341 results about "Ti oxides" patented technology

A non-aqueous electrolyte secondary battery has a positive electrode (11) containing a positive electrode active material, a negative electrode (12) containing a negative electrode active material, and a non-aqueous electrolyte solution (14) in which a solute is dissolved in a non-aqueous solvent. The positive electrode active material is obtained by sintering a titanium-containing oxide on a surface of a layered lithium-containing transition metal oxide represented by the general formula Li1+xNiaMnbCocO2+d, where x, a, b, c, and d satisfy the conditions x+a+b+c=1, 0.7≦a+b, 0≦x≦0.1, 0≦c / (a+b)<0.35, 0.7≦a / b≦2.0, and −0.1≦d≦0.1.

The disclosed Li-Mn composite oxide for positive of secondary Li cell comprises the core LiaMn2-bXbO4 and a coating layer, wherein 0. 97<=a<=1. 06, 0 <=b<=0. 5, X for other metal (except Li and Mn) or Si; the coating layer comprises one of more of Li-B composite oxide, Li-Co oxide, Li-V oxide, Al oxide, Al phosphate, Ti oxide, Cr. Oxide, Mg oxide, and Ca oxide This invention improves material performance, special the circulation performance at high temperature.

The invention relates to a catalyst of selective reduction of nitrogen oxide by ammonia, which mainly solves the existing problems that the commonly used NH3-SCR catalyst system is toxic to environment and human body, the anti-SO2 poisoning ability of the catalyst system is poor in the reference and the catalyst system can not adapt to the conditions of high space velocity. The invention adopts cheap and non-toxic raw materials to prepare a Fe-Ti oxide catalyst with high activity, selectivity, stability and anti-S2 poisoning ability by the simple and practicable co-precipitation method, which can better solve the existing technical problems. If the catalyst is loaded on honeycomb ceramics after being made into pulp, the catalyst is hopeful to be put into practical application of flue gas denitrification of coal-fired power plants.

The invention discloses a method for preparing a composite Ag-Ti oxide antibacterial film by magnetron sputtering, mainly comprising the steps of: 1) carrying out pretreatment on the surface of film carrier base material, sequentially washing by more than two organic solvents and deionized water under the condition of ultrasonic wave, the washing time by using the organic solvents and the deionized water being 5-15min, and finally, drying at 15-85 DEG C for 0.5-3h under the vacuum condition; 2) arranging a metal Ti target and a metal Ag target on a magnetron sputtering device, taking argon as working gas, filling reaction gas containing oxygen into a vacuum chamber of the magnetron sputtering device, sputtering the metal Ti by an intermediate frequency magnetron sputtering power supply of the magnetron sputtering device, sputtering the Ag by the magnetron sputtering power supply, and obtaining Ag-Ti metal oxide composite coating film. The method is simple and efficient, and the obtained film has high uniformity, good dispersibility and strong adhesive force, so as to be taken as antibacterial material which has the advantages of broad spectrum, high efficiency, permanent antibacterial performance, safety and environmental protection.

The invention discloses a making method of Li-La-Ti oxide in the lithium ion battery domain, which comprises the following steps: adopting lithium nitrate, lanthanum nitrate and butyl titanate as raw material with molecular formula as Li3xLa2 / 3-xTiO3 (0<x<0.16); setting the molar rate of Li, La and Ti at 1: 1: 2; adopting alcohol or ethylene glycol monomethyl ether as solvent; or adjusting pH value under 1 through water and acetate; drying solution; sintering under 800-900 deg.c for 2h; obtaining pure LLTO. the invention shortens experimental period and synthesizing temperature with grain size about 200nm, which possesses excellent compact and electric property.

The invention discloses a fuel oil deep-adsorption desulfurizationn catalyst. The desulfurizationn catalyst is characterized by consisting of an active component, a sulfur adsorbent and an adhesion agent, wherein the active component refers to one or more of Ni, Co, Cu, W and Mo oxides; the sulfur adsorbent refers to at least one of Mg, Ca, Zn, Ce, Fe, Mn and Ti oxides; the mass percent content of the active component is 2wt%-50wt%, the mass percent content of the sulfur adsorbent is 20wt%-90wt%, and the mass percent content of the rest components is the adhesion agent. The adhesion agent is one or a mixture of more than one of aluminium oxide, pseudo-boehmite, kaolin, imvite, bentonite, Yunmeng soil, kieselguhr, silica sol, silica gel and expanded perlite. The catalyst has the advantages of high specific surface area, moderate reaction, high intensity and low hydrogen consumption.

