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72 results about "Bioaccumulation" patented technology

Bioaccumulation is the gradual accumulation of substances, such as pesticides, or other chemicals in an organism. Bioaccumulation occurs when an organism absorbs a substance at a rate faster than that at which the substance is lost by catabolism and excretion. Thus, the longer the biological half-life of a toxic substance, the greater the risk of chronic poisoning, even if environmental levels of the toxin are not very high. Bioaccumulation, for example in fish, can be predicted by models. Hypotheses for molecular size cutoff criteria for use as bioaccumulation potential indicators are not supported by data. Biotransformation can strongly modify bioaccumulation of chemicals in an organism.

Acid generator, sulfonic acid, sulfonic acid derivatives and radiation-sensitive resin composition

A novel photoacid generator containing a structure of the following formula (I), wherein R is a monovalent organic group with a fluorine content of 50 wt % or less, a nitro group, a cyano group, or a hydrogen atom, and Z1 and Z2 are individually a fluorine atom or a linear or branched perfluoroalkyl group having 1-10 carbon atoms, is provided. When used in a chemically amplified radiation-sensitive resin composition, the photoacid generator exhibits high transparency, comparatively high combustibility, and no bioaccumulation, and produces an acid exhibiting high acidity, high boiling point, moderately short diffusion length in the resist coating, and low dependency to mask pattern density.
Owner:JSR CORPORATIOON

Uniform fluorescent microsphere with hydrophobic surfaces

Fluorescent microspheres for the measurement of blood flow are provided. The microspheres are substantially uniform in diameter and have a hydrophobic surface, which allows them to circulate more freely throughout bloodstream, while reducing immunogenicity, particle aggregation and bioaccumulation. The hydrophobic surface on each microsphere is generally comprised of polymeric material having a limited surface charge.
Owner:LIFE TECH CORP

Fluorine-containing polyether graft modified aqueous polyurethane and preparation and application thereof

The present invention relates to a fluorine-containing polyether grafting modified waterborne polyurethane, the preparation and the application thereof, a structural general formula of polyurethane is as the formula, wherein, R1 is equal to a polyurethane soft-segment polyol structure, R2 is equal to a polyurethane hard-segment isocyanate structure, R3 is equal to a polyurethane hard-segment chain extender structure, R4 is equal to the fluorine-containing polyether; X is equal to NH and O; the preparation is that: the polyol and the isocyanate react to compound the polyurethane prepolymer, then the waterborne polyurethane are obtained through the chain propagation of a chain extender, then the waterborne polyurethane and the fluorine-containing polyether are carried out a grafting reaction in the big molecules, so as to synthesize the fluorine-containing polyether grafting modified waterborne polyurethane; the application is that: the present invention can be applied to aerospace, aviation, automobiles, electronics, textiles, carpets, leathers, paper making, packaging, washing, machinery, construction and other fields. The present invention adopts the water as the solvent and has no formaldehyde, no or low VOC emission, no bioaccumulation and no toxicity, which is a multifunctional, green, environment protective, water-proof and dirt-proof coating layer and fabric finishing agent.
Owner:DONGHUA UNIV

Method for preparing fluorine-containing acrylate

The invention belongs to the technical field of textile fabric finishing agents, and relates to a method for preparing an intermediate fluorine-containing acrylate monomer of a water-proof and oil-proof organic fluorine fabric finishing agent. The method is characterized by comprising the following steps of: (1) in the presence of a reducing agent, preparing polyfluoroalcohol by using a perfluoroalkylacyl compound as a raw material; and (2) slowly dripping (methyl) acryloyl chloride to prepare fluorine-containing acrylate in the presence of a catalyst by using the polyfluoroalcohol prepared in the step (1) and using phenothiazine as a polymerization inhibitor. The number of long-chain perfluoroalkyl carbon atoms in the prepared fluorine-containing acrylate is less than 8, and the fluorine-containing acrylate can be degraded and has no biological accumulation. The fluorine-containing acrylate has no hidden dangers of long-chain perfluoroalkyl to destroy the environment and harm human health. Fluorine-containing acrylate copolymer emulsion prepared by using the prepared fluorine-containing acrylate monomer is used as a water-proof and oil-proof finishing agent for textiles, and the finished textiles have excellent water-proof and oil-proof performance.
Owner:江苏梅兰化工有限公司

