2001 results about "Butanedioic acid" patented technology

A method of treating a treatment zone in a well to reduce the permeability of the treatment zone including the steps of: introducing into the treatment zone a water-based treatment fluid comprising: an aqueous silica sol; and a water-soluble chemical activator for gelling the silica sol, wherein the chemical activator is selected from the group consisting of: phytic acid, methylglycinediacetic acid, a water-soluble polyepoxysuccinic acid, salicylic acid, ascorbic acid, tannic acid, and an alkali metal salt or ammonium salt of any of the foregoing; and shutting in treatment zone for at least a sufficient time to allow the treatment fluid to in-situ form a solid gel at a design temperature for the method. Alternatively, a first treatment fluid including the aqueous silica sol and a second treatment fluid including the chemical activator can be introduced into the treatment zone separately, in any order.

The invention provides a method for preparing high base number (TBN400) synthetic calcium alkyl-benzene sulfonate. The method comprises the following steps of: adopting a mixed acid of long-chain linear alkyl-benzene sulfonic acid and high-boiling heavy alkyl-benzene sulfonic acid, calcium oxide and/or calcium hydroxide, low-carbon alcohol, alkaline-earth metal halide or nitrate, and a mixture of alkaline-earth metal alkylphenol or alkaline-earth metal alkylphenate and polyisobutylene succinic anhydride for a neutralization reaction in the presence of a solvent and cutback oil at a temperature of between 40 and 80 DEG C; then, passing through carbon dioxide to a product of the neutralization reaction at a temperature of between 40 and 60 DEG C for a carbonation reaction; and producing high base synthetic alkyl-benzene sulfonate with a total base number (TBN) of 400mgKOH/g by adopting a process of a one-step method. The product is divided into high-base number (TBN400) synthetic alkyl-benzene sulfonate containing chlorine and high-base number (TBN400) synthetic alkyl-benzene sulfonate without the chlorine. The product produced by adopting the method with low viscosity, small turbidity, easy filtration, light color and no skin formation has the advantages of excellent high-temperature detergency, excellent anti-foaming property and excellent heat storage stability.

A process for preparing butanediol polysuccinate able to be fully biodegradated includes such steps as adding butanediol and butanedioic acid to reactor, esterifying reacting at 150-200 deg.C, and vacuum polycondensating at 200-280 deg.C under the existance of catalyst. It is a thermoplastic resin with 100,000 of mass average molecular weight and better mechanical performance.

The invention provides a catalyst for continuously producing butanedioic anhydride by maleic anhydride hydrogenation. The catalyst is a nickel loaded catalyst prepared by an equivalent-volume impregnation method, wherein in the catalyst, the content of nickel is 13 to 20 weight percent, the content of accelerating agent is 1 to 7 weight percent, and a carrier is a composite oxide of SiO2 and Al2O3 or SiO2-Al2O3. A preparation method for the catalyst comprises the following steps: impregnating impregnation solution blended by ammonia water and active metal salt solution on a carrier subjected to baking pretreatment at a temperature between 400 and 800 DEG C by the equivalent-volume impregnation method to form the catalyst through drying, baking and reducing treatment. The catalyst is applied to continuously preparing the butanedioic anhydride by maleic anhydride hydrogenation on a fixed bed reactor, the conversion rate of maleic anhydride is more than or equal to 99.98 percent, and the selectivity of the butanedioic anhydride is more than or equal to 98.85 percent. The catalyst achieves the technical-scale continuous production of the butanedioic anhydride, and has the advantages of high activity, good selectivity, high yield (more than or equal to 98.83 percent) and long service life.

The invention relates to magnetic silicon dioxide microspheres with a nuclear shell and surface anisotropic double functional groups and a preparation method thereof. The preparation method comprises the following steps of: preparing superparamagetic microspheres by a solvothermal process; preparing magnetic microspheres which are coated by silicon dioxide by a sol-gel process; preparing the magnetic silicon dioxide microspheres of which the surface has amino group by taking the magnetic silicon dioxide microspheres as seeds and by the copolycondensation of alkyl ester orthosilicate and a silane coupling agent, and drying the magnetic silicon dioxide microspheres to obtain samples; and by a PICKERING emulsion technology, stabilizing a paraffin/aqueous emulsion system with a micrometer scale by using the aminated magnetic microspheres to form single-layer close packing of the magnetic microspheres on the surface of paraffin spheres, then reacting the amino group on the surface of the magnetic microspheres which is exposed in a liquid phase with succinic anhydride to introduce carboxyl into the partial surface of the microspheres, so that the surfaces of the magnetic microspheres have the anisotropic double functional groups. The obtained magnetic microspheres with the double functional groups have the advantages that: magnetic responsiveness is high; grain size can be controlled between 200 and 800 namometers; and the density of the surface functional groups can be adjusted.

