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37 results about "2-propenoic acid" patented technology

Sunscreen compounds and compositions containing same and methods for use thereof

There is provided a photostable and synergistically enhanced topical sunscreen composition that provides increased substantivity, waterproofness, sweat resistance and rub off resistance. There is further provided methods of enhancing the photostability of a sunscreen active in a topical sunscreen composition, synergistically enhancing the UV absorbance of a topical sunscreen composition having a sunscreen active, and enhancing the substantivity, waterproofness, sweat resistance and rub off resistance in a topical sunscreen composition. The preferred compositions and methods have a sunscreen active, a cosmetically acceptable vehicle, and novel 2-substituted-3,3-diaryl-2-propenoic acid derivatives with [A] a C16 to C50 straight or branched chain, substituted or un-substituted, conjugated or non-conjugated hydrocarbon, or [B] a siloxane, polysiloxane, organo-modified polysiloxane residue, a group represented by the formula R10[Si(R10)2]n— and R11 which is a silicone residue derived from a silicone represented by the formula R11OH having a molecular weight up to about 30,000, wherein each R10 is independently selected from the group consisting of alkyl, alkoxy, aryl and aryloxy and n is from 1 to about 500.
Owner:NEW AVON LLC

Super hydrophobic silicon-fluorine polymer/nanometer silica hybridization nanometer material and preparation method thereof

The invention relates to a super hydrophobic silicon-fluorine polymer / nanometer silica hybridization nanometer material and a preparation method thereof, relating to a super hydrophobic nanometer material and a preparation method thereof. The invention provides the super hydrophobic silicon-fluorine polymer / nanometer silica hybridization nanometer material with mild reaction condition, definite reaction product structure as well as simple and convenient operation and the preparation method thereof. The preparation method comprises the following steps of: firstly, preparing nanometer silica modified by a silane coupling agent; secondly, preparing a nanometer silica atom transfer radical surface initiator; thirdly, preparing a SiO2-poly-Methacryloxypropyltrimethoxysilane macromolecule initiator; and finally preparing the silicon-fluorine polymer / nanometer silica hybridization nanometer material. The silicon-fluorine polymer / nanometer silica hybridization nanometer material has excellent high temperature resistance, ultraviolet resistance, infrared radiation resistance, oxidative degradation resistance, chemicals resistance and contamination resistance. Polymethyl 2-propenoic acid, 2,2,3,3,4,4,4-heptafluorobutyl ester has very low surface energy and very good hydrophobicity, wherein the surface energy can be as low as 0.5-1.5mN / m, and the hydrophobic angle can be over 150 degrees.
Owner:XIAMEN UNIV

Radiation-proof light-filtering contact lens and production method thereof

A radiation-proof light-filtering contact lens is characterized in that the weight ratio of each component of liquid material is as follows: 90 to 100 parts of hydroxyethyl methacrylate; 10 to 12 parts of ethenyl pyrrolidinone; 0.3 to 0.5 part of 2-propenoic acid, oxybis(2,1-ethanediyloxy-2,1-ethanediyl)ester; acrylic acid, diester with tetraethylene glycol; 0.15 to 0.2 part of 2,2'-dicyano-2,2'-azopropane azobisisbutyronitrile; 0.7 to 1 part of 4-[(E)-phenyldiazenyl]phenyl-2-methacrylate; and 3 parts of yellow pigment and dye for contact lenses. The contact lens has a good oxygen permeation coefficient, high moisture content, moderate hardness and fewer residues, and also has a good ultraviolet radiation protection effect and a good filtering effect on purple light and blue light.
Owner:北京自然美光学有限公司

Dye sensitized photoelectric conversion device and manufacturing method thereof, electronic equipment, and semiconductor electrode and manufacturing method thereof

