156 results about "2-HYDROXYETHYL ACRYLATE" patented technology

A sensor probe suited for implanting into the skin of a person includes a sensor body which may be formed from a polymer which includes 2-hydroxyethyl methacrylate (HEMA). A sensing system is supported by the body. The sensing system exhibits a detectable change when the probe is exposed to the analyte in the fluid. The sensing system may include an enzyme capable of catalyzing a reaction of the analyte to form a reaction product and a dye system which absorbs in the infrared region of the spectrum in response to the reaction product.

The invention discloses a method for preparing core-shell emulsion type adhesive which is modified by hydroxyl-terminated acrylic ester and is used in fabric printing and dyeing processes. The adhesive is prepared through the following steps: soft monomers copolymerize with crosslinking monomers and portions of hard monomers to produce core-shell particles; then a small portion of soft monomers and a large portion of crosslinking monomers copolymerize with hard monomers to coat the surface of the core layer, thus obtaining a shell layer and forming stable core-shell type emulsion. One or the mixture of two or more from 2-hydroxyethyl acrylate, hydroxypropyl acrylate, hydrobutyl acrylate and hydrohexyl acrylate is taken as a portion of soft monomers and crosslinking monomers; one or the mixture of two or more from hydroxylmethyl methacrylic acid, 2-hydroxyethyl acrylate methacrylic acid and hydroxypropyl methacrylic acid is taken as a portion of hard monomers and crosslinking monomers; one from butyl acrylate, ethyl acrylate and 2 ethylhexyl acrylate is taken as main soft monomers; one or the mixture of two or more from methyl methacrylate, crylic acid, cinnamene, acrylonitrile and methacrylic acid is taken as the hard monomers; surfactant sodium dodecyl sulfate, sodium dodecyl benzene sulfonate and octyl phenol polyethylene glycol are taken as emulsifying agent; potassium persulfate or ammonium persulfate is taken as initiator; and the copolymer emulsion is produced through emulsion copolymerization. Observed by transmission electron microscopy, the particles of the emulsion have visible core-shell structure and are even in distribution; the emulsion is stable, absolutely has no formaldehyde release both during the machining and using processes; the emulsion can be used both for pigment printing and for pigment dyeing.

The invention relates to novel crosslinkable copolymers which are obtainable by (a) copolymerizing at least two different hydrophilic monomers selected from the group consisting of N,N-dimethyl acrylamide (DMA), 2-hydroxyethyl acrylate (HEA), glycidyl methacrylate (GMA), N-vinylpyrrolidone (NVP), acrylic acid (AA) and a C1-C4-alkoxy polyethylene glycol (meth)acrylate having a weight average molecular weight of from 200 to 1500, and at least one crosslinker comprising two or more ethylenically unsaturated double bonds in the presence of a chain transfer agent having a functional group; and (b) reacting one or more functional groups of the resulting copolymer with an organic compound having an ethylenically unsaturated group.

The invention discloses a polycarboxylic-acid water reducing agent synthesized at normal temperature, and a preparation method and application method thereof. The polycarboxylic-acid water reducing agent is prepared from the following components in parts by weight:100 parts of unsaturated polyether DD-424, 9-13 parts of acrylic acid, 0-4 parts of methacrylic acid, 0-2 parts of sodium allylsulfonate, 0-2 parts of sodium methylallyl sulfonate, 0.2-1 part of oxydol, 0.2-1 part of ammonium persulfate, 0.2-0.6 part of L-ascorbic acid, 0-0.8 part of thioglycolic acid, 0-0.8 part of mercaptopropionic acid, 0-0.4 part of 2-hydroxyethyl acrylate, 4-6 parts of sodium hydroxide and 182-185 parts of water. At most one of the methacrylic acid, sodium allylsulfonate and sodium methylallyl sulfonate is 0 part; and at most one of the thioglycolic acid, mercaptopropionic acid and 2-hydroxyethyl acrylate is 0 part. The product disclosed by the invention has the advantages of excellent properties, high water reducing rate and favorable slump retention; and the method is simple and convenient to operate, has the advantages of low energy consumption and no discharge of three wastes, and is beneficial to application to large-scale production.

