The invention relates to a preparation method for a front
electrode of an organic
thin film solar cell. The preparation method comprises the following steps of (a) taking a
glass slide as the substrate, and
sputtering an AZO thin film on the substrate; (b) adding
polyvinyl pyrrolidone, 1-methyl-3 ethyl imidazolium
bromide and
ethylene glycol into a reaction kettle to form a
mixed solution; next, adding an
ethylene glycol solution of
silver nitrate to the
mixed solution, sealing and placing the
mixed solution at a temperature of 100-120 DEG C to react for 1-5h, then carrying out centrifuging, cleaning and carrying out
ultrasonic dispersion on the mixed solution to obtain a silver
nanowire water solution; (c) adding a
chloroauric acid solution and an
oxidizing agent to the silver
nanowire water solution to react at a temperature of 5-30 DEG C for 5-10min, next, adding a
reducing agent to the mixture to continue to react for 5-10min; then centrifuging, washing and evaporating the mixture to remove water, and
drying the mixture to obtain a gold-coated silver
nanowire; (d) dispersing the gold-coated silver nanowire into an isopropanol solution, and then
coating the surface of the AZO thin film with the processed isopropanol solution in a spin-
coating manner to a obtain a composite layer sample; and (e)
sputtering the AZO thin film on the surface of the composite layer sample. By adoption of the preparation method, the efficiency of the organic
thin film solar cell is improved.