Acrylate polymer integrating water and oil repellence with flame retardancy, and preparation and application thereof

The invention relates to an acrylate polymer integrating water and oil repellence with flame retardancy, which has the structural formula shown as the figure, and preparation and application thereof. The preparation of the acrylate polymer comprises the steps: at first, chlorine alkyl phosphate and alkyl alcohol amine are subject to ammonolysis reaction under certain conditions, the resultant alcohol is further subject to esterification reaction with acryloyl chloride at low temperature to prepare acrylate derivative consisting of phosphorus and nitrogen units, and finally the acrylate derivative, fluorine-containing acrylate, crosslinking monomer and long-chain acrylate monomer are subject to polymerization through emulsion. The acrylate polymer according to the invention can be diluted with water at any ratio, has no bioaccumulation toxicity, no or low VOC discharging and no formaldehyde and other harmful substances, and is an environmentally friendly, green, pollution-free water / oil-resisting antifouling flame-retardant finishing agent with high performance; in addition, the acrylate polymer not only can be used for the flame-retardant finishing of fabrics, but also has excellent water and oil repellence and eco-friendliness.
Owner:DONGHUA UNIV

Preparation of environmentally acceptable scale inhibitors

Alkyl phosphonates prepared from amino acids suitable for use in inhibiting scale. The phosphonates are obtained as reaction mixtures where the level of alkyl phosphonation is deliberately controlled to provide only partial alkyl phosphonation of the amino acid. The resulting alkyl phosphonates exhibit improved environmental properties compared to the fully substituted species, while still exhibiting acceptable efficacy in the control of scale. The compositions possess advantages over existing phosphonates in that they exhibit higher biodegradation by method OECD 306. They also offer lower toxicity to marine life compared to the fully substituted species and are not expected to bioaccumulate.
Owner:CHAMPIONX USA INC

Dietary Supplement For Promoting Removal Of Heavy Metals From The Body

A dietary supplement for removing or preventing the bio-accumulation of heavy metals in the body includes one or more chelators, precursors therefore, with at least one chelator capable of crossing the blood brain barrier to promote capture of a heavy metal ion from a site in the central nervous system, and a vascular system promoter for assisting in distributing the chelators within the body. The chelator then crosses back through the blood brain barrier with the entrained heavy metal ion. Preferably, one or more secondary chelators promotes binding any of the heavy metal released from the primary chelator and hold it for removal via an excretion pathway. In one embodiment, the supplement includes a cilantro extract to assist the body's' natural defense systems in removing mercury from the human body. Using the dietary supplement limits the accumulation of heavy metals in the body, which are encountered in trace amounts from various environmental sources, promotes removal of heavy metals previously accumulated in the body and thereby alleviates the symptoms and conditions associated with heavy metal toxicity.
Owner:COLEMAN HENRY D +2

Comprehensive remediation method for soil polluted by heavy metals and application of comprehensive remediation method

