514 results about "Cumene" patented technology

The present invention provides a process for producing a monoalkylated aromatic compound, particularly cumene, comprising the step of contacting a polyalkylated aromatic compound with an alkylatable aromatic compound under at least partial liquid phase conditions and in the presence of a transalkylation catalyst to produce the monoalkylated aromatic compound, wherein the transalkylation catalyst comprises a mixture of at least two different crystalline molecular sieves, wherein each of said molecular sieves is selected from zeolite beta, zeolite Y, mordenite and a material having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom.

The present invention provides a process for producing a monoalkylated aromatic compound, particularly ethylbenzene or cumene, in which a polyalkylated aromatic compound is contacted with an alkylatable aromatic compound in the liquid phase and in the presence of a transalkylation catalyst comprising TEA-mordenite having an average crystal size of less than 0.5 micron.

Catalysts for converting polyalkylaiomatics to monoalkylaromatics, particularly cumene and ethyl benzene are disclosed which comprise modified Y-85 or LZ-210 zeolites. For cumene and ethylbenzene production, a disclosed catalyst, made of 80 wt % zeolite and 20 wt % alumina binder on a volatile-flee basis, has one or more of the following physical characteristics: (1) an absolute intensity of the modified Y zeolite as measured by X-ray diffraction (XRD) of preferably at least 50 and (2) a framework aluminum of the modified Y zeolite of preferably at least 50% of the aluminum of the modified Y zeolite.

A process for the regeneration of materials used in the guard beds preceding the reactors used in an olefin conversion process which converts olefinic refinery streams to higher boiling hydrocarbon products by polymerization (oligomerization) or alkylation of aromatics including benzene. Products of the process may include olefin oligomers and alkylaromatics in the gasoline boiling range as well as alkylaromatic petrochemicals such as cumene and ethylbenzene. The process is integrated with the olefin conversion process to ensure continuous operation of the olefin conversion without sending the feedstock containing the contaminant(s) to the reactor. The process uses reaction products from the olefin conversion process to regenerate the guard bed material and so is economically attractive since it does not require the use of separate purge, regeneration feed and separation systems. A plurality of guard beds is used, each containing a material which removes catalyst poisons. The guard beds are operated on a swing system in which one or more beds is kept on stream to remove the contaminant(s) while one or more of the remaining beds is being purged or regenerated. In this way, continuity of operation is assured. The regeneration medium is a product stream from the olefin conversion process.

The invention discloses a radiation-resistant halogen-free low smoke flame retardant insulating material for cables of nuclear power plants and a preparation method. The radiation-resistant halogen-free low smoke flame retardant insulating material is prepared from the following raw materials: ethylene propylene diene rubber, phenyl siloxane rubber, magnesium hydrate, aluminium hydroxide, zinc borate, white carbon black, cerium dioxide, zinc oxide, Bis(tert-butyldioxyisopropyl)benzene, tri allyl cyanurate, 2-mercaptobenzimidazole, 2,2,4-trimethyl-1,2-dihydroquinoline, Aflux A-25, stearic acid, vinyl tris(beta-methoxyethoxy) silane, and paraffin oil by heating and mixing. The formulation and the mixture ratio are scientific and reasonable, and the process is advanced. The prepared insulating material has good radiation resistance, excellent mechanical property, good electrical property and long service life, and is a good radiation-resistant halogen-free low smoke flame retardant insulating material for manufacturing the cables of the nuclear power plants.

A process for the catalytic alkylation of an aromatic substrate with an alkylating agent is disclosed that comprises contacting the aromatic substrate and the alkylating agent in sequential alkylation zones to obtain an alkylaromatic. The first catalyst comprises UZM-8 zeolite and the second catalyst comprises beta zeolite. The process is particularly well suited for the alkylation of benzene with propylene to produce cumene.

