2201 results about "Hydrosilylation" patented technology

A composition for personal, home, or laundry treatment comprising a polymer made up of one or more crosslinked rake or comb silicone copolymer segments. A process for making copolymers for use in such compositions involves hydrosilylation in the presence of a catalyst.

A composition is prepared by mixing components including: (I) a polyorganosiloxane having an average of at least two unsaturated organic groups per molecule, with the proviso that component (I) is free of fluorine atoms; optionally (II) an organohydrogenpolysiloxane having an average of at least two silicon-bonded hydrogen atoms per molecule, with the proviso that component (II) is free of fluorine atoms; (III) a hydrosilylation catalyst; (IV) a fluoroorganosilicone, with the provisos that (1) component (IV) has at least one functional group reactive with component (I), component (II), or both, (2) when component (II) is not present, then component (IV) has an average of at least two silicon-bonded hydrogen atoms per molecule, and (3) component (IV) is added to the composition in an amount sufficient to provide chemical resistance to a cured product of the composition; and (V) an adhesion promoter.

A method of making a light emitting device is disclosed. The method includes providing a light emitting diode and forming an encapsulant in contact with the light emitting diode; wherein forming the encapsulant includes contacting the light emitting diode with a photopolymerizable composition consisting of a silicon-containing resin and a metal-containing catalyst, wherein the silicon-containing resin consists of silicon-bonded hydrogen and aliphatic unsaturation, and applying actinic radiation having a wavelength of 700 nm or less to initiate hydrosilylation within the silicon-containing resin.

A hydrosilylation process is used to prepare a polyorganosiloxane having clustered functional groups at the polyorganosiloxane chain terminals. The ingredients used in the process include a) a polyorganosiloxane having an average of at least 2 aliphatically unsaturated organic groups per molecule, b) a polyorganohydrogensiloxane having an average of 4 to 15 silicon atoms per molecule and at least 4 silicon bonded hydrogen atoms for each aliphatically unsaturated organic group in ingredient a), c) a reactive species having, per molecule at least 1 aliphatically unsaturated organic group and 1 or more curable groups; and d) a hydrosilylation catalyst. The resulting clustered functional polyorganosiloxane is useful in a curable silicone composition for electronics applications.

Compositions and methods for the in situ formation of hydrosilylation (addition) cross-linked organosiloxane films are disclosed. The disclosed films are long-lasting, flexible, transfer-resistant, and water-proof. The film-forming compositions generally comprise alkoxy-terminated organosiloxane polymers and a catalyst and are useful for formulating cosmetics and personal care products.

Disclosed herein are manganese, iron, cobalt, or nickel complexes containing terdentate pyridine diimine ligands and their use as efficient and selective hydrosilylation catalysts.

A composition includes: (I) an alkenyl functional, phenyl-containing polyorganosiloxane, an Si—H functional phenyl-containing polyorganosiloxane, or a combination thereof; (II) a hydrogendiorganosiloxy terminated oligodiphenylsiloxane having specific molecular weight, an alkenyl-functional, diorganosiloxy-terminated oligodiphenylsiloxane having specific molecular weight, or a combination thereof; and (III) a hydrosilylation catalyst. A light emitting device is made by applying the composition onto a light source followed by curing. The composition provides a cured material with mechanical properties suited for use as an encapsulant for a light emitting device.

The invention relates to a process for the transition metal-catalyzed addition of SiH-containing poly-siloxanes onto olefinic compounds, wherein the catalyst used is a combination of at least two compounds of platinum metals, and also to a corresponding catalyst system.

A hydrosilation processing a silicon hydride with an unsaturated reactant in the presence of a supported bimetallic catalyst comprising an active hydrosilating metal such as platinum in elemental or compound form, and a surface segregating metal such as copper in elemental or compound form on a support.

A solventless cured release coating-forming organopolysiloxane composition having a viscosity at 25° C. of 50 to 2,000 mPa·s comprising (A) 100 weight parts of an alkenyl-functional diorganopolysiloxane that has a viscosity of 25 to 1,000 mPa·s; (B) 0.5 to 15 weight parts of a diorganopolysiloxane that has a viscosity of at least 10,000 mPa·s and that has an aliphatically unsaturated group content of no more than 0.1 mole %; (C) 0.5 to 5 weight parts of a branched organopolysiloxane that has more than one SiO4 / 2 unit and that is a polymer product provided by an equilibration polymerization between a branched organosiloxane oligomer represented by the average siloxane unit formula (1) (SiO4 / 2)(RaRb2SiO1 / 2)x(1) and a diorganosiloxane oligomer; (D) a specific amount of an organohydrogenpolysiloxane that has a viscosity of 1 to 1,000 mPa·s; and (E) a hydrosilylation reaction catalyst in a catalytic quantity.

