The invention discloses a high absorptivity metal pipe wall anti-corrosion and slag resistance wear-resisting ceramic coating, which comprises main components with proportions by weight: silicon carbide 5-15%, brown fused alumina 10-20%, boron nitride 3-8%, boron carbide 2-8%, zirconia 5-10%, potassium titanate 1-3%, chromium oxide 5-10%, iron oxide 5-10%, ball clay 3-10% and high temperature inorganic binder 30-50%, wherein the total weight of the components is 100%. The granularities of all solid components of the high absorptivity metal pipe wall anti-corrosion and slag resistance wear-resisting ceramic coating are less than or equal to 2 microns, parts of components achieve nanometer scales, and the granularities of the parts of components are less than or equal to 100 nanometers. The high absorptivity metal pipe wall anti-corrosion and slag resistance wear-resisting ceramic coating adopts water as solvent, adopts modified high temperature modified inorganic binder as a film forming matter, and determines the addition of the water according to different construction methods, the construction methods comprises a brush coating and a spraying methods, and the volume density of the high absorptivity metal pipe wall anti-corrosion and slag resistance wear-resisting ceramic coating is in 1650-1850kg / m3. The invention discloses a method for making the high absorptivity metal pipe wall anti-corrosion and slag resistance wear-resisting ceramic coating simultaneously.