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340 results about "Diphenyl ketone" patented technology

Dibenzyl ketone, or 1,3-diphenylacetone, is an organic compound composed of two benzyl groups attached to a central carbonyl group.

Aanalysis method of residual quantities of eighteen photoinitiators in ultra violet (UV) printing ink

An analysis method of residual quantities of eighteen photoinitiators in ultra violet (UV) printing ink aims to determine the residual quantities of the eighteen photoinitiators including 2-hydroxy-2-methyl-1-phenylpropanone, methyl benzoylformate, diphenyl ketone and the like. The analysis method is characterized by mainly comprising the following steps: 1) preparation of a test sample, 2) extraction of a sample, 3) dispersive solid phase extraction purification, 4) preparation of standard working solutions, 5) instrument analysis and 6) result calculating. According to the analysis method, through sample pretreatment and optimization and validation by instrument analysis, a sample pretreatment technology of dispersive solid phase extraction purification is applied to the determination of the residual quantities of the photoinitiators in the UV printing ink sample, and compared with a liquid-liquid extraction (LLE) technology and a solid phase extraction (SPE) technology adopted by related methods in the prior art, the analysis method has the characteristics of being rapid, simple, cheap, effective, reliable and safe. So far, the analysis method covers most kinds of residual photoinitiators than analysis methods at home and abroad.
Owner:CHINA NAT TOBACCO QUALITY SUPERVISION & TEST CENT

Method for synthesizing novel reactive ultraviolet absorbent and application thereof

The invention relates to a method for synthesizing 4-(4,6-dichloro-1,3,5-triazine-2-oxo)-2-hydroxyl phenyl benzophenone serving as a novel reactive ultraviolet absorbent (UV-DTHM) and application of the UV-DTHM to the uvioresistant arrangement of cotton fabrics, and belongs to the technical field of functional aids. The method comprises the following steps of: performing etherification reaction of diphenyl ketone (UV-O) and trichloro-s-triazine (CYC) which serve as raw materials under the catalysis of sodium hydroxide, wherein a ratio of UV-O to CYC to NaOH is 1:2.0:1.5; reacting in a mixed solvent of acetone and water at the temperature of 0 DEG C for 5 hours to obtain the UV-DTHM, and the yield of the UV-DTHM is 82.5 percent. The UV-DTHM has the excellent ultraviolet absorption performance, and is high in heat stability; and active groups are contained in a molecular structure and can be reacted with substances containing groups such as animo, hydroxyl and the like. The UV-DTHM is applied to the uvioresistant arrangement of white cotton fabrics to achieve an excellent uvioresistant effect (the value of an ultraviolet protective factor (UPF) reaches 67), and the UPF value is kept at 43+ / -3 basically after the cotton fabrics are soaped for 30 times, so the UV-DTHM has an excellent soaping-resistant effect.
Owner:JIANGNAN UNIV

Synthesis of novel organic luminescent material containing carbazolyl toluylene derivant structure and application thereof

The invention relates to novel luminous material containing a carbazyl stilbene derivative structure, which belongs to the technical field of the organic luminous materials. When the synthesis is performed, two carbazyl diphenyl ketones (2) are connected by an aromatic compound containing two ylide groups; or the carbazyl diphenyl ketones are changed into an intermediate body (3) or an intermediate body (4) firstly, and then the carbazyl stilbene is coupled by a crossed coupling method. The art of the synthetic method provided by the invention is simple, the purification is easy, the synthesized organic luminous material containing the carbazyl stilbene derivative structure has a high thermal stability, a high glass-transition temperature and a strong illumination intensity, the material is suitable for preparing the material of photogenic layers in organic electroluminescent material devices, the luminous material with aggregation-induced emission effect can be serviced as stimuli-response functional material to be applied to chemical / biochemical sensors.
Owner:SUN YAT SEN UNIV

Macromolecular photoinitiator containing diphenyl ketone groups and preparation method of macromolecular photoinitiator

