2046results about "Aluminium compounds" patented technology

Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.

Liquid feed flame spray pyrolysis of solutions of a metal oxide precursor which is an alkoxide or C1-6 carboxylate and at least one second metal oxide precursor and / or second metal compound dissolved in oxygenated solvent by combustion with oxygen lead to the formation of sub-micron mixed-metal oxide powders not accessible by other processes or by the pyrolysis of metal chlorides or nitrates. The powders have numerous uses in advanced materials applications including particulate solid state lasers, advanced ceramic materials, and as catalysts in organic synthesis and automobile exhaust systems.

This invention relates to a high activity ZSM-48. More particularly, a high activity ZSM-48 with defined purity is prepared, the ZSM-48 being free of non-ZSM-48 seed crystals and ZSM-50.

The present invention relates to a method of preparing a microporous crystalline molecular sieve having mesoporous skeleton, comprising following steps: (a) adding a meso-SDA (meso-Structure Directing Agent) into a gel composition of synthesizing molecular sieve, (b) subjecting the mixture obtained in the above step (a) to crystallization by a hydrothermal reaction, a microwave reaction, a dry-gel synthesis, etc., and (c) removing selectively organic materials from the resulted material obtained in the above step (b) by a calcination or a chemical treatment. Molecular sieve having mesoporous skeleton synthesized by the present invention exhibits, as compared with conventional zeolite, a good molecule diffusion ability and a greatly improved catalytic activity.

The invention, in one embodiment, is a method for preparing crystalline zeolites by (a) contacting a calcined essentially aluminum free borosilicate zeolite with an aqueous acid solution, thereby producing an at least partially deboronated zeolite; (b) contacting said at least partially deboronated zeolite with a solution selected from the group consisting of an aqueous aluminum salt solution, thereby producing an aluminosilicate zeolite; an aqueous gallium salt solution, thereby producing a gallosilicate zeolite; an aqueous iron salt solution, thereby producing a ferrosilicate zeolite; and mixtures thereof; and (c) where the contacting in step (b) occurs at a pH of not greater than about 3.5. In another embodiment, the present invention provides a method for preparing crystalline zeolites by contacting a calcined essentially aluminum free large or extra-large pore borosilicate zeolite with a solution selected from the group consisting of an aqueous aluminum salt solution, thereby producing an aluminosilicate zeolite; an aqueous gallium salt solution, thereby producing a gallosilicate zeolite; an aqueous iron salt solution, thereby producing a ferrosilicate zeolite; and mixtures thereof; and where the contacting occurs at a pH of not greater than about 3.5.

A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its calcined, anhydrous form, has a composition involving the molar relationship:(n)X2O3:YO2,wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to about 0.5. The material exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.

The subject invention comprises a novel UZM-14 catalytic material comprising globular aggregates of crystallites having a MOR framework type with a mean crystallite length parallel to the direction of 12-ring channels of about 60 nm or less and a mesopore volume of at least about 0.10 cc / gram. Catalysts formed from the novel material are particularly effective for the transalkylation of aromatics.

A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO4-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.