The invention relates to a metal titanium surface titanium oxide nanowire film and the preparation method. The component of the prepared film can be titanate, titanic acid or titanium dioxide, the diameter of the nanowire is between 10nm to 100nm, the nanowires are interlaced and winded to form a great amount of large holes and mesopore networks, and the pore space is between 20nm to 500nm. The main procedures of the preparation method are: firstly, pickling cleaning of the metal titanium surface; secondly, mixed oxidizing solution of strong alkali and oxydol is used to oxidize the metal titanium surface and to form the titanate nanowire film; thirdly, acid soaking is adopted to exchange alkaline metal ions to form the titanic acid nanowire film; fourthly, the titanium dioxide nanowire film is formed through high temperature torrefying. The preparation method of the metal titanium surface titanium oxide nanowire film of the invention is simple, the cost is low, the method is suitable for large-scale industrial production, and the prepared titanium oxide has the application prospect in photochemical catalysis related field and the electrochemistry sensing related field.

An ornamental article 1 has: a plastic material substrate 2; a first film 3 on the substrate 2 and made of a made of a material containing at least one substance selected from the group made of Cr, Ti, compounds of Cr, and compounds of Ti; and a second film provided adjacent to the surface of the first film that is on the opposite side of the side that faces the substrate and made of a material containing at least one metal selected from the group made of Ag and Al. It is preferred that the first film 3 contain at least one substance selected from the group made of Cr, Ti oxide, and Cr oxide. It is also preferred that the sum of the average thicknesses of the first film 3 and second film 4 be from 0.02 to 2.5 micrometers.

This flux cored wire contains CaF2 and the like with the total content α of CaF2 and the like being 3.3-6.0% by mass relative to the total mass of the flux cored wire; contains Ti oxide and the like with the total content β of Ti oxide and the like being 0.4-1.2% by mass relative to the total mass of the flux cored wire; and contains CaCO3 and the like with the total content of CaCO3 and the like being 0.1-0.5% by mass relative to the total mass of the flux cored wire. The content of iron powder in the flux is less than 10% by mass relative to the total mass of the flux cored wire.

The invention discloses a method for preparing a spherical titanium oxide niobate anode material in a large scale by utilizing a spray drying method and application thereof to a lithium ion battery. The method comprises: 1, dispersing and dissolving a titanium source and a niobium source in an equal molar ratio in a solvent system, and sufficiently stirring to enable the titanium source and the niobium source to be uniformly dispersed; 2, spraying out the mixed solution in a spray dyer according to a certain flow, and drying obtained powder in an oven to obtain a precursor; 3, calcining the precursor in a high-temperature furnace in the air atmosphere at a temperature of 800 to 1,400 DEG C so as to obtain the spherical TiNb2O7 anode material. The spherical titanium-niobium composite oxide TiNb2O7 prepared by the method has excellent electrochemical performance, and has high coulombic efficiency and reversible capacity and excellent high-rate charge / discharge performance and safety performance when being used as a lithium ion battery anode material. The spherical titanium oxide niobate anode material is low in raw material cost, is non-toxic and harmless, and has a very wide application prospect.

Disclosed is a basic flux cored wire having a mild steel or an alloy steel sheath filled with flux, characterized in that the flux essentially consists of, with respect to the total weight of the wire: 0.3 to 3.0% Ti and Ti oxide (TiO2-converted value); 1.0 to 2.5% Si and Si oxide (SiO2-converted value); 0.1 to 1.5% Mg and Mg oxide (MgO-converted value); 1.5 to 4.0% Mn and Mn oxide (MnO-converted value); 0.2 to 1.5% Al and Al oxide (Al2O3-converted value); 0.1 to 1.0% Zr and Zr oxide (ZrO2-converted value); 0.2 to 3.5% CaF2; and 0.01 to 0.5% K2O, with the proviso that the components satisfy the basicity of 0.5 to 4.5 in the basicity equation (1) defined as B=(CaF2+MgO+MnO+K2O) / (TiO2+SiO2+Al2O3+ZrO2). The basic flux cored wire of the present invention is excellent in crack resistance and low temperature toughness, and exhibits excellent welding workability in all welding positions, ensuring an improvement in the efficiency of welding work. Furthermore, the basic flux cored wire according to the present invention exhibits excellent welding workability even under a shield gas of 100% CO2.

