The invention discloses a preparation method of a
titanium complex with high catalytic activity. The preparation method comprises the steps of: adding
tetraisopropyl titanate in an agitated reactor, finishing dropwise adding
triethyl citrate under the condition of stirring within half of an hour, continuously stirring for half of an hour; finishing dropwise adding
ethyl acetoacetate within 2-2.5hours, continuously stirring for reacting for 1hour; evaporating generated isopropanol under negative pressure, adding 1,2-
propylene glycol in the evaporated generated isopropanol, stirring for reacting for 1 hour, and evaporating isopropanol remained in a
system under the negative pressure to obtain a semi-finished product of the
titanium complex; and adding organic
tin in the semi-finished product of the
titanium complex and compounding a
solvent to obtain a finished product. The preparation method provided by the invention has the advantages of simplicity in operation, low cost, light product color, higher purity of the isopropanol as a
side product, stable quality of the finished product, high catalytic activity, difficulty in
crystallization, and longer service life of the catalyst.