This invention relates to a method for producing succinic acid type culture by animalcule fermentation, especially relating to an animalcule actinobacillus succinogenes SW0580 generating succinic acid by a fermentated sugariness raw material, its preservation number: CGMCC No. 1593 and a method for utilizing said animalcule fermentation to produce succinic acid, in which, said animalcule is the actinobacillus succinogenes separated from the rumen tested and 10-50g/L succinic acid can be produced by anaerobic fermentating 20-100g/L sugariness raw materials.

The invention discloses scaling powder for no-clean lead-free low-silver welding paste. The scaling powder comprises, by weight percentage, 3-13% of active agent, 0.2-1.5% of surface active agent, 0.2-3.0% of emulgator, 3.0-10.0% of thixotropic agent, 3-8% of film-forming agent, 0.1-1% of antioxidant, 0.1-0.5% of corrosion inhibitor and the rest of solvent. The active agent is composed of four or five components in succinic acid, oxalic acid, salicylic acid, glutaric acid, citric acid, adipic acid, lactic acid, benzoic acid, malic acid and triethanolamine. The scaling powder for the no-clean lead-free low silver welding paste does not contain halogen, the corrosion to a circuit board is greatly lowered, the printing quality of the welding paste is good without bridging or turned-down edges, a welding point is good in forming after returning, the brazing connecting defect is greatly lowered, the residue is small without solder balls, the cleaning is not needed, the welding paste is directly used for assembling, the Sn-0.45 Ag-0.68 Cu or Sn-0.3 Ag-0.7 Cu low silver welding paste manufactured by using the scaling powder does not contain the halogen and rosin, the organic chemistry smoke is small, and the pollution to the environment is small.

A biodegradable copolyester (butanediester polysuccinate for example) is prepared from butanedioic acid, butanediol, copolydiol and copolydiacid through copolymerizing to obtain atactic linear copolyester, and condensation.

The invention discloses vehicle high-methanol content gasoline, relates to carbon-containing fuels and solves the problems of difficult low-temperature startup, serious metal corrosion, inadequate power and susceptibility to generating precipitates of the conventional methanol gasoline. The vehicle high-methanol content gasoline comprises the following components in part by volume: 70 to 86 partsof methanol, 14 to 30 parts of gasoline component oil, 0.5 to 1 part of cosolvent, 0.1 to 0.2 part of antiseptic and rubber swelling inhibitor, 0.2 to 0.3 part of detergent and 0.01 to 0.05 part of coloring agent. The cosolvent consists of isobutanol, isopropyl ether, 2-isobutanol and tetrahydrofuran, the antiseptic and rubber swelling inhibitor consists of propargyl alcohol, butanedioic acid, hexakis(dihydrogen phosphate), N-methyl morpholine, cyclohexane and dimethyl phthalate, the detergent consists of normal propyl alcohol, isopropanol, limonene and cyclohexane, and the coloring agent is Sudan IV solution. The vehicle high-methanol content gasoline has high startability, high dynamic performance, high environmental protection performance, obvious anticorrosion effect and high safety.

The invention relates to a 1E-level K1-type halogen-free flame-retardant heat-shrinkable pipe for a nuclear power plant, comprising the following components in parts by weight: 100 parts of vinyl polymer, 5-15 parts of microcapsule red phosphorus, 20-60 parts of aluminium hydroxide, 0.5-3 parts of light stabilizer, 0.5-2 parts of ultraviolet absorber, 4-12 parts of antioxidant and 2-5 parts of lubricant, wherein the light stabilizer is polysuccinic acid (4-hydroxyl-2, 2, 6, 6-tetramethyl-1-pyridine) ester; the ultraviolet absorber is 2-(2'-hydroxyl-3', 5'-ditrimethylacetic phenyl) benzotriazole; and the antioxidant is formed by mixing tetra(beta-(3, 5-ditertbutyl-4-hydroxyl phenyl) propionic acid) tetranhaptanoate and 4, 4'-thioic di(6-tertiary butyl-3-methylphenol) according to the proportion of 1:1. The 1E-level K1-type halogen-free flame-retardant heat-shrinkable pipe for the nuclear power plant does not contain halogen, is good in flame retardance, can pass the VW-1 burning test and can be used for 60 years under the temperature condition of 90 DEG C.

The invention belongs to the technical field of tobacco flavors, and particularly relates to a product of the Maillard reaction of a date extract and the application thereof in tobacco. The date extract is mixed with amino acid and a reaction solvent, the pH value of the reaction system is adjusted to be 7-10, ammonium dihydrogen phosphate, ascorbic acid or butanedioic acid is adopted as catalyst, the mixture is heated to 80 to120 DEG C within 20-30min, and then continuously reacts for 0.5-4h, so as to obtain the reaction product finally after being cooled. The invention utilizes abundant date resources, and not only develops a new utilization method for the date resources, but also generates a tobacco flavouring agent through the reaction of the date extract and the amino acid. The invention is applied to tobacco flavoring, thereby decorating the fullness of smoke while highlighting the style of Chinese style cigarette, and reducing the harmfulness of cigarette.