The invention discloses a macromolecular photoinitiator containing diphenyl ketone groups and a preparation method of the macromolecular photoinitiator. The general structural formula of the macromolecular photoinitiator containing the diphenyl ketone groups is shown in the formula (I), wherein R1 refers to a methyl group or hydrogen; R2 refers to an alkyl group, hydrogen, an ethoxyl group or a hydroxypropyl group; R3 refers to an alkyl group, hydrogen or an ethoxyl group; R4-8 and R'4-7are separately selected from hydrogen or an alkyl group; R9 refers to a methyl group or hydrogen. The designed and synthesized macromolecular photoinitiator is obtained through copolymerization of a synthesized special polymerizable photoinitiator. According to the adopted polymerizable photoinitiator, two diphenyl ketone units contained in each molecule are fixed on two sides of a rigid triazine ring and are not contacted with each other, so that the probability of combination of adjacent free radicals is greatly decreased, and the photoinitiation efficiency is improved; meanwhile, the polymerizable photoinitiator contains amido hydrogen supply units, and accordingly, comonomers containing hydrogen supply components such as tertiary amine and the like are not required to be added additionally during preparation of the macromolecular photoinitiator.
Owner:SUN YAT SEN UNIV

Nitrogen heterocycle ligand transition metal complex, and preparation and catalytic application thereof

The invention relates to a novel nitrogen heterocycle ligand / phosphine ligand transition metal complex, and preparation and application thereof in asymmetric catalytic hydrogenation and hydrogen transfer. The complex has the following structural formula: [MLnL' XY], wherein the transition metal M is Ru, Rh, Ir, Pd, Pt, Co, Ni or Os. The complex also contains a nitrogen heterocycle ligand, two monophosphine ligands or one diphosphine ligand, and the like. The transition metal compound, dinitrogen or mononitrogen ligand and diphosphine or monophosphine ligand react at 0-120 DEG C in an organic solvent for 0.5-20 hours to obtain the complex. The complex is used for asymmetric catalytic transfer hydrogenation or asymmetric hydrogenation reaction, and especially for asymmetric catalytic hydrogenation reaction of ketones, esters, hypnones and derivatives thereof, diphenyl ketones and derivatives thereof, beta-N,N-dimethylamino-alpha hypnones and derivatives thereof and other ketone compounds of which the alpha site is a large steric hindrance alkyl group.
Owner:ENANTIOTECH CORP

Liquid chromatography-mass spectrometry (LC-MS) detection method for diphenyl ketone ultraviolet-proof finishing agents in textiles

The invention discloses a liquid chromatography-mass spectrometry (LC-MS) detection method for diphenyl ketone ultraviolet-proof finishing agents in textiles. The LC-MS detection method comprises the following steps: (1) preparing a to-be-detected sample solution; (2) preparing standard solutions: preparing eight mixed standard working solutions in which the concentrations of the diphenyl ketone ultraviolet-proof finishing agents are 0.01-10mu g / mL to be serve as gradient standard solutions; (3) injecting the gradient standard solutions into a liquid chromatography-tandem mass spectrometer, and determining in a positive-negative-ion multi-reaction monitoring mode, and thus a standard curve equation is generated; and (4) taking the supernatant obtained in the step (1) and determining the diphenyl ketone ultraviolet-proof finishing agents in the supernatant and peak areas of the diphenyl ketone ultraviolet-proof finishing agents according to the method in the step (3) and calculating according to the standard curve equation in the step (3) to obtain the contents of the diphenyl ketone ultraviolet-proof finishing agents in the to-be-detected sample.
Owner:THE INSPECTION & QUARANTINE TECH CENT ZHEJIANG ENTRY EXIT INSPECTION & QUARANTINE BUREAU

Water-based ultraviolet-curing printing ink and preparation method thereof

The invention discloses a water-based ultraviolet-curing printing ink and a preparation method thereof. The printing ink comprises the following raw materials by weight: 20-30 parts of epoxy acrylic resin, 10-15 parts of polyurethane acrylic resin, 5-10 parts of polyester acrylic resin, 4-6 parts of diphenyl ketone, 2-4 parts of 2,2-diethoxyacetophenone, 10-15 parts of pigments, 2-3 parts of isopropanolamine, 8-12 parts of pentaerythritol triacrylate, 15-20 parts of diacrylic acid-1,6-hexylene glycol ester, 3-5 parts of propylene glycol ethyl ether, 1-2 parts of a fluorocarbon surfactant FC-4430, 0.5-1 part of a defoamer BYK-019, 3-5 parts of a compound filler and 20-25 parts of de-ionized water. The water-based printing ink is excellent in performance, can be instantly cured after being irradiated by ultraviolet rays, is free from evaporation of a petroleum solvent, cannot pollute the environmental and is safe to use; the printing ink can be still kept stable in performance and cannot be mildewed after being stored in the printing process and even an ink fountain for a long term; a printed product is good in color stability and high in brightness, and an ink layer is higher in friction resistance, chemical resistance and adhesiveness; the printing ink has a wide application prospect.
Owner:青岛米品品服装有限公司

