1596 results about "Co doped" patented technology

High performance (surface channel) CMOS devices with a mid-gap work function metal gate are disclosed wherein an epitaxial layer is used for a threshold voltage Vt adjust / decrease for the PFET area, for large Vt reductions (˜500 mV), as are required by CMOS devices with a mid-gap metal gate. The present invention provides counter doping using an in situ B doped epitaxial layer or a B and C co-doped epitaxial layer, wherein the C co-doping provides an additional degree of freedom to reduce the diffusion of B (also during subsequent activation thermal cycles) to maintain a shallow B profile, which is critical to provide a surface channel CMOS device with a mid-gap metal gate while maintaining good short channel effects. The B diffusion profiles are satisfactorily shallow, sharp and have a high B concentration for devices with mid-gap metal gates, to provide and maintain a thin, highly doped B layer under the gate oxide.

Methods and compositions for using an up-conversion phosphor as an emitting material in a reflective displays and Polymer compositions for display mediums, and blue green red (BRG) display mediums. Roles of the pumping duration and character on the temperature and the efficiency of the up-conversion process in (Ytterbium, Erbium or Thulium) co-doped fluoride crystals are set forth. Methods, compositions and display mediums for using up-conversion phosphors in both reflective and transmissive displays in which the substrate and pixel shapes are designed to maximally remove heat deposited in the emitting material and thereby improve the efficiency of up conversion.

Multimode optical fiber is disclosed herein comprising germania and fluorine co-doped in the core of the fiber. The dopant concentration profiles are defined by a pair of alpha parameters. The operating window, or bandwidth window, is enlarged and attenuation, or loss, is low. In some embodiments, two operating windows are available for transmission.

The invention discloses a process for preparing a high efficiency nanometer Tio2 visible light catalyst codoped with metal and non metallic ion, belonging to the photocatalysis technology field. The invention adopts titanic acid ester as precursor, uses metal salt and non-metallic compound as dopant, in accordance with sol-gel method, prepares the nanometer TiO2-based photocatalyst with codoping, high efficiency and visible light catalytic activity, wherein the catalytic activity is greatly higher than that of single-doped TiO2-based catalyst. The invention is characterized by the following: 1. due to codoping of the metal and non metallic ion, discrete localized doping level is formed respectively on the lower part of the conduction band energy level and the upper part of the valence band energy level of the TiO2-based catalyst, thus increasing the absorption of visible light and greatly improving the catalytic activity; 2. the doping level can inhibit the recombination of photogenerated carrier, promote the probability of the photogenerated carrier entering into the photocatalytic reaction and efficiently degrade pollutant molecules.

Nitrogen-doped titania nanotubes exhibiting catalytic activity on exposure to any one or more of ultraviolet, visible, and / or infrared radiation, or combinations thereof are disclosed. The nanotube arrays may be co-doped with one or more nonmetals and may further include co-catalyst nanoparticles. Also, methods are disclosed for use of nitrogen-doped titania nanotubes in catalytic conversion of carbon dioxide alone or in admixture with hydrogen-containing gases such as water vapor and / or other reactants as may be present or desirable into products such as hydrocarbons and hydrocarbon-containing products, hydrogen and hydrogen-containing products, carbon monoxide and other carbon-containing products, or combinations thereof.

The present invention provides co-doped zinc oxide to flat panel, light emissive display devices and vacuum microelectronic devices to improve their efficiency and lifetime. This material has a low growth temperature and is compatible with metal oxide semiconductor (MOS) processing technology. It is tranparent, chemically stable and has a low work function, which result in many advantages when being used as the cathode for the aforementioned devices. In one embodiment of the emissive display device, an organic light diode (OLED) display has a high work function metal anode, such as platinum (Pt), gold (Au) or nickel (Ni) and a low work function co-doped zinc oxide cathode. Because of the energy level alignment provided by these two materials, the potential energy barriers to injection of electrons from the cathode and holes from the anode into the organic emissive medium are minimized so the display device operates more efficiently.