A high-toughness steel welded with high linear energy (More than 50 KJ / cm) and resisting molten zinc corrosion is prepared through converter smelting at 1250-1320 deg.C, vacuum treating, and rolling at 1000-1180 deg.c or lower than 950 deg.C and cumulative drafts rate is greater than or aqual to 50%. It features that composite Ti oxide is used to resist high linear energy, the Nb, V, etc. and used for raising strength, and the Cu, Ni, B and RE are used to resist molten zinc corrosion. Its advantages are simple technology with high efficiency, low cost, and high performance of finished steel.

To provide a visible light responsible Ti oxide film which has hydrophilicity and antifogging property and is excellent in transparency and which has an ability to decompose gas by UV radiation, and a process for its production, as well as a Ti oxide film-coated substrate. A Ti oxide film formed on a substrate, characterized in that when a voltage is applied to the Ti oxide film while the Ti oxide film is irradiated with light of a xenon lamp having a luminance of 100 mW / cm2 and having ultraviolet light of less than 400 nm cutoff, the electric current value is at least 1,000 times the electric current value when the same voltage as said voltage is applied to the Ti oxide film in a dark place.

A process of preparing coating positive pole for electrolyzation. The coating positive pole bases Ti. Middle layer is oxide Ti. Outside layer is Pt or Pt-Ru oxidate. The coat can be obtained by way of electrochemical oxidation or heat decomposition.

The invention provides a high-activity nano-grade flue gas denitrification catalyst for removing nitric oxides in fuel gas under a low temperature condition, and a low-temperature liquid-phase preparation method of the high-activity nano-grade flue gas denitrification catalyst. The method does not relate to high-temperature roasting; and the prepared catalyst exists in a manner of a lot of amorphous state mixed oxides, and the activity is obviously improved. The high-activity nano-grade flue gas denitrification catalyst can be widely applied to selective catalytic reduction reaction of the fuel gas under an SO2-free or low-concentration SO2 environment of the fuel gas, so as to reduce the nitric oxides in the fuel gas into N2 and H2O. The catalyst takes a Ti oxide as a main component and is at least loaded with Mn-Ce-M-Ti-Ox of compound oxides of active components Mn and Ce, wherein M represents one or more elements of Fe, Co, Cu, Cr, Zr, Al and V; and the mol ratio of the elements is as follows: Ti: Mn: Ce: M is equal to 1: (0.005-1): (0.005-1): (0-0.3).

Disclosed is a steel for machine structural use having good machinability and chip-breakability as well as a method of producing the steel. The steel consists essentially of, by wt.%, C: 0.05-0.8%, Si: 0.01-2.0%, Mn: 0.1-3.5%, S: 0.01-0.2%, Al: 0.001-0.020%, Ca: 0.0005-0.02%, O: 0.0005-0.01% and N: 0.001-0.04%, and further, one or both of Ti: 0.002-0.010% and Zr: 0.002-0.025%, the balance being Fe and inevitable impurities. At production of the steel controlled deoxidization is conducted by operation meeting certain conditions so that at least a certain amount of ''duplex inclusion'' having a specific chemical composition may be formed, and Ti and / or Zr is added to precipitate finely dispersed MnS inclusion particles with nuclei of Ti-oxide and / or Zr-oxide. The finely dispersed MnS inclusions must share a determined part of the total sulfide inclusions.