A process for producing cumene comprising converting plastics to hydrocarbon liquid and pyrolysis gas; feeding hydrocarbon liquid to hydroprocessor to yield hydrocarbon product and first gas stream; feeding hydrocarbon product to reforming unit to produce reforming product, second gas stream, and hydrogen; separating reforming product into non-aromatics recycle stream and second aromatics stream (C6+ aromatics); recycling non-aromatics recycle stream to reforming unit; separating second aromatics stream into benzene, C7, C8, C9, C10, and C11+ aromatics; contacting C7, C9, and / or C10 aromatics with a disproportionation&transalkylation catalyst / H2 to yield benzene&xylenes; conveying C11+ aromatics to hydroprocessor; introducing pyrolysis gas, first and / or second gas stream to first separator to produce first propylene stream, first C2&C4 unsaturated stream, and saturated gas (H2 and C1-4 saturated hydrocarbons); introducing first C2&C4 unsaturated stream to metathesis reactor to produce second propylene stream; and feeding benzene, and first and / or second propylene stream to alkylation unit to produce cumene.

A process for converting carbonyl-type impurities contained in a phenolic solvent to high-boiling derivatives is provided by contacting the phenolic solvent with a hydrotalcite-type material (HTM). The phenol can be separated from the high-boiling derivatives using conventional separation techniques, such as distillation, so the invention also provides a process for separating carbonyl-type impurities, such as hydroxyacetone (HA), from a phenolic solvent. The process can be applied in the conventional industrial process for converting cumene to phenol to remove carbonyl-type impurities from the phenol product. A process and a facility for producing purified phenol by converting cumene to phenol are provided. In the conversion of cumene to phenol, the phenol often contains carbonyl-type impurities. The phenol and carbonyl-type impurities are reacted in the presence of an HTM to produce phenol and high-boiling derivatives. The phenol may be further purified using conventional separation techniques, such as distillation, to remove the high-boiling derivatives.

The invention discloses a novel method for recovering and treating oxidized exhaust gas generated in phenol production, which comprises the following steps: adopting deep cooling to achieve liquefaction separation of organic matters by reducing the temperature of the exhaust gas to below 5 DEG C, wherein the material recovery rate reaches more than 95 percent; and adopting a Pt catalyst to decompose residual total hydrocarbons and cumene in the exhaust gas at a temperature of between 220 and 450 DEG C to achieve emission after reaching standards. The method can improve the exhaust emission quality, recover effective components in the exhaust gas, and reduce the device loss rate and the device material consumption on the basis of raw water cooling and activated carbon adsorption.

A process for the alkylation of aromatics with olefins using a solid catalyst bed containing UZM-8 zeolite is disclosed. A polyalkylated aromatic is passed to the catalyst bed to reduce the concentration of the olefin at alkylation conditions. A portion of the effluent recovered from the catalyst bed may be recycled to the catalyst bed. Such operation can decrease the catalyst deactivation rate and the formation of diphenylalkanes. The process disclosed herein is applicable to processes for the production of a wide variety of commercially important alkylated aromatics, including ethylbenzene and cumene.

A projectile can be used to administer pesticides such as one or more from the group consisting of 4-allylanisole, anisole, allylbenzene, 4-isopropylanisole, p-anisaldehyde, ethylbenzene, cumene, 4-methoxyacetophenone, 4-methylstyrene, 2-propylphenol, phenetole, and toluene, for scolytid infestation. Conifers, which are a target for scolytids, are protected by the application of the pesticides by use of a projectile containing the compound which explodes upon contact with the conifer thereby emitting the compound.

A process for preparing hydroperoxides which comprises oxidizing hydrocarbon by a gas containing oxygen in the presence of a specific compound and converting them selectively to corresponding hydroperoxides. The specific compound is the compound that can capture radicals. The preferable example may be a compound selected from radicals of oxygen, nitrogen, phosphorus, sulfur, carbon or silicon or a compound that forms radicals of these in the reaction system. The present invention can be applied to oxidation of hydrocarbons including arylalkylhydrocarbons such as cumene, m-diisopropylbenzene, p-diisopropylbenzene, 1,3,5-triisopropylbenzene, isopropylnaphthalene, diisopropylnaphthalene, isopropylbiphenyl, diisopropylbiphenyl, etc.

A process for converting polyalkylaromatics to monoalkylaromatics, particularly cumene, in the presence of a modified LZ-210 zeolite is disclosed. The process attains greater selectivity, reduced formation of undesired byproducts, and increased activity.

