169 results about "Nanocomposite catalyst" patented technology

The invention discloses a nano-grade composition, a preparation method thereof, and an application thereof as an electrochemical catalyst. The nano-grade composition provided by the invention is basically composed of a melamine derivative, a carbon material, and transition metal or transition metal alloy nano-cluster. The carbon material comprises at least one selected from conductive carbon black, activated carbon, carbon nano-horn, N-doped carbon nano-horn, carbon nano-tube, graphene, graphite and carbon fiber material. The metal nano-cluster is at least one selected from Pt, Ru, Pd, Rh and Ir nano-clusters. The alloy nano-cluster is nano-cluster formed by more than two elements selected from Pt, Ru, Pd, Rh, Ir, Fe, Cu and Ni. The mass percentage content of the transition metal or alloy nano-cluster is 0.1-90%. The size of the transition metal or alloy nano-cluster is 0.5-10nm. As a fuel cell catalyst, the nano-grade composition provided by the invention has excellent electrocatalytic activity upon reactions such as oxygen reduction and methanol oxidation.

A method for preparing a carbon nano tube loaded cobalt-platinum alloy catalyst belongs to the fields of nano composite catalysts and fuel cells. The electrode catalyst of the conventional fuel cell has the problems of uneven grain size distribution of active components, high cost and the like. By using a carbon nano tube working electrode containing a cobalt-platinum based active precursor as a cathode, using a platinum electrode as an anode and using solid-phase electrolysis salt as electrolyte, the carbon nano tube loaded cobalt-platinum alloy catalyst is generated in situ through pulse electro-deposition. The method has the advantages that the method can effectively control the grain size, composition and load of Co-Pt alloy nano grains, has low cost and no pollution, and is suitable for large-scale production and the like.

The present invention relates to a method of methane steam reforming using a nickel / alumina nanocomposite catalyst. More specifically, the present invention relates to a method of carrying out methane steam reforming using a nickel / alumina nanocomposite catalyst wherein nickel metal nanoparticles are uniformly loaded in a high amount on a support via a melt infiltration method with an excellent methane conversion even under a relatively severe reaction condition of a high gas hourly space velocity or low steam supply, and to a catalyst for this method. In addition, the present invention prepares a nickel / silica-alumina hybrid nanocatalyst by mixing the catalyst prepared by the melt infiltration method as the first catalyst and the nickel silica yolk-shell catalyst as the second catalyst, and applies it to the steam reforming of methane to provide a still more excellent catalytic activity even under the higher temperature of 700° C. or more with the excellent methane conversion.

The invention discloses a palladium nano-composite catalyst loaded by N-doped three-dimensional graphene and a preparing method and application thereof. The method includes the steps that a formaldehyde solution and a nitrogen source are added into an oxidized graphene solution, a N-doped three-dimensional graphene composite material is prepared through a hydrothermal method, then a H2PdCl4 solution and a reducing agent are added to obtain the palladium nano-composite catalyst loaded by N-doped three-dimensional graphene, a carrier of the catalyst is graphene of a N-doped three-dimensional structure, loaded active ingredients are palladium nano particles, the loading capacity of the Pd nano particles accounts for 5-15% of the total mass of the catalyst, and the particle size is 5-10 nm. The palladium nano-composite catalyst loaded by N-doped three-dimensional graphene is applied to a Suzuki reaction of halogeno benzene and phenylboronic acid and shows high catalytic activity and high reusability.