The invention relates to a honeycomb manganese denitration catalyst and a preparation method thereof. The method includes the following steps that manganese salt and a complexing agent are dissolved in water, titanium dioxide is added and stirred, ultrasonic dipping, drying and grinding are conducted, and Mn-Ti oxide solid particles are obtained, wherein the molar ratio of the manganese salt to the complexing agent is (65-187):1; metal salt and cerium salt are dissolved in water to obtain a mixed metal solution, wherein metal salt is at least one of ferric salt, cobalt salt, lanthanum salt, antimony salt and nickel salt; a pore-forming agent, an adhesive, an extrusion aid, a reinforcing agent, the Mn-Ti oxide solid particles and the mixed metal solution are mixed and formed into a honeycomb blank, and drying and forging are conducted. The catalyst is good in active component dispersity, is not easily sintered, good in pore structure, large in porosity and high in mechanical strength, the axial compressive strength of the catalyst is 4.7-5.1 MPa, and the radial compressive strength of the catalyst is 1.2-1.4 MPa. The porosity of the catalyst is 84-90%. The catalyst prepared through the method has relatively high denitration activity in the range of 120-250 DEG C and is suitable for low-temperature denitration.

The invention discloses a low-temperature catalyst. The low-temperature catalyst comprises one or more lanthanide series metal oxides and / or one or more transition metal oxides and / or one or more alkali or alkaline earth metal oxides, and also comprises copper and iron molecular sieve catalysts. The one or more lanthanide series metal oxides are selected from La, Ce, Zr and Nb oxides and have a use ratio of 1-50wt%. The one or more transition metal oxides are selected from Fe, Co, Ni, Cu, Mn, Zn, V, W, Mo and Ti oxides and have a use ratio of 1-50wt%. The one or more alkali or alkaline earth metal oxides are selected from Li, K, Cs, Ba, Sr and Ca oxides and have a use ratio of 1-30wt%. The copper and iron molecular sieve catalysts comprise aluminosilicate zeolite and / or aluminum phosphate molecular sieves. Through loading the one or more composite oxides on the copper and iron molecular sieve catalysts, the oxidizing agent for oxidizing NO into NO2 is obtained and reaction activity of whole SCR is improved.

A Cu / ceramic material joint according to the present invention is produced by joining a copper member comprising copper or a copper alloy to a ceramic member comprising AlN or Al2O3 using a joint material containing Ag and Ti, wherein a Ti compound layer comprising a Ti nitride or a Ti oxide is formed at the joint interface between the copper member and the ceramic member, and Ag particles are dispersed in the Ti compound layer.

According to the present invention, there are provided lithium titanate particles which exhibit an excellent initial discharge capacity and an enhanced high-efficiency discharge capacity retention rate as an active substance for non-aqueous electrolyte secondary batteries and a process for producing the lithium titanate particles, and Mg-containing lithium titanate particles. The present invention relates to lithium titanate particles with a spinel structure comprising TiO2 in an amount of not more than 1.5%, Li2TiO3 in an amount of not less than 1% and not more than 6%, and Li4Ti5O12 in an amount of not less than 94% and not more than 99% as determined according to Rietveld analysis when indexed with Fd-3m by XRD, and having a specific surface area of 7 to 15 m2 / g as measured by BET method, a process for producing lithium titanate particles comprising the steps of adding and mixing a water-soluble lithium solution into a water suspension of an oxide of titanium having a BET specific surface area of 40 to 400 m2 / g and a primary particle diameter of 5 to 50 nm and subjecting the resulting mixed suspension to aging reaction at a temperature of 50 to 100° C.; subjecting the resulting reaction product to filtration, drying and pulverization; and subjecting the obtained dry particles to heat-calcination treatment at a temperature of 550 to 800° C., and Mg-containing lithium titanate particles having a composition represented by the formula: LixMgyTizO4 wherein x, z>0; 0.01≦y≦0.20; 0.01≦y / z≦0.10; and 0.5≦(x+y) / z≦1.0, the Mg-containing lithium titanate particles having a BET specific surface area of 5 to 50 m2 / g, a spinel single phase as a crystal structure, and a lattice constant (a) represented by a value of 0.050y+8.3595<a≦0.080y+8.3595 (Å).

A 590 MPa-class rolled steel shape of high strength and excellent toughness for use as a building structural member and a method of producing the high-tensile rolled steel shape are provided. Strength optimization by an alloy that elevates hardenability, texture refinement obtained by fine dispersion of Ti oxides and TiN owing to Ti addition, precipitation strengthening by Cu addition, and formation of a fine bainite texture by temperature-controlled rolling, cooling control and the like enable a high-strength, high-toughness rolled steel shape of high-strength and excellent toughness having mechanical properties of a tensile strength of not less than 590 MPa, a yield strength or 0.2% proof strength of not less than 440 MPa and a Charpy impact absorption energy at 0° C. of not less than 47 J, and method of producing the same.