A continuous method of cumene oxidation in a gas-liquid system is provided, where the liquid phase is represented by cumene and its oxidation products and the gas phase is represented by air. The oxidation process can be carried out either in a reactor series or in a single reactor at least one of which is preferably equipped with at least two airlift-type trays. When specific CHP concentration is achieved, the oxidation products are discharged from the to reaction zone and treated in a mixing device with aqueous ammonia or water to remove organic acids such as formic acid, benzoic acid, etc. and to remove phenol, which is an inhibitor of oxidation reaction. The cumene oxidation product stream, free of organic acids and phenol is recycled to the same reactor in the case of single reactor, or is passed to the next reactor of the series in the case of reactor series. In all cases, the oxidation products treated with water or aqueous ammonia is first directed to a unit for separation of aqueous phase from organic products and then anhydrous organic product stream is forwarded to the next reactor of the series, or recycled to the single reactor for the continued cumene oxidation until the required CHP concentration is achieved. The airlift-type trays in at least one process reactor accelerate the cumene oxidation reaction therein while increasing the process selectivity and enabling the process to be conducted at lower temperature, improving safety thereof. Advantageously, lower quality cumene having impurities such as sulfur-containing trace elements, can be used in the inventive process while maintaining a high process selectivity.

A process for producing an cumene product having a purity of at least 99.50 percent based on the weight of cumene present in the product by the propylation of the benzene present in non-extracted hydrocarbon composition feed, e.g., non-extracted reformate. The non-extracted hydrocarbon composition feed is substantially free of both C4− hydrocarbons and the C7+ aromatic hydrocarbons and contains benzene and benzene coboilers. The process is carried out in the liquid phase, in the presence of an acid-active catalyst containing MCM-22 family molecular sieve, and under specified conditions.

A process for converting polyalkylaromatics to monoalkylaromatics, particulary cumene, in the presence of a modified Y-85 zeolite is disclosed. The process attains greater selectivity, reduced formation of undesired byproducts, and increased activity.

This invention relates to a method of directly catalyze epoxide. In existing technology takes low concentration H2O2 water solution as oxidizer, phosphorus tungsten heteropoly acid quaternary ammonium salt as catalyzer to prepare epoxide. This invention mainly solve the problem in existing technology of separation energy high caused by water, as well as catalyst stability low caused by decompound of phosphorus tungsten heteropoly acid quaternary ammonium salt, and problem of H2O2 activity factor descending. This invention takes olefine, cyclenes or aromatic alkene contain 1 to 10 carbon atom and aqueous hydrogen peroxide solution as raw material, takes phosphorus tungsten heteropoly acid quaternary ammonium salt as catalyzer, takes at least one of toluene, benzene, ethylbenzene, cumene , chloroform or tributyl phosphate as solvent, takes phosphatic inorganic salt as additive, under 20 to 100deg reaction temperature and 0 to 3.0 Mpa reaction pressure, to carry out reaction for 0.5 to 24 hours. It best solve existing problem, can be used in industrial production of epoxide.

The invention discloses an irradiation resistant non-halogen low smoke flame-retardant sheathing material applied to nuclear power stations and a preparation method. The raw materials comprises ethane-vinyl acetate rubber, maleic anhydride stem grafting ethane-vinyl acetate rubber, magnesium hydroxide fire retardant, organic silicon fire retardant, nano cerium oxide, FEF, zinc stearate, stearic acid, vinyl trisilane, Aflux A-16, Aflux A-25, polycarbonate diimine(PCD-50), 2, 2, 4-trimethyl-1, 2-dihydride quinoline, antiager DDA, di-tert-butyl peroxide cumene, triene propylcyanide uric acid ester and decanedioic acid dioctyl, which are heated and mixed to obtain the materials of the invention. The invention features scientific and reasonable formula and proportion, and the process is advanced. The sheathing material features fine irradiation resistance, excellent mechanical properties and long service life, thus being a good irradiation resistant non-halogen low smoke and flame-retardant sheathing material applied to nuclear power stations.

