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547results about How to "Strong UV Absorbing Properties" patented technology

Metal oxide particle and its uses

An object of the present invention is to provide a metal oxide particle which exercises more excellent ultraviolet absorbency as a matter of course and combines therewith merits of, for example, either being shifted in ultraviolet absorption edge toward the longer wavelength side and being excellent also in the absorption efficiency of a long-wavelength range of ultraviolet rays, or having good transparency and, for example, even in cases where added into or coated onto substrates, not damaging the transparency or hue of the substrates. As a means of achieving this object, a metal oxide particle according to the present invention is a metal oxide particle such that a hetero-element is contained in a particle comprising an oxide of a specific metal element (M), wherein the metal oxide particle is: 1) a metal oxide particle in the form of a fine particle wherein the hetero-element is at least one specific metal element (M′); 2) a metal oxide particle wherein the hetero-element includes at least two specific metal elements (M′); 3) a metal oxide particle wherein: the hetero-element is a more specified metal element (M′) and at least a part thereof is 2 in valence; or the metal element (M) is a more specified metal element and the metal oxide particle is in a specific range in crystal grain diameter in the vertical direction to each of the (002) plane and the (100) plane; or 4) a metal oxide particle wherein: the hetero-element is at least one specific nonmetal element and an acyl group is contained in the particle; or the hetero-element includes at least two specific nonmetal elements; or the hetero-element is at least one specific nonmetal element and a component derived from a metal element (M′) other than the metal element (M) is contained in the particle.
Owner:NIPPON SHOKUBAI CO LTD

Functionalized nanometer silica with ultraviolet ray absorption function group grafted on surface, and preparation method thereof

The invention belongs to the field of functionalized nanometer silica, and particularly relates to functionalized nanometer silica with an ultraviolet ray absorption function group grafted on the surface, and a preparation method thereof. According to the present invention, and an amino silane coupling agent is adopted as bridging, and a o-hydroxybenzoyl group adopted as an ultraviolet ray absorption agent group is chemically grafted on nanometer silica particles, wherein the amino silane coupling agent about accounts for 3-12% of the total weight of the functionalized nanometer silica with the ultraviolet ray absorption function group grafted on the surface, and the o-hydroxybenzoyl about accounts for 2-20% of the total weight. The functionalized nanometer silica with the ultraviolet ray absorption function group grafted on the surface has characteristics of excellent ultraviolet ray absorption capacity and good dispersibility, and can be provided for improving the light oxidation aging resistance of the polymer during the use process and increasing the comprehensive mechanical property of the polymer material when the functionalized nanometer silica is adopted as the polymer auxiliary agent.
Owner:INST OF CHEM CHINESE ACAD OF SCI

Nano SiO2 hybridized acrylic acid ester soap-free emulsion and manufacturing method

ActiveCN103554343AImprove water resistanceEffect of water resistanceAnti-corrosive paintsEmulsionNano sio2
The invention relates to a nano SiO2 hybridized acrylic acid ester soap-free emulsion and a manufacturing method, wherein the nano SiO2 hybridized acrylic acid ester soap-free emulsion is prepared by the following components by weight: 5-20 parts of modified silica sol, 40-70 parts of deionized water, 20-50 parts of double bond containing polymerisable monomer, and 0.1-0.3 parts of initiator. An aqueous resin prepared by the invention has good water proofness, mechanical property and weatherability, can be used for preparing an aqueous woodenware paint, a construction anticorrosion paint and an anticorrosive paint with high ornamental feature.
Owner:JIANGSU RONGCHANG NEW MATERIAL TECH

UV-absorbing borosilicate glass for a gas discharge lamp, process for manufacturing same and gas discharge lamp made with same

Glass for gas discharge tubes, which are used in fluorescent lamps, EEFL lamps, LCD displays, computer monitors, telephone displays and TFT displays, and a process for making it are described. The glass contains, in % by weight based on oxide content: SiO2, 60-75; B2O3, >25-35; Al2O3, 0-10; Li2O, 0-10; Na2O, 0-20; K2O, 0-20; MgO, 0-8; CaO, 0-20; SrO, 0-5; BaO, 0-5; ZnO, 0-3; ZrO2, 0-5; TiO2, 0-10; Fe2O3, 0-0.5; CeO2 0-0.5; MnO2, 0-1.0; Nd2O3, 0-1; WO3, 0-2; Bi2O3, 0-5; MoO3, 0-5; As2O3, 0-1; Sb2O3, 0-1; SO42−, 0-2 C−, 0-2 and F−, 0-2, wherein ΣLi2O+Na2O+K2O=0-25% by weight; ΣMgO+CaO+SrO+BaO=0-20; ΣFe2O3+CeO2+TiO2+PbO+As2O3+Sb2O3 is at least 0-10; and ΣPdO+PtO3+PtO2+PtO+RhO2+Rh2O3+IrO2+Ir2O3 is from 0.00001-0.1.
Owner:SCHOTT AG

Method for synthesizing novel reactive ultraviolet absorbent and application thereof