Disclosed herein are metal-terpyridine complexes and their use in hydrosilylation reactions.

A primer composition for a fluorinated elastomer or a fluorinated gel, said primer composition comprising:100 parts by weight of (a) a linear perfluoro polyether compound having at least two alkenyl groups per molecule, a perfluoro polyether backbone having repeating units represented by the formula, —CaF2aO—, wherein a is an integer of from 1 to 6, and a weight average molecular weight of from 5,000 to 100,000,(b) an organosiloxane compound having one or more fluorine atom and at least two SiH bonds per molecule, in such an amount that a molar ratio of the SiH bond in the organosiloxane compound to the alkenyl group in Component (a) ranges from 0.8 to 5.0,a catalytic amount of (c) a hydrosilylation catalyst,5 to 100 parts by weight of (d) an organosiloxane compound having, per molecule, at least one SiH bond and at least one epoxy group and / or trialkoxysilyl group bonded to a silicon atom of said organosiloxane via an organic group which may have an oxygen atom, and100 to 10000 parts by weight, per total 100 parts by weight of said components (a), (b), (c) and (d), of (e) an organic solvent having a fluorine atom and a boiling point of not higher than 150° C. at atmospheric pressure.

A composition includes: (I) an alkenyl functional, phenyl-containing polyorganosiloxane, an Si—H functional phenyl-containing polyorganosiloxane, or a combination thereof; (II) a hydrogendiorganosiloxy terminated oligodiphenylsiloxane having specific molecular weight, an alkenyl-functional, diorganosiloxy-terminated oligodiphenylsiloxane having specific molecular weight, or a combination thereof; and (III) a hydrosilylation catalyst. A light emitting device is made by applying the composition onto a light source followed by curing. The composition provides a cured material with mechanical properties suited for use as an encapsulant for a light emitting device.

A thermal interface material composition including a blend of a polymer matrix and a thermally conductive filler having particles having a maximum particle diameter no greater than about 25 microns, wherein the polymer matrix includes an organopolysiloxane having at least two silicon-bonded alkenyl groups per molecule, an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms per molecule and a hydrosilyation catalyst comprising a transition metal, wherein the transition metal is present in an amount of from about 10 to about 20 ppm by weight based on the weight of the non-filler components and the molar ratio of the silicon-bonded hydrogen atoms to the silicon-bonded alkenyl groups ranges from about 1 to about 2. A method is also provided.

An asymmetric siloxane is made by reacting a silicone having the formula MHDxM′H where MH is R1R2HSiO1 / 2, M′H is R4R5HSiO1 / 2 and x is an integer 0≦x≦10 under selective hydrosilylation conditions in the presence of a precious metal hydrosilylation catalyst, with a first olefine compound and in a second step, a monohydridosiloxane produced in the first step is reacted under hydrosilylating condtions with another olefine compound different from the first olefine compound.

Branched copolymers of polypropylene (PP) and polysilanes are prepared by procedures involving melt phase hydrosilylation. Such branched copolymers may be formed in situ during the melt phase hydrosilylation or may be prepared by subsequent processing. The branched copolymers exhibit superior properties.

A curable silicone composition comprising at least the following components: (A) a diorganopolysiloxane having in one molecule at least two alkenyl groups; (B) at least two resin-like organopolysiloxanes that have different mass-average molecular weights as reduced into standard polystyrene measured gel permeation chromatography and that are composed of SiO4 / 2 units, R12R2SiO1 / 2 units, and R13SiO1 / 2 units, wherein R1 is an optionally substituted univalent hydrocarbon group that is free of aliphatic unsaturated bonds and R2 is an alkenyl group; (C) an organopolysiloxane that contains in one molecule at least two silicon-bonded hydrogen atoms; and (D) a hydrosilylation catalyst; possesses excellent flowability and filling ability and that can be prepared without extreme viscosity even if the composition contains resin-like organopolysiloxanes required to form a cured silicone body of appropriate strength and hardness.

The present invention provides a curable composition providing a curing product having excellent adhesive properties and high transparency, or a curing product having high toughness and transparency. A curable composition which contains (A) an organic compound containing at least two carbon-carbon double bonds reactive with a SiH group in each molecule, (B) a silicon compound having at least two SiH groups in each molecule, (C) a hydrosilylation catalyst, (D) a silane coupling agent and / or an epoxy group-containing compound, and (E) a silanol condensation catalyst. A light-emitting diode sealed with a curing product obtainable by curing said curable composition.

