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1046 results about "Phase reaction" patented technology

Phase I Reactions: Phase I Reactions Phase I reactions (also termed nonsynthetic reactions) may occur by oxidation, reduction, hydrolysis, cyclization, and decyclization addition of oxygen or removal of hydrogen, carried out by mixed function oxidases, often in the liver.

Anode active material, manufacturing method thereof, and non-aqueous electrolyte secondary battery

In order to provide a 3V level non-aqueous electrolyte secondary battery with a flat voltage and excellent cycle life at a high rate with low cost, the present invention provides a positive electrode represented by the formula: Li2±α[Me]4O8−x, wherein 0≦α<0.4, 0≦x<2, and Me is a transition metal containing Mn and at least one selected from the group consisting of Ni, Cr, Fe, Co and Cu, said active material exhibiting topotactic two-phase reactions during charge and discharge.
Owner:OSAKA CITY UNIVERSITY +1

Power storage device and charging method thereof

An object is to inhibit a decrease in the capacity of a power storage device or to compensate the capacity, by adjusting or rectifying an imbalance between a positive electrode and a negative electrode, which is caused by decomposition of an electrolyte solution at the negative electrode. Provided is a charging method of a power storage device including a positive electrode using an active material that exhibits two-phase reaction, a negative electrode, and an electrolyte solution. The method includes the steps of, after constant current charging, performing constant voltage charging with a voltage that does not cause decomposition of the electrolyte solution until a charging current becomes lower than or equal to a lower current value limit; and after the constant voltage charging, performing additional charging with a voltage that causes decomposition of the electrolyte solution until a resistance of the power storage device reaches a predetermined resistance.
Owner:SEMICON ENERGY LAB CO LTD

Method for preparing furfural compounds from biomass

The invention relates to a method for preparing furfural compounds from biomass. The method specifically comprises the preparation of a solid acid catalyst and a reaction process of the solid acid catalyst. The method disclosed by the invention can also be applied to biomass derivatives. The method comprises the steps of adding biomass or biomass derivatives and the solid acid catalyst to a reactor, filling with protective gas, and adopting an organic solvent / saturated inorganic salt aqueous-solution two-phase reaction system, thereby obtaining furfural and 5-hydroxymethylfurfural in a high yield manner under mild conditions. The method has the advantages that after the reaction is completed, the produced furfural and 5-hydroxymethylfurfural are efficiently extracted into an upper-layer organic phase, the solid acid catalyst and an unreacted substrate are retained in a bottom-layer water phase, the furfural, the 5-hydroxymethylfurfural or a mixture of the furfural and the 5-hydroxymethylfurfural can be obtained through simple separation, and fine chemicals and liquid fuels can be prepared in a manner that the furfural, the 5-hydroxymethylfurfural or the mixture of the furfural and the 5-hydroxymethylfurfural serves as a reaction intermediate; and the used catalyst is pollution-free and can be recovered and reused, so that the method has good industrial application prospects.
Owner:EAST CHINA UNIV OF SCI & TECH

Multi-layer graphene/lithium iron phosphate intercalated composite material, preparation method thereof, and lithium ion battery adopting multi-layer grapheme/lithium iron phosphate intercalated composite material as anode material

The invention relates to a lithium iron phosphate intercalated composite material, a preparation method thereof and a lithium ion battery adopting the multi-layer graphene / lithium iron phosphate intercalated composite material as an anode material. In the prior art, the electronic conductivity of the lithium iron phosphate material is poor, high-rate charging / discharging capacity of the lithium ion battery adopting the lithium iron phosphate material as the anode material is poor. The purpose of the present invention is to solve the problems in the prior art, and improve the rapid charging capacity of the power lithium ion battery so as to meet the requirements of the pure electrocar. The composite material is prepared through the following steps that: a rheological phase reaction method is adopted for multi-layer graphene, a trivalent iron salt, a phosphorus compound, a lithium compound and carbon source of small organic molecule to obtain a composite precursor, then the precursor is sintered to obtain the multi-layer graphene / lithium iron phosphate intercalated composite material. The anode slurry of the lithium ion battery anode plate comprises the composite material, a conductive agent and polyvinylidene difluoride. The composite material is an intercalated structure, wherein the lithium iron phosphate particles are intercalated between the multi-layer graphene to form the intercalated structure. The trivalent iron salt is adopted as the raw material, such that the cost is reduced. The lithium ion battery has good charging / discharging cycle performance, wherein the specific capacity is more than 60 mA.h.g<-1> at the rate of 20C.
Owner:HARBIN INST OF TECH

Process of making polymer blends

InactiveUS20070129497A1Cross-linkPolymer science
In a process for producing a polymer blend, at least one first monomer is polymerized in a first slurry phase reaction zone in the presence of a supported first catalyst comprising a Ziegler-Natta component to produce a thermoplastic first polymer having a crystallinity of at least 30%. At least part of said first polymer is then contacted with at least one second monomer different from said first monomer and at least one polyene in a second solution phase reaction zone in the presence of a second catalyst under conditions to produce and at least partially cross-link said second polymer such that said second polymer comprises at least a fraction which is insoluble in xylene and has a crystallinity of less than 20%.
Owner:EXXONMOBIL CHEM PAT INC