InactiveUS20100116340A1Degrade detection efficiency or photoelectric conversion efficiencyReduce quantum yieldElectrolytic capacitorsSemiconductor/solid-state device manufacturingSemiconductor electrodeTricarboxylic acid
In a dye sensitized photoelectric conversion device having an electrolyte layer (6) between a semiconductor electrode (3) including, for example, fine semiconductor particles to which a sensitizing dye is adsorbed and a counter electrode (5), two kinds of dyes are used as the dye, and the two kinds of dyes are adsorbed onto the surface of the semiconductor electrode (3) at the sites different from each other. The fine semiconductor particles include, for example, TiO2. Tris(isothiocyanate)-ruthenium(II)-2,2′:6′,2″-terpyridine-4,4′,4″-tricarboxylic acid and 2-cyano-3-[4-[4-(2,2-diphenylethenyl)phenyl]-1,2,3,3a,4,8b-hexahydrocyclopent[b]indol-7-yl]-2-propenoic acid are used, for example, as the two kinds of dyes. Thereby, a dye sensitized photoelectric conversion device such as a dye sensitized solar cell capable of obtaining higher light absorption rate and photoelectric conversion efficiency than in a case of using one kind of dye at high purity, as well as a manufacturing method thereof are provided.
Owner:SONY CORP

Preparation and use of EXO-2-fluoroalkyl(bicyclo[2.2.1] hept-5-enes)

There is disclosed a composition comprising a mixture of endo- and exo-2-(bicyclo[2.2.1]hept-5-en-2-yl)-2,2-fluoroalkyl-ethan-2-ol which is rich in the exo isomer, preferably the endo / exo concentration ratio is no greater than 5 / 95. The composition is useful for forming a repeat unit of a polymer which polymer may further comprise additional repeat units derived-from tert-butyl acrylate, hydroxyadamantyl acrylate, protected or unprotected fluorinated-olefins, 2-methyl-2-adamantyl acrylate, 2-propenoic acid, 2-hydroxy-1,1,2-trimethylpropyl ester. Polymers of this invention are useful as the binder component of a photoresist composition for microlithography.
Owner:EI DU PONT DE NEMOURS & CO

Stable oil-in-water and water/oil/water multiple emulsions and hair treating compositions comprising them

The present invention provides an oil-in-water or water / oil / water multiple emulsion, or a mixture thereof, comprising (A) a organopolysiloxane elastomer crosslinked with polyether chains and (B) at least one thickener selected from the group of a polyacrylamide homo- or copolymer, a cellulose ether, a non-silicone cationic polymer or a thickening system comprising a mixture of from about 60% to about 67% of the thickening system of a copolymer of 2-propenoic acid with 2-propenamide, from about 27% to about 32% of the thickening system of the homopolymer of 2-methyl-1-propene and from about 5 to about 7% of the thickening system of poly(oxy-1,2-ethanediyl)-sorbitan-monododecanoate.
Owner:THE PROCTER & GAMBLE COMPANY

High-strength impact resistance oil paint

InactiveCN105255353AOvercoming impact resistanceOvercome the problem of large shrinkage during curingFireproof paintsPolyurea/polyurethane coatingsAcrylic resinPolyethylene glycol
The invention discloses high-strength impact resistance oil paint. The high-strength impact resistance oil paint is prepared from polyurethane acrylic resin, epoxy-acrylic resin, bisphenol A epoxy resin, ethylene diglycidyl ether, polyethylene glycol, 2-propenoic acid,1,1'-[(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)]]ester, pentaerythritol triacrylate, azodiisobutyronitrile, 1-hydroxycyclohexylphenylketone, triarylsulfonium hexafluoroantimonate salt, carbon black, graphene oxide, carbon nanotubes, cresyl diphenyl phosphate, a flatting agent, an antifoaming agent, a thickening agent, a silane coupling agent, phenolic epoxy acrylate, solvent and corrosion inhibitor. The high-strength impact resistance oil paint is good in impact resistance, excellent in anti-static property, high in strength, high in adhesive force with a base material and not prone to be disengaged in the using process.
Owner:安徽嘉年华漆业有限公司