The invention discloses a nitrogen and sulfur co-doped graphene. The method comprises the following steps: grinding and uniformly mixing graphene or a graphene derivative, a nitrogen-containing compound and a sulfur-containing compound, carrying out thermal annealing under the protection of an inert gas at a temperature of 500-1000DEG C, maintaining the temperature for 1-5h, and cooling to room temperature to obtain the nitrogen and sulfur co-doped graphene, wherein content of the nitrogen element in the nitrogen and sulfur co-doped graphene is 1-10at.%, and the content of the sulfur element in the nitrogen and sulfur co-doped graphene is 0.5-2at.%. The method has the advantages of simple technology, low cost, easy control of the reaction process and the like, is suitable for the industrial large-scale production, and can be used in the super capacitor field, the sensor field, the catalytic field, the fuel battery field, the lithium air battery field and the like.

In order to degrade the pollutants in water and atmosphere by the photocatalysis technology, the invention discloses a method for preparing a high activity non-metallic ion co-doped titanium dioxide photochemical catalyst. In the photochemical catalyst, titanium ester or titanate is used as a precursor, non-metallic compound comprising boron, carbon, nitrogen, fluorin, silicon, phosphor, sulfur, chlorine, bromine, iodine, and the like, are used as doping agents, the high activity non-metallic ion co-doped titanium dioxide photochemical catalyst is prepared by adopting the sol gel method. Compared with a titanium dioxide photochemical catalyst single-doped with pure titanium dioxide and the non-metallic irons, the visible light catalytic activity of the titanium dioxide photochemical catalyst on the degradation of parachlorophenol is greatly improved, and the ultraviolet light catalytic activity can also exceed the catalytic activity of the pure titanium dioxide catalyst. The method also has the advantages that the preparation technique is simple, the equipment requirement is low; the particle diameter of the product is small, the specific surface is relatively high, the dispersivity is good, thus having a wide application prospect in the environmental cleaning scientific field.

A transparent polycrystalline yttrium aluminum garnet (YAG) ceramic is described wherein the ceramic is colorless and transparent in both as-sintered and post-sinter, air-fired states which makes it highly desirable for lamp applications. The transparent YAG ceramic is co-doped with an amount of MgO and an amount of ZrO2 wherein the weight ratio of MgO to ZrO2 is from about 1.5:1 to 3:1.

The invention provides a preparation method and an application of a nitrogen and phosphorus co-doped porous carbon catalyst and belongs to the field of oxygen reduction catalysts for a fuel cell cathode. Nitrogen and phosphorus are introduced with an in-situ doping method, and the nitrogen and phosphorus doping amount is changed by adjusting the content of a nitrogen and phosphorus precursor. Besides, nitrogen and phosphorus co-doped porous carbon is prepared with a hard template method, and controllability of pore diameters of the porous carbon is realized by adjusting a hard template. The method comprises steps as follows: an earlier polymer of aniline monomers, a phosphorus precursor, a silica-based hard template and non-precious metal salt is prepared; the earlier polymer is calcined, and solids are obtained; the solids are etched, cleaned and dried, and the carbon material is obtained. More importantly, the prepared nitrogen and phosphorus co-doped porous carbon material has an excellent oxygen reduction electro-catalytic property under the acid condition and has huge application potential.

The invention discloses a preparation method of a nitrogen-phosphorus co-doped carbon nanosheet and application of the preparation method.Nitrogen-phosphorus co-doped carbon nanosheet catalyst material is prepared by: calcining at high temperature, template-free one-step self-assembled precursors: melamine and phytic acid.Oxygen reduction tests show that prepared N-P / CNS-1000 shows corrected initial potential and higher current density, represents four-electron transfer reaction, can match with commercial Pt / C and shows both excellent ethanol resistance and long-range stability in alkali solutions.

Scintillation materials of this invention have an alkali halide host material, a (first) scintillation dopant of various types, and a variety of second dopants (co-dopants). In another embodiment, the scintillation materials of this invention have an alkali halide host material, a (first) scintillation dopant of various types, a variety of second dopants (co-dopants), and a variety of third dopants (co-dopants). Co-dopants of this invention are capable of providing a second auxiliary luminescent cation dopant, capable of introducing an anion size and electronegativity mismatch, capable of introducing a mismatch of anion charge, or introducing a mismatch of cation charge in the host material.