Method for preparing porzite porous honeycomb ceramic with needle-shaped crystal structure

The invention relates to a method for preparing a porzite porous honeycomb ceramic with a needle-shaped crystal structure. The method comprises the following steps: mixing various raw materials containing Al and Si, such as industrially pure kaoline, alumina, silicon oxide and the like according to the mol ratio of Al2O3/SiO2 within the range of 3:2 to 2:1, and then adding a proper amount of nano-scale mineralizing agent which is formed by mixing one or more in an oxide MxOy containing a first transition element, alkali metal and alkaline-earth metal compounds or a raw mineral material containing the compounds; adding a proper amount of fluoride MFx or a catalyst containing an F raw mineral material, screening and mixing the raw materials, adding a proper amount of forming agent, forming a blank body, then drying and finally roasting by adopting a two-stage roasting synthesis technology. In the method of the invention, the raw materials with low price can be adopted, and a particular nano-scale catalyst and mineralizing agent composite can be self-manufactured and synthesized; the porzite porous honeycomb ceramic with the whole needle-shaped crystal structure can be continuously prepared through once roasting by utilizing the principle of a gas-solid phase reaction and adopting the two-stage roasting synthesis technology at lower temperature, and the porzite porous honeycomb ceramic has the characteristics of low cost and high efficiency.
Owner:JINGDEZHEN CERAMIC INSTITUTE

Method for preparing hydrocarbon fuel and methanol

The invention discloses a preparation method for hydrocarbon fuel and methanol, which is characterized in that a wood powder, a lignin, a lignin monomer and (or) a lignin monomer and/or dimer is used as a raw material, the raw material and a hydrogenation catalyst are filled into a high-pressure autoclave, the pH value of an aqueous phase reaction system is adjusted to 2 to 7, hydrogen is charged into the reaction system under the normal temperature, and the temperature is increased to 40 to 350 degree centigrade, the reaction is executed for 0.2 to 5 hours under 40 to 350 degree centigrade, and the product is divided into two phases after the reaction is completed and the temperature is decreased, the upper layer phase is the hydrocarbon fuel, the lower layer aqueous phase is a methanol solution; the molar ratio of the hydrogenation catalyst and the raw material is 1:10-10000. Compared to the traditional prepared hydrocarbon fuel and methanol, the preparation method for hydrocarbon fuel and methanol has the advantages of economy with wide resources of the raw material and low cost, environment protection, simplicity with simple process, high efficiency with high utilization ratio of the raw material and high productivity, which takes an important role in the utilization of the lignin, hydrocarbon fuel and methanol preparation field with a wide application prospect.
Owner:PEKING UNIV

Tubular reactor for catalytic gas phase reactions

A tubular reactor (2) for catalytic reactions with a heat carrier that inside a reactor jacket (10) circulates around a contact tube bundle (8), which extends between a tube plate (4; 6; 80; 82) at the reaction gas inlet side and one at the reaction gas outlet side with gas inlet and gas outlet hoods (12, 14) spanning the face sides of the two tube plates and containing reaction-inhibiting media in the zone of the tube plate on the gas inlet side, characterize themselves in that the reaction-inhibiting media consist entirely or in part of a heat insulation layer (46; 50; 64; 80) with openings for the tube cross-sections on at least one of the two sides of the respective tube plate (4; 60; 82). In this manner, either the respective tube plate (4; 60; 82) is insulated against the hot heat carrier or the reaction gas entering into the reactor is prevented from having contact with the comparatively hot tube plate in order to prevent harmful secondary reactions at the reactor inlet.
Owner:MAN ENERGY SOLUTIONS SE

Solid oxide fuel cell composite cathode and preparation method thereof

The invention belongs to the field of solid oxide fuel cells and particularly relates to a solid oxide fuel cell composite cathode and a preparation method thereof, wherein the solid oxide fuel cell composite cathode has a high electrochemistry performance and is stable in long-time operation. The preparation method includes the following steps of step one, preparing a three-dimensional porous skeleton made of electrolytic materials at a high temperature; step two, preparing a powder suspension or a nitrate solution of a cathode material; step three, impregnating the powder suspension or the nitrate solution into the porous skeleton and then calcinating the porous skeleton; step four, repeating the operation of the step 3 for a plurality of times until the impregnating quantity reaches the requirement; step five, performing high temperature sintering under an air atmosphere to obtain the three-dimensional composite cathode with a core-shell structure. According to the solid oxide fuel cell composite cathode and the preparation method thereof, the process is simple, expensive experiment apparatuses are not required, the obtained composite cathode is of the core-shell structure, a core is the electrolytic skeleton, a shell is a phase reaction layer with a stable nano thin film structure, and the problem that the performance is attenuated due to the fact that nano particles of the solid oxide fuel cell composite cathode prepared by an impregnating method are low in stability and easy to sinter is solved.
Owner:NANJING UNIV OF TECH
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