Patents
Literature
Hiro is an intelligent assistant for R&D personnel, combined with Patent DNA, to facilitate innovative research.
Hiro

49 results about "ALLYL ACRYLATE" patented technology

Betaine type zwitterionic polymer antifogging coating and preparation method thereof

InactiveCN106632830ADoes not affect hydrationImprove stabilityCoatingsCross-linkPolymer science
The invention discloses a betaine type zwitterionic polymer antifogging coating and a preparation method thereof. The coating is prepared from components as follows: 77%-100% of a random copolymer p (BMAm-co-FMAn-co-AMAr) and 0-23% of polyethylene glycol dimethacrylate; the coating is prepared from a betaine type zwitterionic polymer with a crosslinking point and polyethylene glycol dimethacrylate as a cross-linking agent through ultraviolet curing and film-forming, and is a random copolymer formed by betaine type acrylate monomers, fluorinated acrylate and allyl methacrylate through free radical polymerization. Hydrophilic betaine type zwitterionic components are subjected to hydration with water to realize the antifogging effect; with introduction of an appropriate quantity of hydrophobic components, water vapor can be effectively isolated, and interaction of a hydrophobic part and water is not influenced; the crosslinking point is provided by allyl methacrylate, so that stability of the coating is improved; the coating has good transparency and antifogging performance, and light transmittance of the coating in a visible light wavelength range reaches 80% or higher.
Owner:TIANJIN UNIV

Method for preparing antifouling material with surface of spherically raised microstructure

The invention belongs to the technical field of antifouling material processing and relates to a method for preparing an antifouling material with surface of spherically raised microstructure which is formed by direct film forming. The antifouling material prevents marine growth from adhering to the surfaces of the ship and marine structures under marine environment. The method is characterized by first utilizing hydrogen-containing silicone oil and allyl methacrylate for hydrosilylation to synthesize a silicone component containing polymerizable double bonds, carrying out free radical copolymerization on the silicone component and acrylonitrile and acrylate monomers to form acrylate resin mixed liquor hinged with silicone gel particles, mixing the mixed liquor with resins and then coating films, thus obtaining the antifouling material. The mixed resin material has the characteristic of low surface energy. The characteristic of spherically raised microstructure is formed, thus improving the hydrophobic property of the antifouling material, so that the antifouling material prevents marine organisms from being contaminated. With the hydrophobic property being improved, the antifouling material reduces the possibility of organism adhesion, has no devastating impacts on the environment and has good application prospect, reduced surface energy, strong capability of preventing adhesion of diatom, simple and easily controlled preparation process and low cost.
Owner:725TH RES INST OF CHINA SHIPBUILDING INDAL CORP

Washable oiliness coating adhesive and preparation method

The invention relates to a washable oiliness coating adhesive. The washable oiliness coating adhesive comprises the following raw materials by weight percent: 25 to 30 percent of methyl methacrylate, 76 to 86 percent of n-butyl acrylate, 3 to 6 percent of 2-ethylhexyl acrylate, 2 to 4 percent of allyl methacrylate, 1 to 3 percent of vinyl trimethoxy silane, 0.3 to 0.6 percent of sodium dodecyl benzene sulfonate, 3 to 6 percent of fatty alcohol-polyoxyethylene ether XL90, 0.15 to 0.5 percent of sodium hydrogen sulfite, 0.25 to 0.6 percent of ammonium persulfate, 8 to 12 percent of refined castor oil, 180 to 220 percent of deionized water and 3.5 to 4 percent of associated polyurethane leveling rheological agent WT-203; and the raw materials are emulsified, polymerized and thickened to obtain the washable oiliness coating adhesive. The washable oiliness coasting adhesive is used for the after-treatment of textiles, the characteristics of oiliness and firmness can be realized, and a durable washable oiliness effect can be realized.
Owner:LIAONING FIXED STAR FINE CHEM

Functional red microsphere and preparation thereof

The invention relates to a functional red microsphere which is characterized in that the functional red microsphere includes a cue ball and a shell coated on the cue ball; the cue ball is formed by the polymerization of the monomers selected as follows: divinylbenzene, allyl raethacrylate or glycidyl methacrylate; the dosage of the monomers is 6 portions by weight; perylene is used as a copolymer crosslinking agent and the dosage thereof is 0.05 to 0.4 portions by weight; the shell is the homopolymer of the glycidyl methacrylate; the surface of the shell is processed by acid quaternary ammonium salt. The materials of the reaction related in the invention are easier to be obtained; the product of the invention is not only easy to be treated cleanly, but also does not dissolve in a higher organic solvent. The diameter of the microsphere can achieve 10Mum; and the functional red microsphere can be used as electrophoresis.
Owner:BEIJING JIAOTONG UNIV

Environment-friendly white latex

The invention discloses an environment-friendly white latex. The white latex comprises the following components in parts by weight: 700-1050 parts of polyvinyl acetate, 300-350 parts of vinyl acetate, 120-145 parts of polyvinyl alcohol, 60-100 parts of dibutyl phthalate, 20-40 parts of diethylene glycol dibenzoate, 10-15 parts of octanol, 30-45 parts of isopropanol, 10-25 parts of allyl methacrylate, 5-10 parts of ethylene glycol dimethacrylate, 3-7 parts of toluene diisocynate, 35-50 parts of sodium bicarbonate, 1400-1500 parts of water, 40-50 parts of emulsifier, 5-10 parts of initiator, 20-32 parts of hydroxymethyl acrylamide, 10-15 parts of waxy corn starch and 2-7 parts of sodium hypochlorite. By adopting the white latex, the environmental protection property of the product is fundamentally improved, the indexes such as the thermal stability, the initial drying time, the hydrolytic resistance, the bonding strength and the curing time are excellent and the comprehensive performance is superior.
Owner:江苏中丽新材料有限公司

