The invention disclose a method for preparing a hard
alloy by bonding WC group with Ni, which is characterized by comprising the steps that: firstly, the mixing
powder of WC and Ni is subjected to
wet grinding,
drying and pressing in absolute ethyl
alcohol, and then subjected to
vacuum sintering at the temperature of 1440 DEG C to 1480 DEG C; when the
sintering is finished,
nitrogen is introduced to a furnace simultaneously for carrying out vacuum
quenching, the pressure of the
nitrogen is 0.1MPa to 0.4MPa, and the
quenching time is 5min to 10min; after tapping, deep cooling treatment is carried out in
liquid nitrogen, the treatment temperature is 150 DEG C to 196 DEG C, and the heat-preservation time is: the hard
alloy weight multiplied by
weight factor plus the Ni percent content of the hard
alloy weight multiplied by component factor, wherein, the
weight factor is 5min / g to 25min / g and the component factor is 10min to 20 min; and drawing temper is carried out in a
vacuum furnace at the temperature of 120 DEG C to 200 DEG C, the temperature-preservation time is 1h to 3h. By adopting the method for preparing the hard alloy by bonding the WC group with Ni, the contact ratio of the WC can be controlled, the
solubility of the WC in Ni is improved, furthermore, the
surface stress condition of the alloy
after treatment is compressive stress which improves the
shock resistance capability of the alloy, thus being capable of realizing the substitution of Ni to Co and obtaining the performances corresponding to WC-Co series hard alloys.