The invention belongs to the field of catalyst preparation, and particularly relates to a complex nano-catalyst for preparing synthesis gas by reforming methane and carbon dioxide, and a preparation method thereof. The complex nano-catalyst comprises an active ingredient, an accessory ingredient and a complex carrier, wherein the active ingredient is composed of cobalt oxide and nickel oxide; the accessory ingredient is composed of one or more of potassium oxide, magnesium oxide or lanthanum oxide; the complex carrier is composed of two of nano aluminium oxide, nano zirconium oxide or nano silicon oxide. The preparation method comprises the following steps: preparing a mixed solution; preparing the complex nano-catalyst. The complex nano-catalyst is small in particle diameter of the complex carrier, has high surface energy and surface defects, increases catalyst active sites, activates carbon dioxide to generate active oxygen, assists carbon elimination, reduces the yield of carbon, slightly improves stability of the complex nano-catalyst, and prolongs the use period of the complex nano-catalyst; the preparation method is simple, scientific and reasonable.

The nano composite catalyst is prepared with silver iodide, magnesium, aluminum, copper iodide, sliver iodate or other superfine particle, combustible component, adhesive, curing agent, plasticizer, cross-linking agent, anti-aging agent, speed regulator, etc. and through kneading, deairing and curing. In combustion or explosion, the nano composite catalyst produces composite AgI-NaCl-AgCl-KCl-CuI-NH4I kernels, which possess great specific surface area, high activity, and structure and crystal lattice constant similar to those of ice crystal. The catalyst has high kernel forming rate, fast kernel forming speed, excellent physical and chemical performance, less environmental pollution and easy maintenance and transportation, and is safe and efficient composite catalyst for rain making, preventing hail, eliminating cloud, and other weather modifications.

The invention discloses an enzyme-GO-MOFs nano composite catalyst and a preparation method thereof. The preparation method comprises the following steps: (1) adding a modifier into an enzyme liquid so as to obtain a modified enzyme solution, wherein the modifier is an N-vinyl amide polymer or pluronic F-127; the N-vinyl amide polymer is one or a mixture of more of polyvinylpyrrolidone, poly N-vinyl caprolactam and poly N-ethylene formamide; (2) mixing GO and a metallic salt solution, performing ultrasonic treatment, further adding an organic ligand solution into the mixed solution so as to obtain a GO-MOFs composite material synthesized stock solution, and performing ultrasonic treatment for another time; (3) adding a modified enzyme solution into the GO-MOFs composite material synthesized stock solution, and performing ultrasonic treatment so as to obtain a reaction liquid; (4) centrifuging the reaction liquid, collecting precipitate, washing the precipitate, and performing vacuum drying, thereby obtaining the enzyme-GO-MOFs nano composite catalyst. The preparation method disclosed by the invention is simple and feasible, and the nano composite material catalyst is gentle in synthesis condition and high in protein immobilization rate.

The invention relates to a preparation method of a three-dimensional echinoid ZnS / CdS composite semiconductor photocatalytic nano material, which comprises the following steps: preparing uniform-size echinoid ZnS, and carrying out functional assembly on CdS nanoparticles; and by combining the advantages of ZnS and CdS, preparing the three-dimensional ZnS / CdS echinoid nano composite catalyst by a solvothermal and homogeneous precipitation process. The invention aims to solve the problem of low efficiency in the ZnS photocatalysis. The ZnS / CdS composite semiconductor photocatalytic nano material provided by the invention has a unique three-dimensional echinoid structure, and is composed of hexagonal crystal echinoid ZnS and hexagonal structure CdS nanoparticles. The invention has the advantages of high catalytic activity, low cost, accessible raw materials, simple preparation technique and favorable repetitiveness, and has favorable application prospects.

The present invention belongs to the technical field of electrochemistry, specifically relates to a graphene-platinum (RGO-Pt) nano-composite catalyst for a lithium air battery, and a preparation method thereof. The nano-composite catalyst material is prepared by a liquid phase pulsed laser ablation technology (LP-PLA). With adopting the membrane electrode prepared by the composite catalyst for the lithium air battery anode material, the lithium air battery has good charge-discharge cycle reversibility, the charge-discharge over voltage is significantly decreased, and the reversible specific capacity under the current density of 100 mA / g is more than 4000 mAh / g. The membrane anode material based on the graphene-platinum (RGO-Pt) nano-composite catalyst has characteristics of good chemical stability, high specific capacity, excellent cycle performance and simple preparation method, and is applicable for the lithium air battery.

