The invention relates to the field of
high polymer material synthesis, in particular to a preparation method of degradable heat-resistant
copolyester. The method comprises the following steps: addingterephthalic acid,
sebacic acid, 1, 4-
butanediol and an esterification catalyst into a reaction kettle for
esterification reaction, entering a polycondensation stage after the reaction reaches an esterification end point, adding the polycondensation catalyst, heating while reducing the vacuum degree of a
system, reacting until the torque of a motor does not rise to the polycondensation end point,stopping the vacuum of the
system, and blowing
nitrogen for cooling, then adding
polylactic acid, melting, then starting to dropwise add a chain
extender hexamethylene diisocyanate, and carrying out chain extension to the maximum value of the
motor torque, thus obtaining the block degradable heat-resistant
copolyester PBSeT-HDI-PLA. According to the invention, PBSeT is used as a matrix, and the
heat resistance of a sample is controllably adjusted by changing the
mass ratio of PBSeT to PLA and the content of a chain
extender. While the biodegradability is ensured, the thermodynamic property ofthe product is improved, and the
mechanical strength of the product is high. The
vicat softening point is increased by 16 DEG C compared with the
vicat softening point before modification, and the
heat resistance is greatly improved.