The invention provides a two-phase composite compact ceramic oxygen-permeable film and production method thereof. The invention is characterized in that: a perovskite-type lanthanum manganate-based composite oxide is mixed with a stabilized fluorite-type zirconium dioxide at a volume ratio of 0.6-1.8:1 to obtain a ceramic blank, the ceramic blank is further sintered to obtain a slab-like or a hollow fiber-like self-support compact ceramic oxygen-permeable film or porous support-loaded compact ceramic oxygen-permeable film with a thickness of 0.001-10 mm; the perovskite-type lanthanum manganate-based composite oxide is Ln1-xAx-yMnO3, wherein Ln is La, Pr, Nb, Ce, Gd, Dy, Sm or a mixture thereof, A is Sr or Ca, x is 0.1-0.4, y is 0-0.10; the stabilized fluorite-type zirconium dioxide is RzZr1-zO2, wherein R is Y, Sc, Yb, Er, Gd, Eu, Dy or a mixture thereof, and z is 0.10-0.26. The oxygen-permeable film is stable and kept in high oxygen permeability during long-term storage in the atmosphere of CO2 and H2O; and has the advantages of rich raw material, low price, non-toxicity and harmfulness, and environmental friendliness.