The invention relates to a nanometer titanium dioxide photocatalyst co-doped with boron and other elements and a preparation method thereof. The method uses titanate and boric acid as a titanium source and a boron source; the other doped elements comprise one or more of transition metal, rare-earth metal or nonmetal; and the method adopts acetic acid, nitric acid or citric acid as a hydrolysis catalyst and a mixture of alcohol and water as a reaction system and prepares the nanometer titanium dioxide photocatalyst co-doped with the boron and the other elements by a sol-gel reaction and calcinations. The nanometer titanium dioxide co-doped with the boron and other elements prepared by the method can absorb visible light and has catalytic activity of the visible light.

An optical fiber amplifier utilizing a phosphate glass optical fiber highly doped with rare-earth ions such as erbium to exhibit high gain per unit length, enabling the use of short fiber strands to achieve the needed gain in practical fiber optical communication networks. The high-gain phosphate optical glass fiber amplifiers are integrated onto substrates to form an integrated optics amplifier module. An optical pump such as a semiconductor laser of suitable wavelength is used to promote gain inversion of erbium ions and ultimately provide power amplification of a given input signal. Gain inversion is enhanced in the erbium doped phosphate glass fiber by co-doping with ytterbium. A phosphate fiber amplifier or an integrated optics amplifier module utilizing this power amplification can be combined with other components such as splitters, combiners, modulators, or arrayed waveguide gratings to form lossless or amplified components that do not suffer from insertion loss when added to an optical network. The fiber amplifier can be a single fiber or an array of fibers. Further, the phosphate glass fibers can be designed with a temperature coefficient of refractive index close to zero enabling proper mode performance as ambient temperatures or induced heating changes the temperature of the phosphate glass fiber. Large core 50-100 .mu.m fibers can be used for fiber amplifiers. The phosphate glass composition includes erbium concentrations of at least 1.5 weight percentage, preferably further including ytterbium at 1.5 weight percentage, or greater.

The present invention relates to a nanophosphor and method for synthesizing the same, and provides a nanophosphor containing fluoride-based nanoparticles co-doped with Yb3+ and Er3+ expressed by the following Chemical Formula 1,NaY1−w−z−x−yGdwLzF4:Yb3+x,Er3+y  (1)wherein, the description of the values x, y, w, z, and L is the same as defined above.The nanophosphor may exhibit an excellent luminous intensity despite having a small particle size, and be excited by infrared rays to emit visible light, and have magnetic properties and thus can be used as a contrast agent, a counterfeit prevention code, and the like.

The invention discloses a rare earth / alkaline earth metal and transition metal doped bismuth ferrite nano multiferroic material, and the chemical formula is Bi1-xRxFe1-yMyO3, wherein R is rare earth metal or alkaline earth metal, M is transition metal, x is not less than 0 and not more than 0.30, and y is not less than 0 and not more than 0.02. The preparation method has the steps of taking ferric nitrate, bismuth nitrate, rare earth / alkaline earth metal oxide or nitrate and transition metal nitrate as raw materials, taking ethylene glycol as a solvent, or using a specific additive for matching, mechanically stirring, forming even ethylene glycol solution, then aging at room temperature, evaporating and drying the obtained solution at the temperature of 160-250 DEG C, and carrying out thermal treatment at lower temperature for obtaining rare earth / alkaline earth metal A-site doped, transition metal B-site doped and rare earth / alkaline earth metal A-site and transition metal B-site co-doped bismuth ferrite nanoparticles of 20-100nm. The prepared nano multiferroic material has stable crystal quality, thereby having extensive application prospects in the fields of information storage, magnetic sensors of spin electronic devices, capacitor-inductor integrated devices and the like.

Semi-insulating Group III nitride layers and methods of fabricating semi-insulating Group III nitride layers include doping a Group III nitride layer with a shallow level p-type dopant and doping the Group III nitride layer with a deep level dopant, such as a deep level transition metal dopant. Such layers and / or method may also include doping a Group III nitride layer with a shallow level dopant having a concentration of less than about 1×1017 cm−3 and doping the Group III nitride layer with a deep level transition metal dopant. The concentration of the deep level transition metal dopant is greater than a concentration of the shallow level p-type dopant.

