The invention discloses a modified high-
nickel positive
electrode material coated with a
fast ion conductor and a preparation method of the modified high-
nickel positive
electrode material. The high-
nickel positive
electrode material comprises a substrate, wherein the substrate is a compound LiNi<1-x-y>Co<x>Mn<y>M<z>O<2> shown in a formula I, in the formula I, x is more than 0 but less than or equal to 0.20, y is more than 0 but less than or equal to 0.20, z is more than 0 but less than or equal to 0.1, and M is arbitrary one or more of elements of Al, Mg, Ti, Zr, Mn, Ni, Sn, Co, Zn, W, Mo, Ru, Ca, Sr, Ba, B, Y, V and Nb. The preparation method comprises the following steps of washing and
drying the high-nickel positive
electrode material, uniformly mixing the high-nickel positive
electrode material and an appropriate amount of
coating agent, and performing
sintering and sieving to obtain the modified high-nickel positive
electrode material coated with the
fast ion conductor. The fastion conductor is coated by washing and surface
drying methods, the alkali amount of a surface of the positive electrode material is reduced,
side reaction of the material and an
electrolyte is reduced, and the high-temperature stability and the safety of the material are improved; and by
doping and
coating the surface with the
fast ion conductor, the
energy density, the rate performance and the cycle property of the material are improved, and the long cycle lifetime of a battery is finally prolonged.