The invention discloses a thermal activation delayed
fluorescence material based on a dibenzophenazine derivative as well as a preparation method and application of the thermal activation delayed
fluorescence material, and belongs to the technical field of organic photoelectric materials and devices. The
structural formula of the material is shown as a formula (I), in the formula (I), R1 is phenoxazinyl, phenothiazinyl or dimethyl acridinyl, R1' is phenoxazinyl, phenothiazinyl or dimethyl acridinyl, R1 '' is phenoxazinyl, phenothiazinyl or dimethyl acridinyl, and R2 is H, phenoxazinyl, phenothiazinyl or dimethyl acridinyl. The material provided by the invention has the advantages that the
electron acceptor and the
electron donor unit show a highly distorted
rigid structure, 100% theoretical internal
quantum efficiency can be realized, the
fluorescence quantum yield is high, a guarantee is provided for a high-efficiency long-waveband
OLED device, and the like. And a polysubstitution mode is adopted, so that
red shift of molecular emission
wavelength is facilitated, long-waveband
luminescence is realized, and a guarantee is provided for an efficient long-waveband
OLED device.