The invention provides a nitrogen-sulfur co-doped carbon material with an electro-catalytic oxygen reduction activity and a preparation method of the carbon material, and belongs to the technical field of new material application. The technologic process comprises the following steps: performing ultrasonic cleaning on hairs with acetone, then shearing and crushing the hairs, pouring the hairs into a liner of a reaction kettle, adding analytically pure ammonia water, carrying out a hydrothermal degradation reaction, drying the solution obtained from hydrothermal degradation to obtain solid amino acid, mixing the solid amino acid with a template agent uniformly, thermally decomposing the mixture under an inert atmosphere, removing the template agent with diluted hydrochloric acid from the obtained sample, washing and drying, so as to prepare the nitrogen-sulfur co-doped carbon material. As the carbon material is prepared by taking hairs as the raw materials, the raw materials are simple and accessible, and low in cost; the selected template agent is low in cost and easy to remove; the preparation method is simple in technology; the prepared material is high in nitrogen and sulfur content, and has larger specific surface area, and is rich in pore structures; the nitrogen-sulfur co-doped carbon material prepared by the method shows up excellent properties in fuel cell cathode oxygen reduction and catalysis.

A method for fabricating a p-n heterojunction device is provided, the device being preferably comprised of an n-type GaN layer co-doped with silicon and zinc and a p-type AlGaN layer. The device may also include a p-type GaN capping layer. The device can be grown on any of a variety of different base substrates, the base substrate comprised of either a single substrate or a single substrate and an intermediary layer. The device can be grown directly onto the surface of the substrate without the inclusion of a low temperature buffer layer.

The invention provides a method for preparing sulfur and nitrogen co-doped titanium dioxide with visible light catalytic activity, which adopts a sol-gel method and comprises the following steps: hydrolyzing titanium ester and introducing sulfur and nitrogen sources to obtain a titanium dioxide sol, wherein the sulfur and nitrogen sources are from thiourea solution; in a sol system, dropwise adding 1 to 5 percent saturated aqueous solution of thiourea to perform the hydrolysis reaction to obtain the sol; then performing aging and volatilizing a diluent to obtain a titanium dioxide gel; drying the titanium dioxide gel and grinding into powders; performing heat treatment on the solid powder; and calcinating to obtain sulfur and nitrogen co-doped titanium dioxide nano powder. In the method, the thiourea is used as the raw materials of the nitrogen and sulfur sources, the sulfur and the nitrogen are simultaneously introduced in the process of the hydrolysis reaction of the sol to achieve synergistic effect and improve the reaction efficiency, raw material consumption is less, the process is simplified, the absorption range of visible light is effectively improved, the wavelength of the visible light is expanded to about 650nm, and the sulfur and nitrogen co-doped titanium dioxide has obvious visible light activity in the photocatalytic degradation reaction of organic pollutant molecules.

The invention discloses a tungsten-titanium co-doped diamond (DLC) coating material and a preparation technique thereof, which are characterized by: firstly, removing a pollution layer on the surface of a workpiece by ultrasonic cleaning, and performing argon-ion etching cleaning on the surface of the workpiece by glow discharge to obtain an atomic-scale clean surface; secondly, preparing a gradient transition layer by a reactive magnetron sputtering sedimentation method; and finally, preparing a preparing a DLC coating on the transition layer by magnetron sputtering and glow discharge plasma chemical vapor deposition method, wherein the synthesized DLC coating contains carbon element, tungsten element, titanium element and the like; the tungsten content is 2 to 5 percent; and the titanium content is 0.1 to 2.0 percent. The tungsten-titanium co-doped diamond (DLC) coating material is excellent in membrane / base binding force and low in friction coefficient and wear rate.