The invention relates to a surface sizing agent, which contains a polymer of cationic starch grafted monomers and succinylated chitosan sodium, wherein the cationic starch grafted monomers comprise three monomers such as a hard monomer, a soft monomer and a cross-linking monomer, the hard monomer is a mixture comprising one or a plurality of materials selected from styrene, methyl styrene, methyl methacrylate and methyl acrylate, the soft monomer is a mixture comprising one or a plurality of materials selected from n-butyl acrylate, tert-butyl acrylate and octadecyl acrylate, and the cross-linking monomer is a mixture comprising one or two materials selected from 2-hydroxyethyl acrylate and methylol acrylamide. The present invention further provides a preparation method for the surface sizing agent, a sizing liquid containing the surface sizing agent, and sizing paper prepared by applying the sizing liquid containing the surface sizing agent to carry out sizing. The surface sizing agent has characteristics of low price, green environmental protection and good use effect.

The invention discloses a high-solid-content finishing oil-based acrylic resin for automobiles and a preparation method thereof, which belong to the field of automobile paints and solve the problems of low solid content, high viscosity, poor solubility and the like in the existing acrylic resin paint. The resin contains acrylic acid, styrene, butyl acrylate, hydroxyethyl methacrylate, methyl methacrylate, methacrylic acid, butyl methacrylate, 2-ethylhexyl acrylate, n-dodecyl mercaptan, lauryl methacrylate, isoborneol methacrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 100# solvent oil, di-tert-pentyl peroxide, glycidol tert-carboxylate and a resin reactive diluent. The solid content can reach 90%. The acrylic resin has the advantages of favorable dilution property and low viscosity. The self-made reactive diluent can greatly enhance the water resistance and acid resistance of the paint. The construction solid content of the resin is nearly 70%. The acrylic resin greatly lowers the discharge of VOC (volatile organic compound), and is environment-friendly and practical.

The invention discloses a pressure-sensitive adhesive emulsion. The pressure-sensitive adhesive emulsion is prepared from a component A and a component B, wherein the component A is acrylate used for adhesive power of the pressure-sensitive adhesive and has side chain alkyl carbon atoms of 4-8 and is a mixture of 50-85 parts by weight of butyl acrylate and 2-20 parts by weight of 2-ethylhexyl acrylate; the component B is a rigid monomer compound for enhancing the cohesive force of the pressure-sensitive adhesive and is a mixture of two or more of 1-15 parts by weight of methyl methacrylate, 1-15 parts by weight of vinyl acetate, 2-5 parts by weight of 2-hydroxyethyl acrylate and 0.5-2 parts by weight of acrylic acid. The pressure-sensitive adhesive emulsion provided by the invention is capable of guaranteeing good initial adhesion and high holding power under good peeling strength.

The invention discloses an epoxy modified water-soluble acrylic resin, and a preparation method and application thereof. The preparation method of the epoxy modified water-soluble acrylic resin comprises the following steps: adding organic solvent, methyl methacrylate, butyl acrylate, methacrylic acid, 2-hydroxyethyl acrylate, chain-transfer agent and initiator into a reaction kettle, and heating to react; and adding organic solvent, methyl methacrylate, butyl acrylate, unsaturated double-bond terminated epoxy resin, methacrylic acid, 2-hydroxyethyl acrylate, chain-transfer agent and initiator into a dropwise addition tank, uniformly stirring, dropwisely adding into the reaction kettle, keeping the temperature, cooling, and adding an amine neutralizer for neutralization, thereby obtaining the epoxy modified water-soluble acrylic resin. The epoxy resin is introduced to the chain segment of the water-soluble acrylic resin by chemical modification, so that the epoxy modified water-soluble acrylic resin has better comprehensive properties, and better satisfies the requirements of customers.

The invention relates to a preparation method and an application of composite hydrogel provided with an amide group and a hydroxyl group and loaded with nano manganese oxide hydrate. The preparation method comprises the following steps: uniformly mixing 2-hydroxyethyl acrylate, N-hydroxymethyl acrylamide and distilled water to obtain polymer hydrogel by virtue of radiation polymerization; by taking the polymer hydrogel as a template, loading nano manganese oxide hydrate in situ, wherein a molar ratio of 2-hydroxyethyl acrylate to the N-hydroxymethyl acrylamide monomer is (1-9) to (9-1), a polymerization temperature is (-)63 DEG C-(-)95 DEG C, the irradiation polymerization is performed by an aqueous solution of 2-hydroxyethyl acrylate and N-hydroxymethyl acrylamide in the presence of a protective gas, and a method for loading nano manganese oxide hydrate is an oxidization reduction reaction in-situ precipitation method. The composite hydrogel is applied to adsorbing heavy metal ions in wastewater, and capable of effectively removing heavy metals; and moreover, the composite hydrogel has relatively high mechanical strength and a long service life.