The invention provides a composite diaphragm with a
lithium supplementing effect. The composite diaphragm comprises a base membrane, a first
ceramic coating and a second
ceramic coating which are respectively positioned on the upper surface and the lower surface of the base membrane, a
lithium supplementing gel
coating positioned on the upper surface of the first
ceramic coating, and a gel coatingpositioned on the lower surface of the second
ceramic coating. According to the invention, with the
ceramic coating in the diaphragm, the
temperature resistance of the diaphragm is improved, the
thermal shrinkage of the diaphragm is improved, explosion caused by
short circuit due to direct contact between a positive
electrode and a negative
electrode due to diaphragm deformation caused by thermalcontraction of the diaphragm at a high temperature is prevented, the
lithium supplementing gel coating can realize uniform and accurate lithium supplementing of a
silicon-carbon negative
electrode sheet, a
silicon-carbon negative electrode is prevented from being excessively lithiated to cause lithium
precipitation, after lithium supplementing is finished, the gel coating and the electrode sheethave higher bonding force under the action of hot-pressing shaping, and the lithium
ion good conductor
powder remained in the lithium supplementing coating has good
ionic conductivity, so that the conduction of lithium ions is promoted.