The invention discloses a method for efficiently preparing an ex-situ presulfuration agent through a medium-pressure solvothermal method, and belongs to the technical field of organic multi-
sulfur-
ether mixed vulcanizing agent synthesis of ring-free unsaturated carbon skeletons. The synthesis method includes the following steps of adding elemental
sulfur and
solvent into a reaction kettle, raising the temperature to be 145-160 DEG C, continuing to conduct stirring for 0.5 h, slowly adding isobutene into the reaction kettle, controlling the pressure at 3.0-3.5 MPa, conducting reacting for 3-6 h at a constant temperature, cooling to 35 DEG C after the reaction ends, and pressing the reaction mixture out of the reaction kettle through overbottom pressure. After standing and liquid distribution are conducted on the product, a certain amount of 120#
gasoline or methylbenzene is added, filtering, washing,
backflow and
distillation are conducted on the organic phase, the ex-situ presulfuration agent is obtained, and fresh
solvent can be compensated for till reaching the existing concentration to be recycled after the inorganic phase is analyzed.
Ammonia water solutions of different concentrations serve as
solvent. The method has the advantages of being low in cost, high in product yield, free of
pollution, low in device requirement, and the like, solves the problems in the prior art, and breaks through technology monopoly for the ex-situ presulfuration agent at home and abroad.