The invention provides a carbon-carrying core-shell type platinoid-
platinum catalyst for indirect electrolytic
hydrogen production and a preparation method of the catalyst. The preparation method comprises the following steps: using
graphite fiber as a carbon carrier, carrying out ultrasonic cleaning with analytically pure
acetone, carrying out
ion beam cleaning under a vacuum environment, and carrying out conventional multi-target
ion-beam
sputtering deposition to obtain carbon-carrying nanocrystalline film catalyst; and soaking in H2SO4 solution, carrying out ultrasonic cleaning with deionized water, and carrying out constant temperature dry-out treatment in a vacuum environment to obtain the carbon-carrying core-shell type platinoid-
platinum catalyst for indirect electrolytic
hydrogen production, wherein the Pt content and the Cu content on the carbon carrier of the obtained catalyst are 0.190-0.200mg / cm2 and 0.030-0.080mg / cm2 respectively; and the
mass ratio of unit area carbon carrier and reactive
metal Pt carried on the carbon carrier is (1,000-1,842):1, and the
mass ratio of Pt and Cu carried on unit area carbon carrier is (2.5-6.3):1. According to the invention, the binding of the catalyst particles with the carbon carrier is enhanced, and the catalyst is more stable, so as to improve
catalysis efficiency and reduce the usage of noble metals.