The invention discloses a
zinc electrolyte dechlorination method. The
zinc electrolyte dechlorination method includes the specific steps that low grade
zinc oxide is subject to neutral leaching, thena leaching agent containing
chlorine is injected into a dechlorination tank to be stirred, an
antichlor, namely cuprous
oxide is added in the stirring process, then industrial sulphuric acid is added,and dechlorination
slag and dechlorination liquid are obtained; sampling is carried out for analysis of the
copper content,
iron powder is added according to the
copper content, stirring is carried out while the
iron powder is added, stirring lasts for 30 min-40 min, analysis of the
copper content is carried out, filter pressing is carried out when the copper
ion content is smaller than 0.1 g / L,and copper removal
slag is obtained; the dechlorination
slag and the copper removal slag are added into a reaction tank, then regenerated liquid is added, caustic soda flakes are added, the Ph is adjusted, a reaction is made for 3 h-4 h, and regenerated slag and a
sodium chloride solution are obtained; and high
chlorine water is added into the obtained
sodium chloride solution,
evaporation and concentration are firstly carried out to enable the high
chlorine water to be close to a
crystallization point of a
sodium chloride, then cooling
crystallization is carried out, sodium chloride
powder and
mother liquor are obtained through a separating
machine, and the regenerated slag can be recycled. The zinc
electrolyte dechlorination method has the advantages of being low in cost, high in efficiency, free of waste water, free of waste slag and free of
waste gas.