The invention discloses a preparation method and products of a non-noble metal catalyst. The preparation method of the non-noble metal catalyst comprises the steps of dissolving two metal salts and an organic ligand proportionally in an organic solvent respectively, mixing well, standing a solution at room temperature, and centrifuging or filtering and fully drying to obtain a precursor; subjecting the precursor to high-temperature pyrolysis in an inert atmosphere to obtain the non-noble metal catalyst; the prepared non-noble metal catalyst is a nano-structure carbon material with cobalt and another metal element co-doped, with MOF structure as a core and with carbon nanotubes grown on the surface; the non-noble metal catalyst prepared herein has high redox catalytic activity and stability and excellent CH3OH / CO tolerance in acidic electrolyte, the cost for the materials used herein is low, the preparation method is simple and convenient and is easy to perform.

The invention discloses a method for directly preparing a co-doping three-dimensional graphene electrode material through biomass carbon sources. The method mainly includes the steps that biomass such as eggshells of artemia cysts, bean pulp and shrimp shells are used as the carbon sources, red phosphorus or boric acid is added to serve as a stripping agent, metal nickel salt is added to serve as a catalyst, and oxygen-nitrogen-phosphor multi-atom co-doping three-dimensional porous graphene is synthesized in a roasted mode at the temperature of 700 DEG C to 900 DEG C under argon atmosphere; the obtained graphene is ground into powder, the graphene, acetylene black and PTFE are ultrasonically dispersed into absolute ethyl alcohol in the mass ratio of 85:10:5, the mixture is dried at the temperature of 80 DEG C to be pasty, 0.5 mg to 5 mg of the mixture is taken and evenly smeared on 1*1-cm foam nickel, vacuum drying is carried out at the temperature of 120 DEG C for 12 h, plate pressing is carried out at the pressure of 12 MPa, and an electrode plate is obtained. According to the method, the source of the required raw materials is wide, the price is low, devices are simple, repeatability is good, and low-cost large-scale industrial production can be achieved easily; the prepared graphene electrode material has the advantages of being good in electrochemical activity, large in specific area, not prone to repeated accumulation and the like; the broad application prospects are achieved in the aspects such as electrode materials and catalyst carriers of supercapacitors and lithium ion batteries.

The invention relates to an iron and nitrogen co-doped carbon-oxygen reduction catalyst, and a preparation method and application thereof. Fe / Zn bimetallic ZIF with elemental gradient distribution isprepared to prepare an iron and nitrogen co-doped carbon-oxygen reduction catalyst by pyrolysis and carbonization as a precursor, in order to improve the utilization rate of active sites, optimize thepore structure and further enhance the catalytic activity. The iron and nitrogen co-doped carbon-oxygen reduction catalyst prepared by the invention can efficiently catalyze the oxygen reduction reaction and exhibits better oxygen reduction catalytic activity and electrochemical stability than the commercial Pt / C catalyst. The preparation method is simple and controllable, has short cycle, abundant raw material reserves and low cost, and can realize large-scale production.

The invention discloses a single longitudinal-mode optical fiber laser with low noise, narrow linewidth and high power. Polarization maintaining optical fiber is rare-earth-doped phosphate single-mode glass optical fiber, the component of a fiber core is phosphate glass which consists of 70P2O5-8Al2O3-15BaO-4La2O3-3Nd2O3, the fiber core of the polarization maintaining optical fiber is doped with high-concentration luminous ions, the luminous ions are one or combination of more than one of lanthanide ions and transition metal ions, the doping density of the luminous ions is greater than 1*10<19>ions / cm<3> and the luminous ions are evenly doped in the fiber core. A polarization maintaining fiber Bragg grating with the narrow linewidth and a dichroscope form a front cavity mirror and a rear cavity mirror of the optical fiber laser, a centimeter-sized erbium-ytterbium co-doped phosphate glass polarization maintaining optical fiber is taken as a laser working substance, and polarization maintaining output laser generated by a single-mode semiconductor laser is taken as a pumping source, thus achieving the single longitudinal-mode laser output by designing and manufacturing the reflection spectrum width of the polarization maintaining fiber Bragg grating and controlling the cavity length of the whole laser cavity.