The invention relates to a novel amphiphilic-block-copolymer-based pro-camptothecin drug, which is a compound of methoxy polyethylene glycol- polylactic acid and camptothecin derivatives (mPEG-X-PLA-T), wherein, mPEG refers to methoxy polyethylene glycol; X refers to linking group, for example, succinic acid; PLA refers to polylatic acid; T refers to drug molecule, that is, camptothecin derivatives such as, camptothecin, 10-hydroxycamptothecine, 7-ethyl-10- hydroxycamptothecine. Polylactic acid is connected with camptothecin derivatives through ester bond.

The invention relates to an emulsified metal antirusting agent and a preparation method thereof. The antirusting agent comprises the components by weight percentage of 2-2.5% of dicarboxylic acid, 6-6.5% of triethanolamine, 1-1.5% of monoethanolamine, 5-6.5% of synthesized borate, 8-10% of dodecenylbutadioic acid, 4.5-6% of octadecane oeoyl sarcosine acid, 0.1% of benzotriazole and 66.9-73.4% of water. The preparation method comprises the following steps of: firstly preparing a water-base antirusting agent; subsequently adding the octadecane oeoyl sarcosine acid, the synthesized borate and thedodecenylbutadioic acid in a reaction kettle; and mixing the solution, thus obtaining the emulsified antirust product. The method utilizes the strong adsorption function between the antirusting agentand the metal, displaces the residual oil dirt out of the surface of the metal, leads the surface of the metal to be adsorbed by a hydrophobic protective film; no oil dirt is remained on the surfaceof the metal that is processed by the antirusting agent, and the surface of the metal is not easy to be polluted by the dust; the antirusting agent can be used directly; furthermore, the components contains no nitrite, thus being safe and environment-friendly for use.

The invention provides a biodegradable multilayer co-extrusion material. The material is characterized by comprising two surface functional layers and a middle layer located between the two surface functional layers, components of the surface functional layers and the middle layer include biodegradable materials, and the biodegradable materials refer to one or more of polybutylene succinate, polylactic acid, polyhydroxyalkanoate and polybutylene adipate-polybutylene terephthalate. The invention further discloses a preparation method of the material. The biodegradablity of four selected master batches of the multilayer co-extrusion material is good, and adopted inorganic minerals are natural, so that the co-extrusion material has completely biodegradable properties and can be widely used in various types of food packages, medical products, environmental protection labels, advertisements and all kinds of environmental-protection products.

A demetalating agent for hydrocarbon oil contains one mor mixture of more than two of formic acid, acetic acid, propionic acid and butanoic acid, one or mixture of butanedioic acid and fumaric acid or maleic acid, polyacrylamide, one or mixture of more than two of S-carboxyethyl thiosuccinic acid, 2-mercaptobenzothiazole, hydroxyethylidene biphosphonic acid and 2-hydroxyphosphion acetic acid, andwater.

A high concentration, aqueous liquid surfactant composition is disclosed, comprising at least one amphoteric or anionic surfactant and a liquid-stabilizing amount of at least one liquid-stabilizing agent. The liquid-stabilizing agent is a succinic acid derivative, glutaric acid derivative or a combination thereof. The composition is pourable and pumpable at ambient room temperature.

The invention discloses a method for producing butane diacid through continuous fermentation or semi-continuous fermentation, which belongs to the bioengineering technical field. The invention provides application of Actinobacillus succinogenes in the method for continuously or semi-continuously preparing the butane diacid by utilizing carbohydrate raw materials such as cane molasses, corn starch syrup, Jerusalem artichoke hydrolysis syrup, sweet sorghum straw syrup, and lignocellulose hydrolysis syrup and so on. The method utilizes multi-step continuous fermentation or two-step semi-continuous fermentation, which can improve germ concentration and cell activity and can obtain high butane diacid output and high butane diacid production intensity; the method is easy to realize automatic and continuous operation; compared with batch fermentation, the method can save non-fermentation time such as repeated tank cleaning, sterilization and so on, so the production efficiency can be greatly improved; the semi-continuous fermentation for producing the butane diacid is easier to control fermentation parameters than the continuous fermentation, has high sugar utilization rate, target product yield and target product output, has simple and easy equipment and operation, and is suitable for industrialized production.

The invention relates to a method for extracting succinic acid from fermentation broth. The method includes the following steps that: (1) fermentation broth from which succinic acid can be obtained by way of microbial fermentation is ultrafiltered to remove mycelium cells and macromolecular impurities, so that clear filtrate is obtained; (2) H- storng-acid cation exchange resin is chosen, the filtrate obtained in the step 1 is exchanged by the ions of the H- storng-acid cation exchange resin, so that impurity cation is exchanged by H plus, and thereby succinic acid solution is obtained; (3) the succinic acid solution obtained in the step 2 is nanofiltered and decolored, so that decolored succinic acid solution is obtained; (4) the decolored succinic acid solution obtained in the step 3 isconcentrated, crystallized, centrifuged and washed, so that succinic acid is obtained. Compared with the prior art, the invention has the advantages of reasonable process route, less steps, low energy consumption and cost, high product crystallization rate, high product purity, byproduct recyclability, energy saving and the like.