The invention relates to a method for synthesizing 4-(4,6-dichloro-1,3,5-triazine-2-oxo)-2-hydroxyl phenyl benzophenone serving as a novel reactive ultraviolet absorbent (UV-DTHM) and application of the UV-DTHM to the uvioresistant arrangement of cotton fabrics, and belongs to the technical field of functional aids. The method comprises the following steps of: performing etherification reaction of diphenyl ketone (UV-O) and trichloro-s-triazine (CYC) which serve as raw materials under the catalysis of sodium hydroxide, wherein a ratio of UV-O to CYC to NaOH is 1:2.0:1.5; reacting in a mixed solvent of acetone and water at the temperature of 0 DEG C for 5 hours to obtain the UV-DTHM, and the yield of the UV-DTHM is 82.5 percent. The UV-DTHM has the excellent ultraviolet absorption performance, and is high in heat stability; and active groups are contained in a molecular structure and can be reacted with substances containing groups such as animo, hydroxyl and the like. The UV-DTHM is applied to the uvioresistant arrangement of white cotton fabrics to achieve an excellent uvioresistant effect (the value of an ultraviolet protective factor (UPF) reaches 67), and the UPF value is kept at 43+ / -3 basically after the cotton fabrics are soaped for 30 times, so the UV-DTHM has an excellent soaping-resistant effect.
Owner:JIANGNAN UNIV

Preparation method of kaolin/1-butyl-3-methyl bromide imidazole intercalated nanocomposite

The invention discloses a preparation method of a kaolin/1-butyl-3-methyl bromide imidazole intercalated nanocomposite. The method comprises the following steps: firstly, directly intercalating the kaolin by using dimethyl sulfoxide to obtain a kaolin/dimethyl sulfoxide intercalated composite; then intercalating the kaolin intercalated composite by using methyl alcohol to obtain a kaolin/methyl alcohol intercalated composite; and finally, enabling synthesized 1-butyl-3-methyl bromide imidazole and the kaolin/methyl alcohol intercalated composite to carry out intercalating reaction in room-temperature and atmospheric environment so as to obtain a kaolin/1-butyl-3-methyl bromide imidazole intercalated nanocomposite. Through the preparation method of the kaolin/1-butyl-3-methyl bromide imidazole intercalated nanocomposite, imidazole ionic liquid carries out intercalating reaction with the kaolin/methyl alcohol intercalated composite under the room-temperature and atmospheric environment for the first time so as to obtain the kaolin/1-butyl-3-methyl bromide imidazole intercalated nanocomposite; and the kaolin/1-butyl-3-methyl bromide imidazole intercalated nanocomposite is integral in structure, stable in property, good in heat resistance, fluorescence property and ultraviolet absorbency.
Owner:CHINA UNIV OF GEOSCIENCES (WUHAN)

Method for preparing a waterborne poly(urethane acrylate)/nano-titanium dioxide hybrid material

The invention provides a method for preparing a waterborne poly(urethane acrylate) / nano-titanium dioxide hybrid material. The method comprises the following steps: (1) firstly, preparing TBT (tetrabutyl titanate) sol; (2) adding mono-polyol and isocyanate as raw materials to a container, adding a hydrophilic chain extender, increasing the temperature of the reaction system to 30 to 80 DEG C and further adding catalysts in the presence of NMP (N-methyl pyrrolidone) as a solvent; and (3) adding triethylamine as a salt-forming agent, reacting for 10min to 60min, and dispersing with water in the presence of ethylenediamine as a chain extender to obtain the waterborne polyurethane emulsion; adding a small amount of gamma-glycidoxy-propyl-tri-methoxy-silane, stirring for 10min to 90min, adding the TBT sol to the reaction system, further dropwise adding a small amount of hydrochloric acid, and keeping stirring for 12h to 48h to obtain the waterborne poly(urethane acrylate) / nano-titanium dioxide hybrid material. The hybrid material of the invention has the advantage that the weather resistance, mechanical properties, coating transparency and other properties of the hybrid material are greatly increased.
Owner:JIANGSU UNIV

Surface modified aramid fiber and preparation method thereof

ActiveCN108642862AEnsure service reliabilityHigh UV absorptionFibre typesNanotechnologyFiber structureChemistry
The invention relates to surface modified aramid fiber and a preparation method thereof. The method comprises the following steps: aramid fiber with an amino group and a carboxyl group on the surfaceis modified with a siloxane gamma-glycidyloxypropyltrimethoxysilane in order to obtain silicon methoxylated aramid fiber; and the silicon methoxylated aramid fiber and polydopamine modified turbostratic boron nitride coated cerium oxide are reacted in order to obtain surface modified aramid fiber. Polydopamine modified turbostratic boron nitride coated cerium oxide has high ultraviolet absorption,at the same time has extremely low catalytic activity, in order to avoid destroy of photocatalysis on the fiber structure in a radiation process, and is an effective and safe high efficient ultraviolet absorbent. The surface modified aramid fiber has anti-UV function, high surface activity, high thermal performance and higher mechanical properties, and excellent comprehensive performance and higher utilization value. The preparation method is simple and controllable, and is suitable for large-scale production.
Owner:SUZHOU UNIV