The invention discloses a synthesis method of 2-phenyl-2-propanol and acetophenone through catalytic oxidation of cumene, the synthesis method includes that firstly, adding the cumene and a solid catalyst into a reactor, forming a suspension through ultrasonic processing, wherein the solid catalyst is nitrogen-doped carbon material, heating the obtained suspension to 40-100 DEG C, introducing oxygen for reaction at constant pressure; after the reaction is finished, separating the reaction mixture to obtain the solid catalyst and a liquid mixture which contains the 2-phenyl-2-propanol, the acetophenone and cumene hydrogen peroxide; and obtaining target products of the 2-phenyl-2-propanol and the acetophenone through separation and purification. The cumene is oxidized at the constant pressure to generate 2-phenyl-2-propanol and acetophenone, the nitrogen-doped carbon material is used as the heterogeneous reaction catalyst, the oxygen is used as oxidant, an operational process is simple, the nonmetal catalyst is free of corrosion, environment-friendly, low in price and capable of being used repeatedly, the conversion ratio of the cumene is relatively high, and the target products are good in selectivity.

The invention discloses a dimethyl benzyl alcohol hydrogenolysis catalyst and a preparation method thereof. The catalyst comprises 35-70wt% of copper oxide, 5-25wt% of zinc oxide, 15-40wt% of silicondioxide, 0.5-15wt% of alkaline earth metal oxide and 0.1-5wt% of bismuth oxide and lead oxide. The preparation method comprises the following steps: (a) adding a mixed solution containing a Cu compound, a Zn compound, an alkaline earth metal compound, a Bi compound and a Pb compound and an alkaline precipitant solution into a silica sol aqueous solution for precipitation reaction and heating aging; (b) filtering, washing, drying and roasting the aged slurry to obtain complex compound powder; and (c) adding a binder, a forming assistant and the like into the complex compound powder, fully mixing, extruding and forming, drying and roasting to obtain the catalyst. When used for preparing cumene by hydrogenolysis of dimethylbenzyl alcohol, the method not only has good activity and selectivity,but also has good liquid resistance and high mechanical stability.

A process for producing a monoalkylation aromatic product, such as ethylbenzene and cumene, utilizing an alkylation reactor zone and a transalkylation zone in series or a combined alkylation and transkylation reactor zone.

The apparatus includes an alkylation unit connected to a first benzene recycle conduit, a feed conduit and an alkylation effluent conduit; a transalkylation unit connected to an polyalkylbenzene recycle conduit, a second benzene recycle conduit, and a transalkylation effluent conduit. A dividing wall distillation column is in fluid communication with the transalkylation effluent conduit, the alkylation effluent conduit, a product stream, a bottoms stream conduit and first and second benzene recycle conduits. A polyalkylbenzene fractionation column is connected to the bottoms stream conduit, the polyalkylbenzene recycle conduit and a heavy component conduit.

The present invention relates to a hot melt adhesive film for adhering a sole. The hot melt adhesive film comprises the following raw materials by weight: 50-60 parts of ethylene-vinyl acetate (EVA), 30-60 parts of modified ethylene-ethyl acrylate (EEA), 15-35 parts of a styrene-butadiene block copolymer (SBS), 5-20 parts of a terpene resin, 0.1-0.5 part of bis-(tertbutylperoxy isopropyl)benzene (BIPB), and 0.1-0.5 part of benzoyl peroxide (BPO). According to the present invention, the hot melt adhesive film does not contain benzene, toluene, xylene and other harmful solvents, the sole does not require the primer treatment, the operation process is simple, and the environmental requirement requirements are met.

The invention relates to an EPDM (ethylene-propylene-diene monomer) composition and a hose, wherein the composition comprises the following components: ethylene-propylene-diene monomer, fast extruding furnace black, Sillitin powder, paraffin oil, magnesium oxide, poly(1,2-dihydro-2,2,4-trimethyl-quinoline), polyethylene glycol, 1,3-bis(tert-Butylperoxy-isopropyl)benzene, and triallyl isocyanurate. The EPDM composition can be used for preparing a hose which has the advantages of excellent high-temperature resistance, electrochemical corrosion resistance and sufficient physical properties, wherein the high-temperature resistance of the prepared hose is shown as follows: the elongation of the hose is minus 7.9 percent after being subjected to thermal aging for 94 hours at the temperature of 170 DEG C, and the permanent deformation rate of the hose is 60 percent after being compressed for 22 hours at the temperature of 120 DEG C; and the electrochemical corrosion resistance of the hose is shown as follows: the volume resistivity is 1*1012 ohm.cm, and the hose has no crack after being subjected to electrochemical degradation for 504 hours at the temperature of 115 DEG C and at a voltage of 12V.