InactiveCN105945047AReduce the total amount of heavy metalsNo pollution in the processContaminated soil reclamationMaggotSoil science
The invention discloses a comprehensive remediation method for soil polluted by heavy metals and application of the comprehensive remediation method. The comprehensive remediation method comprises the following steps of arranging an enclosing wall around the soil polluted by the heavy metals, supplying water to the soil through a water pipeline, and cultivating aquatic plants with better metal absorbency; taking out the aquatic plants, draining excessive water, enabling the soil to ventilate, and naturally drying in the air; planting plants with better absorbency to the heavy metals, pruning stems and leaves of plants at fixed period when the stems and leaves of the plants over grow, accelerating vegetative growth of the plants, and completely digging out root systems of the plants after a growing period; introducing earthworms, and watering during the period; digging out a plurality of grass pits in the soil, wherein the space between every two adjacent grass pits is 2 to 3m; cultivating maggots by adopting a straw insect rearing method, and using the maggots to purify residual heavy metals in the soil, wherein the maggots become adults and then fly away; and adopting phytoremediation, earthworm bioaccumulation and maggot bioaccumulation at the same time. According to the comprehensive remediation method, which is a soil remediation method, disclosed by the invention, the total amount of the heavy metals in the soil can be effectively reduced, and no pollution and damage to a site proposed to be remediated are caused; and the method is environmentally friendly.
Owner:ZHONGSHAN LVLANG ADDITIVES CO LTD

Polyfluoroalkylphosphonic acid, method for producing the same and mold-releasing agent comprising the same as active ingredient

Disclosed is a polyfluoroalkylphosphonic acid represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2, wherein n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3, or a salt thereof, which is a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and being usable as an active ingredient of a mold-releasing agent. The polyfluoroalkylphosphonic acid is produced by hydrolyzing a polyfluoroalkylphosphonic acid diester represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OR)2, wherein R is a C1-C4 alkyl group, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3.
Owner:UNIMATEC CO LTD

Polyfluoroalkylphosphonic acid, method for producing the same and mold-releasing agent comprising the same as active ingredient

Disclosed is a polyfluoroalkylphosphonic acid represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2, wherein n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3, or a salt thereof, which is a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and being usable as an active ingredient of a mold-releasing agent. The polyfluoroalkylphosphonic acid is produced by hydrolyzing a polyfluoroalkylphosphonic acid diester represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP (O)(OR)2, wherein R is a C1-C4 alkyl group, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3.
Owner:UNIMATEC CO LTD

Streptomycete S1-5 and uses thereof

The invention provides a new bacterial strain that can prevent and control plant pathogenic fungi and kill acarids—streptomyces S1-5 and its application in resisting plant pathogenic fungi and killing acarids. Streptomyces sp.S1-5 (Streptomyces sp.S1-5), preserved in China Center for Type Culture Collection, date of preservation: May 24, 2007, preservation number CCTCC No: M 207073. The pesticide prepared by the present invention can achieve the effect of killing fungicides and killing acarids by using it once, greatly reducing agricultural costs and lightening the burden on farmers; and the duration of effect is as long as 30 days, and it is also safe for humans and animals, does not kill natural enemies and is beneficial Insects are not easy to produce resistance to control objects, do not pollute the environment, can be rapidly degraded by soil microorganisms without affecting soil fertility and microbial flora, have no bioaccumulation, and are very safe for ecology. They are a key enzyme inhibitor. Pesticides, no cross-resistance with other insecticides.
Owner:ZHEJIANG UNIV OF TECH

Emulsion and mold-releasing agent using the same

Disclosed is an emulsion formed using, as an emulsifier, 0.01 to 30 parts by weight of a perfluoroalkylethyl phosphonic acid salt represented by the general formula: CnF2n+1CH2CH2P(O)(OM1)(OM2) [III] (M1: a hydrogen atom, ammonium salt, or organic amine salt, M2: an ammonium salt or organic amine salt, n: 1 to 6), based on 100 parts by weight of a perfluoropolyether oil represented by the general formula: RfO(C3F6O)p(C2F4O)q(CF2O)rRf′ [I] (Rf and Rf′: C1-C5 perfluoroalkyl groups, p+q+r: 2 to 200) or the general formula: F(CF2CF2CF2O)nCF2CF3 [II] (n: 2 to 100), or a perfluorocarbon compound. In spite of using, as an emulsifier, a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, the emulsion exhibits excellent emulsification stability, and therefore can be effectively used as a surface-treating agent, such as a mold-releasing agent.
Owner:UNIMATEC CO LTD