Disclosed is a method for producing a catalyst for removing nitrogen oxides which comprises dispersing a hydrated titanium (Ti) oxide or dried material thereof, tungstic acid or a salt thereof, and cerium (Ce) dioxide in a dispersion medium to form a sol-like material, mixing the sol-like material with an aqueous medium to form a catalyst slurry or paste, supporting the catalyst slurry or paste on a catalyst carrier, and then calcinating the carrier; in which catalyst the Ce dioxide is prevented from being embedded in the Ti oxide to realize such a high degree of dispersion of the Ce dioxide on the surface of the Ti oxide as comparable with the case wherein cerium ions are dispersed in micro voids of a zeolite by ion exchange; and the catalyst is free from the occurrence of such phenomena as sintering of the Ti oxide, and deterioration of zeolite with steam when a zeolite is used as carrier.

In a flux-cored wire according to the present invention, CaF2 and the like are included and a total amount thereof α is 3.3 to 6.0% in terms of mass % with respect to a total mass, Ti oxide and the like are included and a total amount thereof β is 0.4 to 1.2% in terms of mass % with respect to the total mass, CaCO3 and the like are included and a total amount thereof is 0.1 to 0.5% in terms of mass % with respect to the total mass, and an amount of an iron powder in the flux is less than 10% in terms of mass % with respect to the total mass.

The flux cored wire comprises, with respect to the total weight of the wire, a Ti and a Ti oxide of 3.0 wt % to 8.0 wt % as calculated in terms of TiO2 content, a Si and a Si oxide of 0.5 wt % to 2.0 wt % as calculated in terms of SiO2 content, a metal Mn and an alloy of Mn of 1.5 wt % to 3.5 wt % as calculated in terms of Mn content, a carbon (C) of 0.02 wt % to 0.10 wt %, an Mg and an Mg oxide of 0.5 wt % to 1.5 wt % as calculated in terms of MgO content, a compound of Na2O and K2O of 0.2 wt % and less, a Zr and a Zr oxide of 0.1 wt % to 0.5 wt % as calculated in terms of ZrO2 content, and an Al and an Al oxide of 0.2 wt % to 0.8 wt % as calculated in terms of A12O3 content.

[PROBLEMS] To develop metal microparticles useful in dye-sensitized solar cell, etc. and to provide a photoelectric transducer capable of exhibiting enhanced release voltage in dye-sensitized solar cell.[MEANS FOR SOLVING PROBLEMS] There are provided modified titanium oxide microparticles comprised of titanium oxide and one or two or more types of nontitanic metal oxides (including silicon oxides) selected from the group consisting of periodic-table group IB oxides, group IIA oxides, group IIB oxides, group IIIA oxides, group IIIB oxides, group IVA oxides other than titanium oxides, group IVB oxides, group VIA oxides, group VIII oxides and vanadium oxides.Further, there is provided a photoelectric transducer making use of the modified titanium oxide microparticles.

The invention discloses a catalyst for oxidizing and synthesizing dimethoxymethane by methyl alcohol. The catalyst for oxidizing and synthesizing dimethoxymethane by methyl alcohol consists of vanadium oxide serving as a main catalytic active component, titanic oxide serving as an auxiliary catalytic active component and auxiliary metallic oxide with the composition in mass percentage: 6-60wt% of V2O5, 40-95wt% of TiO2 and 0-55wt% of auxiliary metallic oxide. The catalyst for oxidizing and synthesizing dimethoxymethane by methyl alcohol, which is provided by the invention, has the advantages of simple method, mild reaction condition, good stability, easiness in reproducibility, and high dimethoxymethane selectivity and methyl alcohol conversion rate.

According to one embodiment, a secondary battery is provided. The secondary battery includes a positive electrode, a negative electrode, and an electrolyte solution. The negative electrode includes a negative electrode current collector including elemental zinc, and a negative electrode layer disposed on the negative electrode current collector. The negative electrode layer includes a negative electrode active material including at least one compound selected from the group consisting of an oxide of titanium, a lithium-titanium oxide, and a lithium-titanium composite oxide. The electrolyte solution includes an aqueous solvent and an electrolyte.