Method for preparing 2-methyl-2-propenoic acid 2-ethyl-2-[[(2-methyl-1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester

The invention discloses a method for preparing 2-methyl-2-propenoic acid 2-ethyl-2-[[(2-methyl-1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester, which comprises the following steps of: (1) putting main materials of trimethylolpropane and methacrylic acid into an esterification reaction container, adding a solvent, adding a catalyst and a polymerization inhibitor A, and performing mixing reaction to obtain a reaction material; (2) controlling the pressure in the esterification reaction container to be -0.04 to -0.08MPa, raising the temperature in the esterification reaction container until reflux flows out, keeping the temperature, and beginning cooling to normal temperature until no reflux flows out or an acid value in reaction solution is detected to be 30-50mgKOH / g; (3) transferring the reaction material to a washing container, adding alkali liquor, controlling the pH value of the reaction material to be 7-8, standing until the reaction material is layered, and discharging wastewater on the lower layer; and (4) transferring the reaction material of which the wastewater is removed to a distillation container, adding a polymerization inhibitor B, vacuumizing the distillation container, and distilling to remove methylbenzene to obtain the product. The product is high in purity, good in color, and high in yield.
Owner:天津市天骄化工有限公司

Method for providing anti-felting function for wool fabric

The invention relates to a method for providing an anti-felting function for a wool fabric. The method utilizes tris(2-carboxyethyl)phosphine (TCEP) to pre-treat a wool fabric so that disulfide bonds in wool fiber keratin are broken to form mercapto groups with high activity. 2-propenoic acid-(2-hydroxy-1,3-propanediyl)bis[oxy(2-hydroxy-3,1-propanediyl)]ester (GDA) and the wool fabric pre-treated by TCEP undergo a click chemical reaction, in other word, C-C double bonds and the mercapto groups undergo a reaction so that a molecular chain rich in hydroxyl is introduced into wool protein molecules by a medical bonding method. The treated product has an anti-felting function, realizes a certain degree of machine washing, has good size stability and has a certain durability by chemical treatment. The method has substantial effects, belongs to a chlorine-free treatment method and is safe and environmentally friendly.
Owner:DONGHUA UNIV

Environment-friendly light-curing electrostatic spraying primer

The invention provides an environment-friendly light-curing electrostatic spraying primer, comprising the following components in percentage by weight: 10-20% of 2-Propenoic acid,1,1'-[(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)]] ester, 1-5% of trimethylolpropane triacrylate, 5-8% of a photo-initiator, 15-20% of epoxy acrylate, 20-25% of polyester acrylic resin, 5-8% of polyurethane acrylic resin, 0.2-0.5% of a flatting agent, 0.2-0.5% of an anti-settling agent, 5-12% of flour, 5-10% of 1,6-hexanediol diacrylate, 5-8% of 2-ethylhexyl acrylate and 0-0.2% of a defoaming agent. The light-curing electrostatic spraying primer adopts a UV monomer with low viscosity and strong dilution capacity to replace an original solvent, contains no VOC (Volatile Organic Compounds), can be recycled and belongs to green and environment-friendly paints; UV resin with low viscosity and good wettability is used as main resin so that the content of solid paint is high; and the light-curing electrostatic spraying primer can be directly applied to electrostatic spraying without being diluted by the organic solvent and has the advantages of good atomization effect, good package to devices, excellent adherence and good rubbing property.
Owner:东莞大宝化工制品有限公司 +1

Antimicrobial polymeric compositions

A method for the preparation of polymers derived from acrolein and including poly(2-propenal, 2-propenoic acid), characterised in that the polymers are exposed to the presence of water, whereby such polymers exhibit increased antimicrobial activity. The polymers may be heated in the range of 40 to 150 deg.C. Further, the polymers may be prepared in the presence of polyethylene glycols, polyols and / or alkanols.
Owner:CHEMEQ