The bio-sample (e.g., a live cell) is labeled with a proper number of nanoparticles. Each nanoparticle is pre-co-doped with a controlled ratio of fluorophore donors and acceptors. Two laser pulses are applied to the bio-sample. The first laser pulse has a center wavelength near the peak of absorption spectrum of acceptors. The intensity of first laser pulse is adjusted such that FRET saturation occurs near the center of the focal spot. The focal spot of the first laser pulse is a diffraction-limited Airy disk that has the highest laser intensity in the center of the focal spot. The second laser has a center wavelength in the emission spectrum of acceptors and with a uniform intensity distribution throughout the focal spot. The fluorescence emission from acceptors after two laser pulses is from an area that is smaller than the diffraction-limited focal spot. Hence, a higher than diffraction-limit resolution is achieved.

The invention discloses an F, Mn co-doping deposition nano-SnO2 transparent heat insulating thin film, wherein the F, Mn element co-doping effect is utilized to increase the number charge carriers in the thin film material, thus increasing the index of thin film reflection to infrared rays. The invention can prevent the excess doping of one single element, it can be applied to chemical CVD or supersonic spraying thermal dissociation deposition.

The invention discloses a multi-element in-situ co-doped ternary material precursor as well as a preparation method and an application thereof. The chemical formula of the precursor is (NixCoyMnz)(1-a-c)MaNc(OH)(2+k), wherein x is larger than or equal to 1 / 3 and smaller than or equal to 0.9, y is larger than 0 and smaller than or equal to1 / 3, z is larger than 0 and smaller than or equal to 0.4, the sum of x, y and z is 1, a is larger than or equal to 0.0001 and smaller than or equal to 0.01, and c is larger than or equal to 0.0001 and smaller than or equal to 0.01; radius of a doped ion M is close to that of the lithium ion, and M is selected from one or more of Mg<2+>, Zn<2+>, Zr<4+>, Nb<5+>, Ta<4+>, In<3+>, Sc<3+>, Y<3+>, Ce<4+> and Gd<3+>; radius of a doped ion N is close to that of metal ions Mn and Co in the ternary material, and N is selected from one or more of Al<3+>, Ti<4+>, Ge<4+>, W<6+> and V<5+>. In the preparation process of the ternary material precursor, two kinds metalions with different radii are introduced in situ, so that the doped metal ions are uniformly distributed in a precursor phase, and uniform mixing on the atomic grade is realized. The two kinds of metal ions with different radii are doped in different positions, cell parameters have coordinated variation, so that not only can a lithium ion transmission channel be expanded, but also good lattice structure of the ternary material can be kept, and the ternary material with excellent electrochemical performance is obtained.

The invention relates to a preparation method for a rare earth element-doped titanium dioxide nano material. The method comprises the steps of dissolving urea and rare earth element nitrate in absolute ethyl alcohol; adding liquid titanium source into the above solution to form a homogeneous solution; adding deionized water with stirring to form a transparent gel; performing hydro-thermal treatment on the above gel; washing, filtering and drying to obtain the rare earth element-doped titanium dioxide nano material. An object of doping titanium dioxide by using the rare earth element is realized through automatic regulation and control of pH value of a reaction system by slow decomposition of urea in the hydrothermal process. The preparation method is simple in process and flow, has wide parameter adjustable range, strong repeatability and low cost, and can be used for preparing different rare earth element-doped titanium dioxide nano materials or a plurality of the rare earth elements co-doped titanium dioxide nano material.

The invention relates t a phosphate base optical glass mixed with ytterbium and bismuth and a manufacturing method of the phosphate base optical glass. The compositions and mol percentage of the glass is that: P2O5(50-80), Al2O3(5-30), Ta2O3(0-5), Ga2O3(0-5), Y2O3(0-5) , Li2O(0-30), Na2O(0-15), K2O(0-5), ZnO(0-15), MgO(0-40), CaO(0-30), SrO(0-15), BaO(0-15), TiO2(0-5), ZrO2(0-5), SiO2(0-20), Bi2O3(0.01-5), Yb2O3(0.01-15); wherein the figures in the bracket refer to the selection range of mol percentage of the corresponding oxide of the compositions. Under the pump of 405nm, 532nm, 808nm and 980nm, higher near infrared ultra wideband fluorescence can be obtained; and under the pump of 980nm, the glass fluorescence emission has a remarkable reinforced effect and is hopeful to be applied in fields such as optical amplifier, superpower laser and tunable laser.