Mold-releasing agent

Disclosed is a mold-releasing agent comprising, as active ingredients, a graft copolymer (A) in which a polyalkylene glycol or an alkyl ether thereof is graft-copolymerized with a polyfluoro-1-alkene represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)bCH═CH2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3), and a polyfluoroalkylphosphonic acid represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3, and c is an integer of 1 to 3) or a salt thereof (B). The mold-releasing agent comprises, as an active ingredient, a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and having mold release performance equivalent to or more than that of a mold-releasing agent comprising a compound having a perfluoroalkyl group containing 8 or more carbon atoms as an active ingredient.
Owner:UNIMATEC CO LTD

Method for improving the environmental impact of formulated products

Disclosed are methods for developing a product having a relatively benign environmental impact. The methods evaluate the environmental hazard of various chemical components in formulated products and identify improvements in environmental safety based on those evaluations. Environmental criteria are in part developed based on three factors including; persistence, bioaccumulation and toxicity. One method includes obtaining a preliminary formula for a product, wherein the preliminary formula includes a plurality of chemical components, identifying at least one different chemical component that is capable of being substituted for the chemical component in the preliminary formulation and determining an environmental performance score for the chemical component and the different chemical component and determining an environmental performance score of the preliminary formula and a second formula, wherein the second formula utilizes the different chemical component. The formula having the highest environmental performance score is selected as the product. A second method includes tracking the use of chemical components in an existing product portfolio offered or sold by a business unit or a company, in which existing products having the lowest environmental performance scores would be targeted for replacement by reformulated products having higher environmental scores in order to improve the environmental performance of the business unit or company.
Owner:JOHNSON & JOHNSON CONSUMER COPANIES

Hydraulic fluid compositions

A novel hydraulic fluid composition for application to drilling equipment is described herein. These hydraulic fluid compositions permit effective monitoring or controlling well-head pressure of a well during drilling on land or offshore. The hydraulic fluid compositions prevent uncontrolled flow of gas, oil, or another well fluid out of an underground formation during a drilling or extraction process when applied to the drilling equipment. Accordingly, provided is a hydraulic fluid concentrate which contains a water-soluble phosphate ester and a sulfide compound containing at least one S—S linkage, at least 10 carbon atoms and at least one terminal carboxylate group, wherein the S—S linkage bridges two alkyl groups. Additional components can be added to the concentrate and include one or more alkaline compound, one or more dicarboxylic acid or salt thereof, a water-soluble corrosion inhibitor, a water-soluble biocide, a pour point depressant, and water, ethylene glycol, or a combination thereof. The concentrate is then further diluted by the customer for use as described herein. Particularly, these compositions are effective in reducing seawater corrosion of a metal in contact with the hydraulic fluid composition, reducing bioaccumulation in oil drilling equipment contacted with the hydraulic fluid composition, and have low toxicity to sea life.
Owner:HOUGHTON TECH CORP

Determining method for aquatic organism protection water quality standard of bioaccumulation substance

The invention belongs to the technical field of water quality protection, and particularly relates to a determining method for an aquatic organism protection water quality standard of a bioaccumulation substance. The method includes the following steps of collecting and screening toxicity data NOED; obtaining the optimal fitted equation through fitting; obtaining a reference value BTC based on tissue through the optimal fitted equation; obtaining an aquatic organism protection water quality criteria WQC of the bioaccumulation substance; obtaining predicted environment concentration PEC; determining the aquatic organism protection water quality standard WQS of the bioaccumulation substance. The aquatic organism protection water quality standard WQS of the bioaccumulation substance can be scientifically determined, the aquatic ecosystem of China can be protected more scientifically, and a new thought and method are provided for formulating the water quality standard in China.
Owner:CHINESE RES ACAD OF ENVIRONMENTAL SCI

