A core-shell structure poly-2,3-dimethylaniline / polyaniline conductive composite material and its preparation method, the structure of the composite material is poly-2,3-dimethylaniline as the core and polyaniline as the core of the shell It has a shell structure, and its preparation method is to firstly prepare poly-2,3-dimethylaniline by solution polymerization, and obtain its powder after suction filtration, washing, drying and grinding. Then use powdered poly-2,3-dimethylaniline as the core, and polymerize on its surface by solution polymerization or emulsion polymerization. After the product is filtered, washed, dried, and ground, the core-shell structure poly-2 , 3-Dimethylaniline / polyaniline conductive composites. The core-shell structure poly 2,3-dimethylaniline / polyaniline conductive composite material provided by the present invention significantly improves the conductivity of poly 2.3-dimethylaniline, which is beneficial to its application in sensors, conductive components, electrode active materials, etc. field applications.