The invention relates to a preparation method of amino modified Fe3O4@SiO2@mSiO2 composite particles with a mesoporous structure. The preparation method comprises the steps: dispersing Fe3O4@SiO2
powder into a mixture solution of
ethanol, deionized water,
ammonia water and a template agent, so as to obtain a
sol solution; then, dropwise adding TEOS into the
sol solution, so as to prepare Fe3O4@SiO2@mSiO2 composite particles with the mesoporous structure;
drying the Fe3O4@SiO2@mSiO2 composite particles, then, adding
ethylene glycol into the dried Fe3O4@SiO2@mSiO2 composite particles, carrying out ultrasonic separation, then, adding a
silane reagent, carrying out high-temperature refluxing while carrying out stirring so as to enable the
silane reagent to be adsorbed into mesoporous pore passages of SiO2, carrying out a hydrolytic reaction, removing unreacted
silane reagent or the silane reagent which is not adsorbed into the mesoporous pore passages, and finally, carrying out
vacuum drying, thereby obtaining the amino modified Fe3O4@SiO2@mSiO2. According to the preparation method, SiO2 with a mesoporous structure serves as a shell layer, a
nanoparticle Fe3O4 serves as a
magnetic core, the stability in an acidic
solution system is excellent, the difficult problem of the ordinary adsorbents that the separation is difficult after adsorption can be solved, the efficiency of adsorbing a target product is increased, and the
reuse rate of an adsorbent is increased, so that the preparation method has good economic and environmental benefits.