The invention discloses a hydroxypolyacrylate
emulsion, and a preparation method and an application thereof. The preparation method comprises the following steps: weighing an
acrylate monomer and / or a metacrylate
monomer, a hydroxyacrylate
monomer, an acrylic monomer, an
acrylate function monomer and a hydroxy
oligomer, uniformly mixing to prepare a monomer mixture, weighing 10-15% of the monomer mixture, and emulsifying by using an emulsifier to prepare a seed pre-
emulsion for later use; and adding the emulsifier,
sodium bicarbonate and deionized water into a reaction kettle, stirring, rising the temperature of a
reaction system, adding an initiator, stabilizing, adding the seed pre-
emulsion in a dropwise manner, stabilizing, adding the remaining monomer mixture and the remaining initiator in a dropwise manner, heating, slaking, cooling, neutralizing, carrying out heat insulation, cooling, and discharging to obtain the hydroxypolyacrylate emulsion. A film made by using an aqueous dual-component
polyurethane coating prepared from the hydroxypolyacrylate emulsion and an aqueous polyisocyanate curing agent has the advantages of high
hardness, high luster and excellent
chemical resistance.