The invention discloses a nitrogen hybridized carbon nanohorn-graphite nanocomposite, a preparation method thereof and application of the nanocomposite as a catalyst carrier. A nanometer composite catalyst provided by the invention is composed of the nitrogen hybridized carbon nanohorn-graphite nanocomposite and a transition metal and / or transition metal alloy nano-cluster, wherein the mass percentage content of the transition metal and / or transition metal alloy nano-cluster is 0.1 to 80%, the size of the transition metal and / or transition metal alloy nano-cluster is 0.5 to 20 nm, and the transition metal and / or transition metal alloy nano-cluster is dispersed in a porous nanometer network formed by nitrogen hybridized carbon nanohorns and graphite. As a fuel cell catalyst, the nanometer composite catalyst has excellent electrocatalytic activity and stability in reactions like oxygen reduction and methanol oxidation.

The invention discloses a magnetic nano composite catalyst, in particular to a preparation method of a ferrocobalt oxide / graphene magnetic nano composite catalyst and an application of the magnetic nano composite catalyst in degrading organic wastewater. The catalyst acts on sulfate radicals with a strong oxidizing property generated by peroxysulfate and therefore efficiently removes organic matters from the wastewater. The catalyst serving as a solid phase catalyst has larger specific surface area, higher catalytic activity and a lower ion release rate, so that the catalyst can continuously and efficiently activate the sulfate radicals generated by peroxysulfate and effectively reduce cobalt ion leakage. The preparation method of the catalyst is simple; the catalyst has high catalytical performance, does not cause secondary pollution and is an environment-friendly material; since the catalyst is magnetic and can be recycled after reaction, the treatment cost of the organic wastewater is lowered; wide application prospects are provided for the treatment of the degradation-resistant organic wastewater.

The invention discloses a metal organic frame / graphene carried palladium nano-composite catalyst and a preparing method and application thereof. Firstly, anhydrous zirconium tetrachloride, terephthalic acid and N,N-diamide are added in a graphene oxide solution to prepare a metal organic frame / graphene composite; secondly, normal hexane, an H2PdCl4 solution and a reducing agent are added to obtain the metal organic frame / graphene carried palladium nano-composite catalyst, wherein a carrier of the catalyst is composed of the metal organic frame and graphene, palladium nano-particles serve as carried active components, the carrying quantity of the palladium nano-particles accounts for 1-10% of the total mass of the catalyst, and the particle size ranges from 10 nm to 20 nm. The metal organic frame / graphene carried palladium nano-composite catalyst shows high catalytic activity and good reuse performance when applied to a Suzuki reaction of halogeno benzene and phenylboronic acid.

The invention provides a comprehensive treatment pneumatic caisson method for indoor environment pollution, and is used for solving the problem that concentrations of indoor formaldehyde, indoor benzene, indoor ammonia and indoor TVOC (total volatile organic compound) exceed the national standard. The comprehensive treatment pneumatic caisson method comprises the step of: applying the following six treatment solutions in an occasion that the concentrations of the indoor formaldehyde, the indoor benzene, the indoor ammonia and the indoor TVOC (total volatile organic compound) exceed the national standard: a nanocomposite catalyst solution, 1%-50% of acetum, a formaldehyde treatment solution containing active amido, a VOC (volatile organic compound) stabilizing solution, a negative oxygen ion generator and a deodorant. According to the application of the comprehensive treatment pneumatic caisson method for the indoor environment pollution, provided by the invention, the concentrations of pollutants after treatment are obviously reduced; and various effects are obtained for reducing the concentrations of the pollutants including the indoor formaldehyde, the indoor benzene, the indoor TVOC, the indoor ammonia and the like caused by furniture, floor, doors and window, carpets, wallpaper, fabrics, paint, coatings, dyes, building materials and the like.