Industrial synthesis method of high-thermal-stability blocked binphenyl-structure-containing polyaryletherketone resin

ActiveCN104479089ANo depolymerizationAvoid rejoiningSynthesis methodsSolvent
The invention discloses an industrial synthesis method of high-thermal-stability blocked binphenyl-structure-containing polyaryletherketone resin. The industrial synthesis method of the high-thermal-stability blocked binphenyl-structure-containing polyaryletherketone resin comprises the following steps: carrying out polymerization reaction based on paradioxybenzene, biphenol and 4,4'-difluoro diphenyl ketone or 4,4'-difluoro triphenyl diketone as reaction monomers, a high boiling point organic solvent as a solvent, alkali carbonate as a salt-forming agent and asymmetric aromatic ketone-based derivative as a blocking agent, so as to obtain polymerization mucosal fluid; cooling the polymerization mucosal fluid and smashing the cooled polymerization mucosal fluid into powder, filtering and boiling and washing with an organic solvent and deionized water for removing the solvent and byproduct salt, and drying, thus obtaining the binphenyl-structure-containing polyaryletherketone resin. The industrial synthesis method of the high-thermal-stability blocked binphenyl-structure-containing polyaryletherketone resin has the advantages that sodium carbonate alkali metal is individually adopted as a catalyst, and a good blocking effect is realized after the blocking agent is added; besides, no polymerization phenomenon is caused in a system, and the obtained blocked binphenyl-structure-containing polyaryletherketone resin has high temperature thermal stability.
Owner:JIANGMEN YOUJU NEW MATERIALS

Synthesis method of ternary copolymer containing PEEK and poly(ether ether ketone ketone)s using sulfolane as solvent

ActiveCN1884331AAchieve refined effectSulfolaneSynthesis methods
The invention relates to a method for preparing polyetheretherketone and polyetheretherketone terpolymer by using sulfolane. It comprises following steps: the mole number of 4, 4'- difluoro diphenyl ketone and 4, 4'- difluoro triphen dione is more than that of eldopaque by 0.1-1%, the mle number of 4, 4'- difluoro triphen dione is 1-4% of that of total fluorin and acetone, the solid content in reaction system is 15-30%; filling dimethylbenzene with its mass being 10-20% of that of organic solvent, stirring, heating, adding mixed salt of alkali metal carbonate when monomer is totally dissolved and the temperature is between 75 to 85 Deg. C, reacting at constant temperature 230-260 Deg. C for 1-3 hours, stopping reaction, pouring product into cold water, cooling and disintegrating and filtering, boiling solid product with deionized water for several times, drying refined powder material in baking box, and getting said final product.
Owner:长春吉大特塑工程研究有限公司

N doped activated carbon-supported Pd-Fe catalyst for synthesizing diphenylcarbinol through catalytic hydrogenation of diphenyl ketone and application thereof

The invention discloses an N doped activated carbon-supported Pd-Fe catalyst for synthesizing diphenylcarbinol through catalytic hydrogenation of diphenyl ketone and application thereof. The N doped activated carbon-supported Pd-Fe catalyst is prepared from an N doped activated carbon carrier and active components Pd and Fe supported on the surface of the carrier, wherein the support capacity of Pd is 1 to 5 weight percent, and the support capacity of Fe is 1 to 5 weight percent; the granularity of N doped activated carbon is 100 to 1000 meshes, the specific surface area is 600 to 2000 m<2> / g,and the pore volume is 0.3 to 0.8 ml / g; an N element in the N doped activated carbon is directly doped in an activated carbon skeleton or between activated carbon and is connected by N-C bonds, wherein the N content is 0.5 to 10 weight percent. The invention provides the application of the N doped activated carbon-supported Pd-Fe catalyst in synthesizing the diphenylcarbinol through the catalytichydrogenation of the diphenyl ketone. High catalytic activity, high product selectivity, high catalytic hydrogenation reaction speed and high stability are expressed.
Owner:ZHEJIANG UNIV OF TECH

Organic phase electrolyte and application thereof in negative electrode of redox flow battery

