The present invention relates to a process for direct electrodeposition of zincium
nickel alloy at
electron alloys surfaces. According to the process, an
electroplating method is adopted,
electron alloys is selected as
cathode, zincium
nickel alloy containing
nickel of 8-12% therein is selected as
anode, the
electric current density during electric plating is controlled at 1-2 A / dm2, and the electric plating time is 1 hour; finally, the
electron alloys suffering an electrodeposition of zincium
nickel alloy is put to a heat treatment furnace for a
heat treating at the temperature of 150-200 DEG C and for 1 hours; the electrolysing solution adopted uses deionized water as
solvent, wherein the components and their concentrations are as follows: ZnF2 8-12 g / L, NiF2, 15-25 g / L,
ammonium citrate 80-120 g / L,
potassium sodium 50-70 g / L, EDTA 8-12 g / L,
hexamethylenetetramine 1-2 g / L, all the solutes are stirred to being entirety dissolved and into clear solution , in which the
mole ratio of zincium
ion to
ion is controlled within 1:2-3. Said process for electrodeposition of zincium
nickel alloy at electron alloys surfaces by adopting electric plating method is not dependant on the grade of electron alloys, in other words, surfaces of electron alloys of any grades can be electrodeposited with zincium. On one hand, the cost for electron alloys mat-forming treatment is reduced; on the other hand, the
electroplating method is easy to realize industrialisation production. The fluorinion in
zinc fluoride (
nickel fluoride) plating solution exhibits an inactivating sheltering effect of the electron alloys, preventing the electron alloys being eroded in the solution. And the
zinc fluoride (
nickel fluoride) plating solution is of periodic duty and will not pollute the environment.