Linear organopolysiloxanes containing alpha, omega terminal Si bonded omega-alkenyl groups or alpha, omega Si bonded H are prepared via hydrosilylation.

The invention relates to self-adhesive addition-crosslinking silicone compositions which comprises(A) diorganopolysiloxanes, (B) organohydrogenpolysiloxanes containing less than 20 SiH bonded hydrogen atoms and less than 12% aryl groups, (C) organosilicon compounds having epoxy groups and hydrolyzable groups and (D) a hydrosilylation catalyst. The compositions are transparent to translucent, exhibit good compositional comparability, and cure to form strongly adhesive elastomers with good physical properties.

Disclosed herein is the use of manganese, iron, cobalt, or nickel complexes containing tridentate pyridine di-imine ligands as hydrosilylation catalysts. These complexes are effective for efficiently catalyzing hydrosilylation reactions, as well as offering improved selectivity and yield over existing catalyst systems.

Silicone polyethers and a process for preparation thereof wherein polyethers modified laterally with methylidene groups are reacted with hydrosiloxanes in a hydrosilylation reaction.

A continuous method for performing a hydrosilylation reaction comprising effecting a hydrosilylation reaction between a liquid organosilicon compound (A) having in each molecule at least one silicon-bonded hydrogen atom and a liquid organosilicon compound (B) having in each molecule at least one aliphatic unsaturated bond in the presence of a platinum catalyst (C) continuously in a tubular reactor equipped with a stirring and plug-flow maintaining apparatus located within the reactor.

The invention provides a transparent adhesive sheet for flat panel display, which shows superior level difference absorbability and does not develop bubbles in the adhesion surface to a plastic plate. The transparent adhesive sheet for flat panel display is made of a cured product of a composition comprising (A) a polyoxyalkylene based polymer having at least one alkenyl group in one molecule, (B) a compound having an average of not less than 2 and less than 5 hydrosilyl groups in one molecule, and (C) a hydrosilylation catalyst, wherein the transparent adhesive sheet has a shear storage elastic modulus (G′) of not more than 1.0×105 Pa at 25° C. and 1 Hz, and a gel fraction of not less than 40%.

Hydrophilic siloxane copolymers are prepared by(a) reacting organopolysiloxanes having at least one Si-bonded hydrogen atom with substantially linear oligomeric or polymeric compounds of formulaR1-(A-CnH2n)m-A1-H  (I)where R1 is a monovalent optionally substituted, hydrosilylatable hydrocarbyl radical,A is a bivalent polar organic radical selected from —O—, —C(O)—O—, —O—C(O)—, —O—C(O)—O—, —C(O)—NH—, —NH—C(O)—, urethane radicals and urea radicals,A1 is a bivalent polar organic radical selected from —O—, —NH— and —NR′—, n is an integer from 1 to 20, and m is zero or a positive integer,(b) reacting the resulting intermediate with organic compounds which have two or more isocyanate groups, in the presence of further organic compounds (6) reactive toward isocyanate groups and containing at least one tertiary amine group, and(c) quaternizing the amino-group-containing intermediate from step (b) with an alkylating agent (8),with the proviso that the water content of the compounds (1) and (2) is lower than 2000 weight ppm.

The problem of the present invention is to provide a pressure-sensitive adhesive sheet for skin adhesion, having an adhesive layer, which can be formed without using an organic solvent, shows superior adhesion performance to the skin, and shows extremely mild irritation to the skin and stratum corneum damage. To solve the problem, the present invention provides a pressure-sensitive adhesive sheet for skin adhesion, which has a substrate and an adhesive layer laminated on the substrate, wherein the adhesive layer is obtained by curing an adhesive composition containing polyether polymer (A) having at least one alkenyl group on the terminal, compound (B) having 1-10 hydrosilyl groups in a molecule and hydrosilylation catalyst (C).

A composition includes: (I) a polyorganosiloxane fluid having an average of at least two unsaturated organic groups per molecule, (II) an organohydrogenpolysiloxane having an average of at least two silicon-bonded hydrogen atoms per molecule, (III) a hydrosilylation catalyst; and (IV) a fluoroorganosilicone.

The present invention relates to compositions comprising the components A, a polymer obtainable by the reaction in the sense of a hydrosilylation of a siloxane having SiH functions and vinyl functions with a further unsaturated compound, and D, metal atoms or ions, not equal to silicon, a process for the preparation of these compositions, and the use of the compositions for producing antifoams or as antifoams of liquids, and also for suppressing or reducing the foam formation of foaming liquids, and also for foam destabilization.