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Antistatic polyethylene glycol terephthalate composite material

A technology of ethylene phthalate and composite materials, which is applied in the field of antistatic polyethylene terephthalate composite materials, can solve the problems of entering water and reducing the antistatic properties of polyester fibers, and achieves lasting effects Effect

Active Publication Date: 2012-12-12
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method will cause the antistatic agent to enter the water during cleaning, thereby reducing the antistatic performance of the polyester fiber.

Method used

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  • Antistatic polyethylene glycol terephthalate composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Add 1000 grams of purified terephthalic acid (PTA), 250 grams of ethylene glycol (EG), 280 grams of nanometer copper-ethylene glycol sol ( Wherein copper 20 grams, ethylene glycol is 260 grams), esterification reaction temperature is 250 ℃, reaction pressure is 0.26MPa, and reaction time is 110 minutes. The product of the above-mentioned esterification process is then subjected to a polycondensation process to form an antistatic PET composite material. Among them, the polycondensation reaction temperature in the low vacuum stage is 260°C, the pressure is gradually reduced from normal pressure to 1000Pa, the reaction time is 30 minutes, the polycondensation reaction temperature in the high vacuum stage is 275°C, the vacuum degree of the reaction system is 55Pa, and the reaction time is 82 minutes.

[0020] The melting point of the obtained polymer chips is 245° C., the intrinsic viscosity is 0.65 dL / g, and the volume specific resistance of the obtained fibers is 3.26×10 ...

Embodiment 2

[0025] Add 1000 g of purified terephthalic acid (PTA), 300 g of ethylene glycol (EG), and 230 g of nano-carbon black-ethylene glycol sol into a 5L stainless steel reaction kettle equipped with nitrogen inlet, condensate outlet and stirrer (Wherein carbon black 20 grams, ethylene glycol is 210 grams), esterification reaction temperature is 245 ℃, reaction pressure is 0.25MPa, and reaction time is 120 minutes. The product of the above-mentioned esterification process is then subjected to a polycondensation process to form an antistatic PET composite material. Among them, the polycondensation reaction temperature in the low vacuum stage is 255°C, the pressure is gradually reduced from normal pressure to 1000Pa, the reaction time is 25 minutes, the polycondensation reaction temperature in the high vacuum stage is 280°C, the vacuum degree of the reaction system is 50Pa, and the reaction time is 90 minutes.

[0026] The melting point of the obtained polymer chips is 246°C, the intri...

Embodiment 3

[0028] Add 1000 grams of purified terephthalic acid (PTA), 250 grams of ethylene glycol (EG), and 280 grams of nano-cuprous iodide-ethylenedioxide into a 5L stainless steel reaction kettle equipped with nitrogen inlet, condensate outlet and stirrer Alcohol sol (including 20 grams of cuprous iodide and 260 grams of ethylene glycol), the esterification reaction temperature is 250° C., the reaction pressure is 0.25 MPa, and the reaction time is 90 minutes. The product of the above-mentioned esterification process is then subjected to a polycondensation process to form an antistatic PET composite material. Among them, the polycondensation reaction temperature in the low vacuum stage is 200-240°C, the pressure is gradually reduced from normal pressure to 1000Pa, the reaction time is 30 minutes, the polycondensation reaction temperature in the high vacuum stage is 285°C, the vacuum degree of the reaction system is 50Pa, and the reaction time is 78 minute.

[0029] The melting point...

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Abstract

The invention relates to an antistatic polyethylene glycol terephthalate composite material. Glycol, terephthalic acid and nano antistatic agent-glycol sol are polymerized, the esterification reaction temperature is 200-290 DEG C, and the pressure is 0.1-0.5MPa; the low-vacuum polycondensation reaction temperature is 200-290 DEG C, the pressure is reduced from normal pressure to 1,000Pa; and the high-vacuum polycondensation reaction temperature is 250-300 DEG C, and the reaction vacuum degree is 100-50Pa. The nano antistatic agent-glycol sol is formed by nano carbon black, nano metal, nano metal compounds and glycol. A nano antistatic agent accounts for 0.1-10% of the weight of the polyethylene glycol terephthalate and accounts for 1-10% of the weight of the nano antistatic agent-glycol sol. The intrinsic viscosity of the material is 0.55-0.75dL / g, and the volume resistivity of a fiber is 108 ohms / cm-109 ohms / cm.

Description

Technical field: [0001] The invention relates to an antistatic polyethylene terephthalate composite material. Background technique: [0002] Polyester fiber is a hydrophobic high polymer with a regular structure, neither ionization nor free electrons; polyester fiber itself is an insulator with poor hygroscopicity, and it is difficult to dissipate the static electricity generated after contacting or rubbing with other objects. Then the polyester fiber is charged with static electricity. [0003] At present, there are two main ways to eliminate static electricity of polyester fiber. One is post-treatment technology, that is, electroplating on the surface of the fiber with metals such as copper and silver, or coating the surface of the fiber with a hygroscopic agent, and treating it with polyaniline or pyrrole solution. Polyester fabric. However, the antistatic effect is not long-lasting, it is not washable and wear-resistant, and it affects the hand feel. [0004] The othe...

Claims

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Application Information

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IPC IPC(8): C08G63/183C08K3/04C08K3/08C08K3/22C08K3/24C08L67/02
Inventor 史君张野张培华陈颖夏秀丽马城华吴传祥王洪星秦中秋陈君孙一峰
Owner PETROCHINA CO LTD
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