The invention discloses a method for catalyzing and selectively oxidizing cumene into cumene hydroperoxide, which comprises in a mixture of oxidant air, oxygen-enriched air, or of oxygen gas and inertia gas, at an absolute reaction pressure of 0.1 to 1.0 MPa and a reaction temperature of 70 to130 DEG C, using the single metalloporphyrin of a formula (1), mu-oxgen double metalloporphyrin or relative carrier as catalyst at the density of 1 to 80 ppm without additional materials. The metalloporphyrin of low density can effectively and high selectively catalyze air to oxidize cumene into cumene hydroperoxide. The catalyst of the invention has low consumption, low synthesis cost, low catalysis reaction temperature, quick initiation, less byproduct, high selectivity and simple process, while cumene hydroperoxide yield is higher than industrial non-catalysis reaction yield and the reaction time is shorter than industrial non-catalysis reaction.

The invention provides a process for producing a variety renewable aromatic compounds such as benzene, toluene, xylenes, and cumene, as well as compounds derived from these including, for example, aniline, benzoic acid, cresol, cyclohexane, cyclohexanone, phenol and bisphenol A, toluene di-isocyanate, isophthalic acid, phthalic anhydride, terephthalic acid and dimethyl terephthalate. The invention also provides for renewable forms of these aromatic compounds.

The invention relates to 100# lead-free aviation gasoline and a preparation method thereof. The 100# lead-free aviation gasoline comprises, by volume, 10-18% of industrial isopentane, 1-11% of light alkylated oil, 45-55% of industrial isooctane, 15-22% of toluene, 0-4% of m-xylene, 5-11% of cumene, 1.5-5.5% of aniline, 0.5-3.5% of N-methyl aniline and 0-3% of m-toluidine. The components are blended to form the finished product. Compared with the prior art, the 100# lead-free aviation gasoline does not contain lead and solves the problem of lead pollution of aviation gasoline. Through the optimized combination of the components, the 100# lead-free aviation gasoline quality is high and the 100# lead-free aviation gasoline satisfies the quality index requirements. The 100# lead-free aviation gasoline has a high economic value. The 100# lead-free aviation gasoline blending process is simple and is conducive to industrial production.

In an alkylation zone, a benzene recycle stream and a propylene feed stream are contacted with an alkylation catalyst to convert the propylene and benzene into cumene. In a transalkylation zone, a polyisopropylbenzene stream and a benzene recycle stream are contacted with a transalkylation catalyst to convert the polyisopropylbenzene and benzene into cumene. The alkylation and transalkylation zone effluents are passed into a dividing wall fractionation column.A cumene product stream is removed from an intermediate point of the dividing wall fractionation column. A benzene recycle stream is removed from a first end, and another benzene recycle stream is removed from an intermediate point of the dividing wall fractionation column. A polyisopropylbenzene stream is removed from a second end of the dividing wall fractionation column. The polyisopropylbenzene stream is passed to a polyisopropylbenzene fractionation column to separate the polyisopropylbenzene from a heavy ends stream.

The invention relates to lead-free aviation gasoline. The lead-free aviation gasoline contains components as follows: A) 55wt%-90wt% of alkylation unit oil, B) 5wt%-15wt% of pentane component oil, C) 0-20wt% of C7 aromatic component oil, D) 0-15wt% of cumene and E) 0-15wt% of an alkyl ether antiknock agent, wherein the alkylation unit oil is prepared from a reaction product distillate C4 obtained through alkylation of 1-butene and / or 2-butene and iso-butane as well as light components shown in the specification; the content of arylamine compounds in the lead-free aviation gasoline does not exceed 0.5wt%, and further, the lead-free aviation gasoline contains lead which does not exceed 0.01 g / L and contains at least one of the component C and the component D. The gasoline does not contain the arylamine compounds basically, so that environmental pollution caused by the aviation gasoline is greatly reduced, moreover, an octane value and a heat value realize good balance, a net heating value at least reaches 43.5 MJ / kg, and a motor octane value is not smaller than 91.