The invention discloses an organic phase electrolyte and an application thereof in a negative electrode of a redox flow battery. The organic phase electrolyte consists of active materials, a supporting electrolyte and an organic solvent, wherein the active materials are diphenyl ketone and a derivative thereof, anthrone and a derivative thereof, or dibenzoyl methane and a derivative thereof; the supporting electrolyte is selected from tetraethylammonium hexafluorophosphate, tetraethylammonium tetrafluoroborate, tetrabutylammonium hexafluorophosphate or tetrabutylammonium tetrafluoroborate; and the organic solvent is selected from acetonitrile, tetrahydrofuran, propylene carbonate, ethylene carbonate, dimethyl sulfoxide, dimethylformamide, glycol dimethyl ether or ethylene glycol diethyl ether. The organic phase electrolyte disclosed by the invention has relatively low electrochemical potential and high electrochemical property; when the organic phase electrolyte is used as the negative electrode electrolyte of the redox flow battery for assembling an organic phase redox flow battery, relatively high open-circuit voltage can be realized, so that the energy density of the battery can be improved; and meanwhile, the capacity fading of the battery can be lowered, so that the cycle life of the battery can be prolonged.
Owner:TIANJIN UNIV

Optical polyester film

The invention discloses an optical polyester film. The optical polyester film adopts a single-layer A, double-layer A / B and three-layer A / B / A or A / B / C coextruded biaxially oriented polyester film, wherein the layer A or the layer A and the layer C contain polyester modified by 4.4'-dihydroxy diphenyl sulfone or 4.4'-dihydroxy diphenyl ketone; the thickenss of the optical polyester film is 12 to 350 microns. The surface performance of the polyester film is modified, so the adhesion fastness and the adhesive force with a functional layer are improved, and the hardness and the scratching resistance of the surface of the polyester film are improved. The optical polyester film can be widely applied to deep processing of a diffusion sheet, a prismatic lens, a protective film, in-film decoration, a window film and a photovoltaic material in a backlight module.
Owner:HEFEI LUCKY SCI & TECH IND

Novel self-hydrogen-supplying diphenyl ketone macromolecular photoinitiator and preparation method thereof

The invention discloses a novel self-hydrogen-supplying diphenyl ketone macromolecular photoinitiator shown in the specification and a preparation method thereof. Diphenyl ketone containing an epoxy group is used as a raw material and is subjected to ring-opening reaction under the action of a specific initiator, thus generating the novel self-hydrogen-supplying diphenyl ketone macromolecular photoinitiator. The macromolecular photoinitiator does not migrate after curing, is less prone to volatilize, reduces the odor, reduces the environmental pollution and has the characteristics of favorable resin compatibility and the like; and meanwhile, the macromolecular photoinitiator has the maximum advantage that the macromolecular photoinitiator is a self-hydrogen-supplying one, so that micromolecular auxiliary initiators do not need to be added, thereby avoiding the problems of migration, precipitation and the like during curing of the micromolecular auxiliary initiators in the photocuring process. Thus, the invention has wide application prospects in the field of photocuring. R is tert-butyl ethyl butyl.
Owner:HANGZHOU INST OF ADVANCED MATERIAL BEIJING UNIV OF CHEM TECH

Preparation method for polyimide film

The invention relates to a preparation method for a polyimide film. The preparation method comprises the following steps that step 1, pyromellitic dianhydride and 4, 4'-diaminodiphenyl ether are placed in dimethylacetamide solvent for polymerization reaction, so that polyamide acid gel A is obtained; step 2, 3,3',4,4'-diphenyl ketone tetracarboxylic acid dianhydride and ursol are placed in dimethylacetamide solvent for polymerization reaction, so that polyamide acid gel B is obtained; step 3, the polyamide acid gel A and the polyamide acid gel B are mixed; step 4, ultrafine nano-montmorillonite powder dispersion liquid is prepared; step 5, the ultrafine nano-montmorillonite powder dispersion liquid is fully dispersed in polybasic polyamide acid gel, so that composite polyamide acid gel is obtained; step 6, the composite polyamide acid gel is made into a film through the tape casting technology, and finally the film is fed into an imidization furnace to be treated, so that the polyimide film is obtained. The polyimide film prepared through the preparation method has the performance advantages of low thermal expansivity, high strength, high stability, high electric strength and the like.
Owner:安徽统唯新材料科技股份有限公司

Ultraviolet light curing glass paint and preparation method thereof

The invention relates to an ultraviolet light curing glass paint and a preparation method thereof. The paint comprises organic silicon resin, modified epoxide resin, diluent and 1-hydroxide radical-cyclohexyl diphenyl ketone and is prepared by evenly mixing the materials. The paint is free from organic solvent and toxicity, and being combined, the materials have very good property of visible light penetration, prevent ultraviolet and infrared radiation and have very good heat-insulating property.
Owner:LIAONING 113 GRP CHEM
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