The invention relates to a nano-composite air electrode catalyst for a zinc-air battery and a preparation method of the nano-composite catalyst, belonging to the technical field of zinc-air batteries. The nano-composite catalyst is composed of manganese dioxide, nano-silver, a carbon nano tube and a carbon material in the mass ratio of (0-0.5) to (0-0.5) to 1 to (1.75-2.75), wherein the mass of manganese dioxide and the mass of nano-silver cannot be zero at the same time. Due to the addition of nanometer materials such as nano-silver and the carbon nano tube, the wettability of the nano-composite catalyst is improved, and the reduction reaction of oxygen in a three-phase boundary formed by electrolyte, catalyst material and oxygen is facilitated; meanwhile, the composite catalyst formed by manganese dioxide and nano-silver has oxygen reduction effect higher than that of a single catalyst. The nano-composite catalyst adopts the preparation technology comprising the steps of pretreatment, granulation, ultrasonic dispersion and ball-milling treatment, the operation is simple and efficient, and the application prospect is good.

The invention belongs to the technical field of catalysts, and provides a preparation method of a cationic polymer functionalized graphene-loaded platinum nanocomposite. The preparation method comprises the following steps: preparing cationic polymer functionalized grapheme; and taking a halogen-containing acid of a precious metal as a metal source, taking a mixed solvent of polyethylene glycol and ethylene glycol as a stabilizer, a reducing agent and a solvent, adjusting the pH of a system by using sodium hydroxide, adding chloroplatinic acid and surface-functionalized graphene in a mass ratio of (1-5): 20, and reacting for 3-6min in a microwave oven at 140 DEG C to obtain a functionalized grapheme-loaded monodisperse platinum nanocomposite catalyst by one step. The functionalized grapheme-loaded monodisperse platinum nanocomposite catalyst prepared with the method has good stability, high load rate and dispersion of metal particles, and high electrocatalytic activity; and the preparation method is low in cost, nontoxic, and simple in process, and has low requirements on equipment; and with the preparation method, the large-scale production can be easily carried out.

The invention provides a core-shell structure type copper-based catalyst as well as a preparation method and application thereof. The catalyst takes Cu as a core and takes mesoporous SiO2 as a shell layer material, the weight percentage of Cu is 8-25%, and the weight percentage of SiO2 is 75-92%. The core-shell structure type nano-composite catalyst material is uniform in grain distribution, adjustable in size, good in dispersibility, small in inner core copper grain, large in specific surface area, good in stability performance, and long in service life; in CO2 hydrogenation reaction operation, the catalyst is stable in performance, and high in activity, and can be operated at a high temperature (240-300 DEG C); the high CO2 conversion per pass can be still kept after long period evaluation, and the core-shell structure type copper-based catalyst has the advantages of being low in cost, easy to operate, easy to enlarge in industry and the like.

A composition for treating dye wastewater and method of synthesizing said composition, is disclosed. The composition is a catalyst composition used for ultrasound irradiation process. The composition comprises a copper sulfide and cobalt ferrite (Cu2S / CoFe2O4) nanocomposite material, and hydrogen peroxide (H2O2). Further, the present invention also discloses a method for treating dye wastewater using said nanocomposite catalyst composition. The composition according to the present invention, provides a novel, eco-friendly and economical method for the complete degradation of the organic dye pollutants from the industrial wastewater. Further, the sonocatalyst has enough stability, as its structure and degradation ability does not change even after multiple use. Further, the sonocatalyst could be easily separated and reused from a waste water, without any need for complex separation process.

