: the present invention can be applied to
aerospace,
aviation, automobiles,
electronics, textiles, carpets, leathers, paper making, packaging, washing, machinery, construction and other fields. The present invention adopts the water as the
solvent and has no
formaldehyde, no or low VOC emission, no
bioaccumulation and no
toxicity, which is a multifunctional, green, environment protective, water-proof and
dirt-proof
coating layer and fabric finishing agent.