Sequestering polycyclic aromatic hydrocarbons in asphalt

This invention is based upon the discovery that activated carbon can be used to sequester polycyclic aromatic hydrocarbons that may be present in asphalt and creosote compositions. The treatment of asphalt and creosote compositions with activated carbon accordingly reduces the level of free polycyclic aromatic hydrocarbons in such compositions by sequestering them therein or removing them from the composition. After being sequestered the polycyclic aromatic hydrocarbons remain trapped in the asphalt or creosote composition, and are not available to the environment during normal processing into useful industrial products. This sequestration reduces the risk of exposing humans and the environment to the polycyclic aromatic hydrocarbons which would otherwise be free to migrate from the asphalt or creosote product during manufacturing and the service life of the product. In other words, the polycyclic aromatic hydrocarbons are absorbed onto the activated carbon and are not available for bioaccumulation from the environment.
Owner:FLOW POLYMERS

Environmentally-friendly durable water repellent fabric and processing method thereof

The invention discloses an environmentally-friendly durable water repellent fabric and a processing method thereof. A water repellent layer contains at least one of a polyurethane treelike macromolecular structure unit and an aliphatic paraffin structure. The fabric has the advantages of high water repellency, air permeability, washability, abrasion resistance, no use of fluoride-containing waterrepellent, no edge substances such as perfluorooctanoic acid (PFOA) and perfluorooctane sulfonates (PFOS) and precursor substances thereof, no biological accumulation and no production of fluoride-containing gas and belongs to a high-performance environmentally-friendly water repellent fabric.
Owner:TORAY FIBER RES INST(CHINA) CO LTD

Method for improving the environmental impact of formulated products

Disclosed are methods for developing a product having a relatively benign environmental impact. The methods evaluate the environmental hazard of various chemical components in formulated products and identify improvements in environmental safety based on those evaluations. Environmental criteria are in part developed based on three factors including; persistence, bioaccumulation and toxicity. One method includes obtaining a preliminary formula for a product, wherein the preliminary formula includes a plurality of chemical components, identifying at least one different chemical component that is capable of being substituted for the chemical component in the preliminary formulation and determining an environmental performance score for the chemical component and the different chemical component and determining an environmental performance score of the preliminary formula and a second formula, wherein the second formula utilizes the different chemical component. The formula having the highest environmental performance score is selected as the product. A second method includes tracking the use of chemical components in an existing product portfolio offered or sold by a business unit or a company, in which existing products having the lowest environmental performance scores would be targeted for replacement by reformulated products having higher environmental scores in order to improve the environmental performance of the business unit or company.
Owner:JOHNSON & JOHNSON CONSUMER COPANIES

Perspiration and odor control compositions

The present disclosure is directed to a cosmetic composition for controlling perspiration and odor. Despite being free of volatile silicones—which have garnered a bad reputation due to their ecotoxicity and bioaccumulability in aquatic species—the composition of the instant disclosure replicates the textural and sensorial benefits provided by the use of volatile silicones like cyclotetrasiloxane, cyclopentasiloxane and cyclohexasiloxane.
Owner:LOREAL SA

Sulfenamide, vulcanization accelerator containing the sulfenamide for rubber, and process for producing the vulcanization accelerator

A sulfenamide vulcanization accelerator is provided that acts satisfactorily slowly on a vulcanization reaction, produces no carcinogenic nitrosamine, and is free from environmental hygiene problems such as bioaccumulation. Also provided is an N-alkyl-N-t-butylbenzothiazole-2-sulfenamide represented by formula [I]. The vulcanization accelerator is a vulcanization accelerator for rubber, containing this compound. Furthermore provided is a process for producing the vulcanization accelerator.wherein R represents methyl, ethyl, n-propyl, or n-butyl.
Owner:OUCHI SHINKO CHEM IND