The invention discloses a supported nickel-copper alloy nano-catalyst and a preparation method thereof and application to catalytic hydrogenation. Self-assembly is carried out in a water solution through the simple coprecipitation synthetic technology, layered copper nickel hydroxide intercalated by a large amount of organic anions is obtained and serves as a precursor, and the nickel-copper alloy / carbon nano composite catalyst with high catalytic activity and stability is obtained through one-step in-situ solid-state pyrolysis in the inert atmosphere. According to the method, high-crystallinity nickel-copper alloy nano-particles can be evenly dispersed in a graphitized carbon matrix, and metal and a carrier have high interaction. No additional reducing agent or surfactant or organic solvent is used, the production cost is reduced, and the product purity is improved. In a catalytic hydrogenation reaction performance test, the prepared nickel-copper alloy / carbon nano composite catalyst shows higher catalytic activity and stability compared with a commercialized platinum / carbon catalyst, and high catalytic efficiency is still achieved after eight times of magnetic separation, recycling and cyclic utilization.

The invention discloses a nanocomposite catalyst for an ethane oxidative dehydrogenation reaction and a preparing method thereof. According to the method, firstly, an M1 purity-phase compound in a vanadium molybdenum niobium tellurium multielement metal oxide system is obtained through hydro-thermal synthesis and hydrogen peroxide purification processing; then, cerium oxide sol with the mass fraction of CeO2 being 5-30% is prepared; two methods, namely the sol-gel method and the physical mixing method are adopted, and the M1 purity-phase compound in the vanadium molybdenum niobium tellurium multielement metal oxide system and a finished product of cerium oxide nanometer complex catalyst are obtained. According to the prepared nanocomposite catalyst, the surface of rod-shaped crystal of the M1 purity-phase compound is evenly provided with a great mount of CeO2 nanometer particles, and the grain diameter of the CeO2 ranges from 2 nm to 30 nm. The nanocomposite catalyst has higher catalytic activity and selectivity in the ethane oxidative dehydrogenation reaction process, and meanwhile the synthesizing cost of the vanadium molybdenum niobium tellurium multielement metal oxide system can be lowered through the introduction of the CeO2.

The invention provides a nano-composite catalyst and a preparation method thereof, belongs to the technical field of catalyzing, and solves the problem that the conventional load nano-composite oxide catalyst is low in nano-composite degree, and poor in catalyzing performance. The nano-composite catalyst is obtained by the flowing steps based on the condition that a surface-active agent is not used: firstly, reducing composite oxide crystal lattices or first metal ions mixed in the crystal lattices so as to obtain nano-metal granules containing first metal; and then introducing second metal into the surface of the first metal by Galvanic substitution reaction so as to obtain the nano-composite catalyst. Compared with the conventional catalyst, the nano-composite catalyst has more efficient catalyzing performance when being used for catalytic reaction of VOC (volatile organic compound) removal, automobile tail gas purification, formaldehyde removal, methane combustion, hydrogenation, hydrogenolysis, ammonia synthesis, ammonia decomposition, hydrocarbon synthesis, hydroformylation and the like.

Provided are a three-dimensional carbon nanotube nano composite catalyst, and a preparation method and application thereof, which belong to the technical field of nano-material preparation. The nano composite catalyst contains carbon nanotube sponge and cadmium sulfide nano particles. The preparation method includes the step that the carbon nanotube sponge is dipped in an organic solution of the cadmium sulfide nano particles, so that the cadmium sulfide nano particles adhere on a surface and in apertures of the carbon nanotube sponge to form a three-dimensional carbon nanotube nano compositecatalyst. The invention also provides application of the catalyst to adsorption-photocatalysis degradation of dye molecules in water. On the one hand, the carbon nanotube sponge has large specific surface area, good adsorption property, and is easily operated and processed; on the other hand, the cadmium sulfide nano particles have high photocatalytic activity, and can catalyze degradation of dyemolecules in water under visible light. Therefore, the nano composite catalyst obtained in the invention has advantages of large adsorption quantity, high degradation efficiency, easy operation and processing, and capability of simultaneously degrading a plurality of pollutants in water, etc.

