The invention discloses a method for recycling
chromium from
chromium passivation wastewater of an electrolytic
manganese factory. The method is characterized by comprising the following steps of: adding
hydrogen peroxide into the
chromium passivation wastewater, oxidizing Cr(III) into Cr(VI), adding
sodium hydroxide into liquid to remove impurities, such as Mn and other
metal ions, adjusting pH and adding Pb<2+>, washing the obtained precipitate part by using water,
drying and preparing
powder to obtain
chrome yellow, adjusting pH of supernate, adding aluminum
sulfate, stirring, reacting andperforming
solid-liquid separation, wherein the obtained supernate is used for washing the negative plate of the discharged
manganese of the electrolytic
manganese factory. By the method, the chromium recycling rate is over 99 percent, the impurities, such as manganese and other
metal ions are removed, purity of
chrome yellow in the product and the product quality are improved, the chromium content in
sludge is reduced through recycling and recovering of chromium in
wastewater, the
sludge does not belong to risky
solid wastes, the wastewater can be used for washing the negative plate of the discharged manganese of the electrolytic manganese factory, the policy of
energy conservation and emission reduction, recycling of resource, and cyclic utilization is met, and economic benefit is brought to relative industry.