Process for disposing of solvent-containing liquids

A process for disposing of solvent-containing liquids so that they do not contaminate ground water. An absorbent blend is mixed into a water-containing solvent mixture at the rate of about 1 lb. of blend per gallon of liquid. The blend is made up of a swellable polymer, consisting of polyacrylamide / polyacrylate co-polymer salt or poly 2-propenamide-co-2-propenoic acid homopolymer salt which swells and absorbs liquid. The blend also contains a mixture of solid absorbents. The resulting mixture is stirred in the container until it becomes thick and then it is allowed to set to provide a disposable modeling clay-like solid. The resulting solid material, after curing, may be then simply added to solid trash, and thus, be freed from contaminating ground water.
Owner:ATKINS DON C +1

Hydroxyl polyester resin for high-gloss powder coating, and preparation method and application thereof

The invention specifically relates to hydroxy polyester resin for a high-gloss powder coating, a preparation method thereof and application of the hydroxy polyester resin to powder coatings, belongingto the technical field of powder coatings. The hydroxy polyester resin for the high-gloss powder coating is prepared through polymerization of the following raw materials: terephthalic acid, 6-aminocaproic acid, domoic acid, 3,6-dithia-1,8-octanediol, 2-propenoic acid-2,18-dihydroxy-4,7,10,13,16-pentaoxanonadecane-1,19-diyl ester, neopentyl glycol, 3-(2,3-epoxypropoxy)propyl trimethoxy silane and3,5-di-tert-butyl-4-hydroxybenzyl alcohol. It has been determined that the obtained hydroxy polyester resin has good melt fluidity at 200 DEG C, low melt viscosity and long leveling time, and allowsa film to have high gloss. The hydroxy polyester resin is eventually applied to the powder coating cured by polyurethane B1530, can improve the surface gloss of the coating, and allows a coated boardsurface with high gloss to be obtained.
Owner:安徽恒隆新材料有限公司

Nanocellulose compound temperature-sensitive type hydrogel and preparation method thereof

The invention discloses nanocellulose compound temperature-sensitive type hydrogel and a preparation method thereof. The preparation method comprises the following steps: uniformly mixing cellulose nano-fibril gel, 2-methyl-2-propenoic acid-2-(2-methoxyethoxy)ethyl ester and methoxy polyethylene glycol methacrylate to obtained mixed liquid A; carrying out degassing treatment and ultrasonic dispersion treatment on the mixed liquid A to obtain mixed liquid B; after introducing nitrogen gas into the mixed liquid B, adding an initiator; uniformly stirring in a water bath to obtain the nanocellulose compound temperature-sensitive type hydrogel. The nanocellulose compound temperature-sensitive type hydrogel prepared by the preparation method has relatively great rigidity, good elasticity and good biocompatibility and has relatively high gel strength and rupture strength; the temperature-sensitive performance of the nanocellulose compound temperature-sensitive type hydrogel is not influenced by the adding amount of cellulose nano-fibrils; the nanocellulose compound temperature-sensitive type hydrogel has a good application prospect in the fields including intelligent temperature sensing, medicine controlled release, artificial muscle and the like.
Owner:CENTRAL SOUTH UNIVERSITY OF FORESTRY AND TECHNOLOGY

Quick-drying latex paint

The invention relates to the field of latex paint, in particular to quick-drying latex paint, being prepared from the following raw materials in parts by weight: 8-15 parts of sodium propionate, 17-35 parts of manganese naphthenate, 20-40 parts of silicon dioxide ultrafine powder, 20-35 parts of polyvinyl alcohol, 3-5 parts of 2-propenoic acid octyl ester, 1-4 parts of lignin, 4-5 parts of calcium fluoride, 5-9 parts of potassium citrate, 30-40 parts of linseed oil, 20-25 parts of tung oil and 80-150 parts of deionized water. The quick-drying latex paint is non-toxic, harmless and free of peculiar smell, and the construction is convenient.
Owner:吕林霖