Microsphere for electronic papers and uses thereof

The invention relates to a microsphere used for synthesizing electronic paper by embedding dyes as well as the synthesis and application thereof. The invention is characterized in that the microsphere comprises an inner core and a shell; wherein, the inner core is polymer embedding dye. The polymer is formed by copolymerization of the following selected monomers: styrene, divinyl benzene, methyl metharcrylate, isobutyl methacrylate, n-butyl methacrylate, methacrylate, 4-vinylpridine, ethyl acrylate, butyl acrylate, acrylonitrile, glycidolmethacrylate, allyl methacrylate, methylacrylic acid, acrylic acid, vinyl acetate or perchloroethylene; the shell is polymerized by the following monomers: ethylene monomer containing a epoxy group or ethylene monomer containing a pyridyl in a side chain. The microsphere used for electronic paper in the invention has the advantages of excellent flexibility and anti-aggregation performance, thus keeping the stability of microsphere in the medium.
Owner:BEIJING JIAOTONG UNIV

Preparation method of organic silicone additive and application of organic silicone additive in water-based acrylic semi-gloss resin emulsion

The invention provides a preparation method of an organic silicone additive and application of the organic silicone additive in water-based acrylic semi-gloss resin emulsion. The method comprises the following steps: uniformly stirring isopropanol chloroplatinate which is used as a catalyst, 2,6-ditertbutyl-4 methylphenol which is used as a polymerization inhibitor, and allyl methacrylate in absence of an solvent and under the dry inertia atmosphere; heating to reach the temperature of 65-105 DEG C; dropwise adding 1,1,1,3,5,5,5-heptamethyltrisiloxane at the rate of 0.5-1 ml / min; then carrying out a continuous reaction for 30-100min; decreasing the temperature to reach room temperature; filtering to obtain the organic silicone additive; the organic silicone additive is added to the preparation of water-based acrylic resin emulsion, and then the emulsion is uniformly coated on a base material to form a film, and finally the film is dried to obtain a water-based acrylic resin coated film. The method is carried out in the absence of the solvent, so that the environmental pollution is avoided; the after-treatment is simple; the production efficiency is high; with the adoption of the organic silicone additive, the surface glossiness and the surface free energy of the resin can be reduced; a delustering agent is saved, thus the production processes are simplified, and the production efficiency is improved.
Owner:NANCHANG UNIV

Method for synthesizing allyl methacrylate

The invention discloses a method for synthesizing allyl methacrylate. The method comprises the following steps of: A, reacting potassium methacrylate or sodium methacrylate and 3-chloropropene serving as raw materials in a solvent in the presence of a catalyst and a polymerization inhibitor with stirring at the temperature of between 40 and 60 DEG C for 2 to 5 hours; and B, recovering excess 3-chloropropene by distillation, and distilling or fractionating to obtain the allyl methacrylate, wherein the molar ratio of the potassium methacrylate or the sodium methacrylate to the 3-chloropropene is 1:1.5-5; the solvent is selected from dimethyl sulfoxide and N,N-dimethylformamide; the catalyst is selected from hexadecyl trimethyl ammonium bromide serving as a quaternary ammonium salt and benzyl triethyl ammonium chloride; and the polymerization inhibitor is selected from p-benzoquinone and hydroquinone. The method is simple and convenient, is easy to operate, has short reaction time and is low in cost; and by the method, the allyl methacrylate can be prepared at a higher yield.
Owner:WUHAN TEXTILE UNIV

Waterproof, breathable and puncture-proof safety shoe upper and manufacturing method thereof

The invention provides a waterproof, breathable and puncture-proof safety shoe upper and a manufacturing method thereof. The safety shoe upper comprises a moisture absorption inner layer and a waterproof and puncture-proof outer layer, the formula of the moisture absorption inner layer is as follows: jute fiber, polyester fiber, cotton fiber, corn fiber and bamboo charcoal fiber; the waterproof and puncture-proof outer layer sequentially comprises a puncture-proof adhesive and a waterproof membrane from inside to outside, the formula of the puncture-proof adhesive is as follows: epoxy resin, acuring agent, carbomer, latex, cellulose, 1,4,5,8-tetrachloroanthraquinone, and 2-allyl methacrylate; and the waterproof membrane is an expanded polytetrafluoroethylene microporous membrane. The moisture absorption inner layer of the shoe upper disclosed by the invention is blended and woven by a plurality of fibers, so that the shoe upper can be effectively protected, and the comfort of use canbe improved due to the moisture absorption effect; and the waterproof and puncture-proof outer layer can make up the defects of the insufficient puncture-proof performance of the shoe upper, and provides certain puncture-proof performance and waterproof performance for the shoe upper.
Owner:TIANJIN TIANXING KESHENG LEATHER PROD

Anti-stripping agent for asphalt cold paving materials and preparation method of anti-stripping agent

The invention discloses an anti-stripping-type asphalt cold paving material and a preparation method thereof. The anti-stripping-type asphalt cold paving material is prepared from aggregate, a filler,diesel oil, asphalt, a cold paving agent and a special anti-stripping agent which are mixed, wherein the special anti-stripping agent is prepared in the mode that trichlorosilane, allyl methacrylateand N,N'-bis(2-naphthyl)-p-phenylenediamine react and then are mixed with lime. Aiming at solving the problems that a current cold paving asphalt mixture is poor in water stability and slow in strength formation, a modifier capable of enhancing the asphalt cold paving material mineral aggregate and asphalt bonding property is developed, stripping between asphalt and mineral aggregate in the cold paving material is prevented under the action of water, and the water-resistant stability property of the asphalt cold paving material is improved.
Owner:HUBEI UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products