The invention discloses a wire mesh loaded 'metal-metal oxide' nano composite catalyst, and an application thereof in catalytic alcoholic preparation of aldehyde ketone. The catalyst is prepared by using a wire mesh subjected to surface pretreatment to load a 'metal-metal oxide' nano composite. The wire mesh loaded 'metal-metal oxide' nano composite catalyst is simple and convenient in preparation, easy to amplify, low in preparation cost, good in heat conductivity, high in low-temperature activity, high in selectivity and good in stability; and moreover, the wire mesh loaded 'metal-metal oxide' nano composite catalyst is applied to a reaction for preparing aldehyde ketone by catalyzing selective oxidation of alcohol, so that the efficiency is high, the reaction is environment-friendly, and the production cost is low.

The present invention discloses a preparation method of a charcoal-supported palladium-silver nanometer composite catalyst for direct methanol fuel cells. The method comprises: in the presence of polyvinylpyrrolidone, adding a NaOH aqueous solution to adjust the pH value of the reaction system, and using NaBH4 as a reducing agent to prepare the charcoal-supported palladium-silver nanometer composite catalyst. According to the present invention, the morphology of the palladium-silver nanoparticles in the charcoal-supported palladium-silver nanometer composite catalyst is characterized through TEM, and the methanol electrochemical oxidation activity of the charcoal-supported palladium-silver nanometer composite catalyst is evaluated by using the cyclic voltammetry method.

The invention belongs to the field of preparation of organic pollutant catalytic degradation materials, and discloses an agricultural straw charcoal loaded nano Co3O4 composite catalyst and a preparation method thereof. The method comprises the following steps: cleaning, drying, crushing and sieving agricultural straws to obtain straw powder, calcining and cooling the straw powder to obtain primary biochar powder, mixing the primary biochar powder with a KOH aqueous solution, stirring and drying the mixture to obtain a mixture of primary biochar and KOH, and calcining, cooling, washing and vacuum-drying the mixture to obtain the biomass charcoal. The preparation method comprises the following steps: preparing activated charcoal with a porous structure and a high surface area, mixing the activated charcoal with ethanol to obtain a suspension, mixing the suspension with CoCl2. 6H2O and NH4HCO3, stirring, washing and drying to obtain a charcoal composite catalyst precursor, and grinding,calcining and cooling the charcoal composite catalyst precursor to obtain the agricultural straw charcoal loaded nano Co3O4 composite catalyst. The method can solve the problem that a single metal oxide Co3O4 is low in catalytic efficiency and unstable and easily causes secondary pollution to the environment.

The invention provides a preparation method of a transition metal hexacyanoferrate / titanium dioxide nanocomposite catalyst. According to the preparation method, by taking transition metal chloride or transition metal nitrate, potassium ferrocyanide and titanium dioxide as raw materials, through an in-situ chemical solution method, in-situ growth of transition metal hexacyanoferrate (MHCF) is carried out on the surfaces of titanium dioxide nanoparticles to obtain the MHCF / TiO2 nanocomposite catalyst. The invention also provides a method for degradation of organic pollutants by light-fenton concerted reaction of the MHCF / TiO2 nanocomposite catalyst. According to the method, in dark reaction in the absence of light, the organic pollutants can be degraded by the MHCF in the form of fenton reaction, while under ultraviolet irradiation, the titanium dioxide (photocatalyst) can generate electron-hole pairs, electrons can accelerate reduction of ferric iron oxidized by H2O2 in the MHCF, meanwhile, the MHCF receiving the electrons of the titanium dioxide can also inhibit compounding of photoelectron holes, and then accelerate the generating efficiency of hydroxyl radicals during fenton reaction and a photocatalytic process, and the synergistic effect of the MHCF and the electrons has very high degradation efficiency for various different organic pollutants.