Eu-(TTA)3-1,10-phen/SiO2 core/shell type nano composite fluorescent material

The invention relates to an Eu-(TTA)3-1,10-phen / SiO2 core / shell type nano composite fluorescent material belonging to the preparation field of composite fluorescent materials. TTA is used as a first ligand and phen is used as a second ligand to prepare Eu-(TTA)3phen ligand which is the novel photoluminescence material and is hydrolyzed under the function of base catalyst by TEOS, and a layer of SiO2 shell is formed on the surface of a rare-earth composition so as to obtain rare-earth ligand nano particles with stable fluorescence intensity. The invention has the advantages of simple preparation process, low cost of raw materials, reaction at normal temperature and low energy consumption. Because the SiO2 shell is separated from oxygen and water in the air, compared with the Eu-(TTA)3phen fluorescent material, the Eu-(TTA)3phen / SiO2 core / shell type nano composite fluorescent material has greatly improved stability under the ultraviolet irradiation, strengthened fluorescent emission intensity and better UV absorptivity.
Owner:BEIJING UNIV OF CHEM TECH

Waterborne glass nano-paint containing composite metal nanometer nuclear particles and preparation

The invention relates to waterborne glass nano-paint containing composite nanometer nuclear particles and preparation. The paint is prepared from composite metal nanometer nuclear particles, nano-silicon dioxide modified by fluorinated alkyl silane, nano-silicon dioxide coated by nano-titania, organic silicon molecules modified by acrylic ester, modified nano-titania, waterborne polyurethane resin / polysiloxane resin composite resin, an additionally adsorbed adjuvant and other auxiliary ingredients. By certain modification and combination of composite nanometer nuclear particle ingredients andother ingredients, the performance of the paint is expanded, by mutual synergy between the ingredients, the coating material shows excellent properties, has excellent effects of high light transmitting performance, heat insulation performance, ultraviolet isolation / absorption performance, high adhesiveness, anti-aging stability, water dredging, dust prevention and self cleaning, and further has anintelligent energy-saving effect specific to environmental temperature.
Owner:深圳威耐纳米新材料科技有限公司

Preparation methods of distearoyl phosphatidyl ethanolamine and amino polyethylene glycol derivatives thereof

The invention discloses preparation methods of distearoyl-phosphoethanolamine and amino polyethylene glycol derivatives thereof and relates to effective preparation methods of a medicinal carrier material phospholipids-distearoyl-phosphoethanolamine (DSPE for short) and amino polyethylene glycol derivatives of the distearoyl-phosphoethanolamine (NH2-PEG-DSPE for short). The preparation method of the distearoyl-phosphoethanolamine comprises the following steps of: firstly reacting phosphorus oxychloride with 1,2-distearoyl-glyceride to obtain phosphorylcholine monoester which is I for short; reacting the phosphorylcholine monoester with 2-hydroxyethyl-benzyqcarbamate to obtain DSPE containing amino-protecting group which is II for short; and carrying out catalytic hydrogenation on the II to remove the protecting group to obtain DSPE. The preparation method of the amino polyethylene glycol derivatives of the distearoyl-phosphoethanolamine comprises the following steps of: reacting DSPE with nitrine substituted PEG chloro-carbonic ester which is VI for short to obtain nitrine-polyethylene glycol DSPE derivatives which is III for short; and reducing the nitrine into amino by catalytic hydrogenation to obtain the amino polyethylene glycol derivatives of the distearoyl-phosphoethanolamine.
Owner:SOUTHEAST UNIV +1

Eu3+/Eu2 doped aluminate multicolor fluorescent material and preparing method thereof

The invention discloses an Eu3+ / Eu2 doped aluminate multicolor fluorescent material and a preparing method thereof. A material matrix is composed of CaCO3 and Al2O3 with a molar ratio of 1:1. The molar fraction of the filler Eu2O3 accounts for 2% of the matrix. The molar fraction of the filler SiO2 accounts for x% of the matrix, wherein x=25, 50 or 200. The preparing method comprises the steps of weighing raw materials precisely according to the ratio, mixing the raw materials evenly, and then conducting grinding continuously till mixing is even; placing powder obtained from grinding in a corundum crucible, placing the corundum crucible in a muffle furnace for high-temperature solid-phase reaction for 8-20 h in the air atmosphere at the temperature of 1000-1300 DEG C, taking the corundum crucible out and cooling the corundum crucible to room temperature after the furnace is cooled to 900 DEG C, and obtaining a sample after even grinding. The preparing technology is simple, cost is low, toxicity and pollution are avoided, and the physical and chemical properties of the product are stable. The requirement for experiment equipment, especially the sealing performance of the experiment equipment is quite low, safety performance is high, and mass production can be achieved easily. Eu2+ emission is broadband emission, the intensity and position of an emission peak are adjustable, and ultraviolet absorption can be well achieved.
Owner:NANCHANG UNIV
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