Method for removing green alga in nori cultivation process

The invention relates to a method for restraining green alga growth, in particular to a method for removing green alga in the nori cultivation process. Firstly, algaecide is prepared, wherein solid sodium percarbonate is dissolved in deionized water, so that sodium percarbonate treating fluid is prepared, and the pH value of the treating fluid is between 9 and 10; the prepared algaecide is directly sprayed on green alga bodies attached to a net curtain, a whole raft frame and a whole mooring rope in the nori cultivation process 2 hours before a flood tide and the algaecide is sprayed once every 1 to 3 months. According to the method for removing the green alga in the nori cultivation process, the sodium percarbonate serves as the algaecide and is free of toxin, odor and pollution, high in water solubility, convenient to prepare, free of harm to the environment and free of biological accumulation. The method for removing the green alga in the nori cultivation process is very simple and convenient to achieve, the use cost is low, rinse is not required, and the method is slightly influenced by natural conditions and can be used in a large scale. Three days later after the algaecide is sprayed, the removal rate of the green alga is 100%, and the growth of the nori is not influenced.
Owner:SHANGHAI OCEAN UNIV

Preparation method of polymerizable non-ionic fluorine-containing short chain surfactant

The invention discloses a preparation method of a polymerizable non-ionic fluorine-containing short chain surfactant. The surfactant is obtained in the modes that firstly, short-chain fluorol and isophorone diisocyanate react in the same mole ratio to obtain an intermediate I with a monoisocyanate group, then the intermediate I is coupled with polyethylene glycol in the same mole ratio to obtain an intermediate II with monohydroxyl, then the intermediate II is coupled with isophorone diisocyanate in the same mole ratio to obtain an intermediate III with one end provided with an isocyanate group, and finally the intermediate III and hydroxyalkyl acrylate generate a coupling reaction in the same mole ratio. The preparation method has the advantages that the surfactant has polymerization andhigh surfactivity, meanwhile, a short fluorine-carbon chain in the surfactant enables the surfactant to have the low bioaccumulation, a polyurethane structure enables the surfactant to have good later-period environmental degradation, organic solvents are not used in the synthesis process, and thus environmental friendliness is achieved; and the surfactant can be used as a waterproof and oil-proofassistant, a coating leveling agent and the like, and has wide application prospects.
Owner:SICHUAN UNIV

Method for controlling nitrogen leaching loss of farmland

The invention relates to a method for controlling nitrogen leaching loss of farmland, and belongs to the technical field of agricultural environment protection. The characteristic that plant root systems are distributed in different layers is utilized, plants with the deep root systems and the high nitrogen bioaccumulation capacity are selected as nitrogen pumping plants to absorb excessive nitrogen in deep soil, and meanwhile the root systems of the nitrogen pumping plants are bound with a root binding device, so that the condition that the nitrogen pumping plants compete for the nitrogen with plants to be planted in shallow soil is avoided, and then not only is the normal agricultural production process guaranteed, but also the influences of the nitrogen on the soil ecological environment are avoided. According to the method, the soil environment is improved, pollution to the environment is reduced, ecological protection on the farmland and sustainable agriculture development are promoted, and the method is easy to operate and high in benefit and has a wide application prospect.
Owner:孙新磊

Fluorine-containing polymer aqueous dispersion

ActiveUS20130079466A1Low bioaccumulation potentialImprove performanceHydrogen atomMechanical stability
Disclosed is a fluorine-containing polymer aqueous dispersion in which a fluorine-containing polymer is dispersed using, as an emulsifier, a polyfluoroalkylphosphonic acid salt represented by the general formula:CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OM1)(OM2)  [I],wherein M1 is a hydrogen atom, an alkali metal, an ammonium base, or an organic amine base, M2 is an alkali metal, an ammonium base, or an organic amine base, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3. This fluorine-containing polymer aqueous dispersion uses a polyfluoroalkylphosphonic acid salt with a low bioaccumulation potential as an emulsifier, and has excellent mechanical stability.
Owner:UNIMATEC CO LTD
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