The invention discloses a nanocomposite catalyst which is characterized by comprising nano composites with the size of 5-30nm, wherein the nano composites comprise the following components in parts by weight: 1-20% of active metal oxide, 0-20% of an alkaline oxide accelerant, 0-20% of an oxidation-reduction additive and 40-99% of an aluminium oxide carrier. The invention also discloses a preparation method of the catalyst and application of the catalyst to reforming reaction of methane. By optimizing active components, improving interaction between the active components and the carrier and properly performing passivation modification on the catalyst carrier, the activity, stability and the capabilities of resisting sintering and carbon deposition of the catalyst at high temperature under high pressure are improved, the methane conversion rate of the catalyst reaches up to over 90% at the high temperature of 700-1,100 DEG C under high pressure of 1-10bar at the space velocity of 500-250,000cm<3> / (gh), and the catalyst can stably operate for more than 1,000h.

The invention discloses a preparation method of a ZrO2 nanosheet supported ruthenium catalyst. The catalyst is characterized in that metal Ru is supported on a ZrO2 nanosheet and the loading volume of Ru is 1wt%-10wt% (subjected to ZrO2). The preparation method comprises the following steps: with a hydrothermal-precipitation method, anchoring the active component Ru on the ZrO2 nanosheet (ZrO2-NS) for preparing a nanometer compound catalyst; mixing Ru and Zr soluble salt solutions and conducting hydrothermal reaction, thereby acquiring a catalyst precursor crystal nucleus; and introducing a precipitator, drying and reducing, thereby acquiring the ZrO2 nanosheet supported ruthenium catalyst (Ru / ZrO2-NS). Compared with other supported type benzene hydrogenation catalyst, the catalyst prepared according to the method provided by the invention has the advantages that Ru is uniformly distributed on the ZrO2 nanosheet, the dispersity is high and the preparation process is simple, when applied to reaction for local benzene hydrogenation for preparing cyclohexene, the catalyst has the advantages of high conversion rate, excellent selectivity and high stability.

The invention discloses an inorganic nano composite catalyst with peroxidase property. The inorganic nano composite catalyst is characterized in that oxidized graphene and Fe3O4(at)MnO2 nano particles are mixed and are ultrasonically dispersed to obtain a composite nanosheet with the size being 40-70nm, wherein the concentration of the oxidized graphene is 1-4mg.mL<-1>, the concentration of Fe3O4(at)MnO2 is 2-8mg.mL<-1>, and the ratio of the concentration of the oxidized graphene to the concentration of Fe3O4(at)MnO2 is 1:2. The capacity of performing catalytic decomposition on TMB for the obtained composite catalyst is superior to that of the oxidized graphene or the Fe3O4(at)MnO2 nano particles, and the composite catalyst is wide in application range and can be applied to sewage treatment.

The invention discloses a novel composite nanometer visible light catalyst and a preparation method thereof, belonging to the field of fine chemical industry. The main components are: 5-20wt% of nano cuprous oxide, 80-95wt% of carrier molecular sieve. The method is a mesoporous material coated with nano-cuprous oxide on the surface prepared by an in-situ reduction method, and can effectively utilize visible light to treat printing and dyeing sewage. The invention has the advantages of simple process, convenient operation, mild reaction, short reaction time and high efficiency; the particle size of the nano-cuprous oxide is small, and the particle size of the nano-composite catalyst is large, which is beneficial to the separation of the treatment agent and the treatment liquid; the preparation cost is low, and the energy Low consumption, no harmful waste, in line with the modern production requirements of "green production, environmental protection and energy saving".

A highly active supported bimetallic nanocatalyst and its preparation method is disclosed. During the preparation, using an ion exchange or absorption resin bearing basic functional groups as the support of the said catalyst, successively introducing the first metal precursor FeCl4− and the second metal precursor (PdCl42−, NiCl42− or CuCl42−) onto the resin through ion exchange process; then under the protection of nitrogen gas, simultaneously reducing the two metals with either NaBH4 or KBH4; washing the material with deoxygenated water and drying it, and the said catalyst is therefore obtained. The supported bimetallic material is characteristic of independent distribution of the two metals within the support. The independently distributed structure of the two metals enhances the catalytic efficiency of the second metal and the catalytic stability.