The invention discloses a directional conversion system for organosilicon high-boiling mixed liquid, which comprises a directional oxidation conversion device, a high-temperature oxidation chamber, an oxygen-supplementing air heat exchanger, a high-temperature too-cotton catcher, a waste heat recovery device, and a quenching hydrochloric acid absorption tower arranged in sequence , Hydrogen chloride absorption tower first / secondary, chlorine oxidation tower, alkali washing tower, smoke exhaust fan, activated carbon filter, exhaust pipe. The invention adopts directional oxidation conversion device, high-temperature oxidation chamber, oxygen-supplementing air heat exchanger, high-temperature too-cotton trap, waste heat recovery device, quenching hydrochloric acid absorption tower, hydrogen chloride absorption tower first / secondary, chlorine oxidation tower, alkali washing tower, etc. Gradually carry out directional transformation and treatment of organosilicon high-boiling mixed liquid. The separated silica, hydrochloric acid and other products are all qualified industrial products and can be used industrially. All are advanced, reliable, economical and reasonable, can effectively reduce operating costs, and realize material recycling and energy recovery.