Coloring matter-sensitized photoelectric conversion element, process for producing the coloring matter-sensitized photoelectric conversion element, electronic equipment, semiconductor electrode, and p

This invention provides a coloring matter-sensitized photoelectric conversion element comprising an electrolyte layer (6) provided between a semiconductor electrode (3) formed of, for example, semiconductor fine particles, onto which a coloring matter for sensitizing has been adsorbed, and a counter electrode (5), wherein two types of coloring matters are used as the coloring matter and are adsorbed on respective different sites on the surface of the semiconductor electrode (3). The semiconductor particles are formed of, for example, TiO2. The two types of coloring matters are, for example, tris(isothiocyanato)-ruthenium(II)-2,2':6',2''-terpyridine-4,4',4''-tricarboxylic acid and 2-cyano-3-[4-[4-(2,2-diphenylethenyl)phenyl]-1,2,3,3a,4,8b-hexahydrocyclopent[b]indol-7-yl]-2-propenoic acid. The above constitution can realize the provision of a coloring matter-sensitized photoelectric conversion element, such as coloring matter-sensitized solar cells which can realize higher level of light absorbance and photoelectric conversion efficiency than the case where a single type of high-purity coloring matter is used, and a process for producing the coloring matter-sensitized photoelectric conversion element.
Owner:SONY CORP

Outer-wall antifouling latex paint

The invention relates to the field of latex paint, in particular to outer-wall antifouling latex paint, being prepared from the following raw materials in parts by weight: 8-15 parts of sodium propionate, 17-35 parts of manganese naphthenate, 20-40 parts of silicon dioxide ultrafine powder, 20-35 parts of polyvinyl alcohol, 3-5 parts of 2-propenoic acid octyl ester, 10-17 parts of barium sulfate, 3-5 parts of sericite powder, 1-4 parts of titanium dioxide, 0.2-0.4 part of sodium hexametaphosphate and 80-150 parts of deionized water. The outer-wall antifouling latex paint has excellent weather fastness, alkali resistance and scrub resistance, and solves the problems of poor water resistance, great cracking possibility, peeling, powder removal, discoloration, cleaning difficulty and the like.
Owner:吕林霖

Coagulation-accelerating early strength agent for 3D printing house slurry

The invention discloses a coagulation-accelerating early strength agent for 3D printing house slurry. The coagulation-accelerating early strength agent is prepared from raw materials in parts by weight as follows: 50-100 parts of anhydrous sodium sulfate, 1-7 parts of calcium nitrite, 5-7 parts of aluminum sulfate, 5-10 parts of humic acid, 0.1-0.3 parts of guar gum, 5-7 parts of 3-[(2,4-dichloro)phenyl]-2-propenoic acid, 10-20 parts of a filling agent and 1-3 parts of additives. The coagulation-accelerating early strength agent is exclusively used for a 3D printing house and can promote coagulation and hardening of the 3D printing house slurry, and the strength of the slurry after coagulation develops more rapidly than that of a conventional early strength agent; furthermore, the cost of the raw materials of coagulation-accelerating early strength agent is low, and the applicability is wider.
Owner:ZHUODA NEW MATERIALS TECH GRP WEIHAI CO LTD

Inner-wall silky latex paint

The invention relates to the field of latex paint, in particular to inner-wall silky latex paint, being prepared from the following raw materials in parts by weight: 8-15 parts of sodium propionate, 17-35 parts of manganese naphthenate, 20-40 parts of silicon dioxide ultrafine powder, 20-35 parts of polyvinyl alcohol, 3-5 parts of 2-propenoic acid octyl ester, 1-4 parts of lignin, 4-5 parts of calcium fluoride, 5-9 parts of potassium citrate, 30-40 parts of titanium dioxide, 20-30 parts of benzene acrylic and 80-150 parts of deionized water. The weather fastness is stronger, and a protection layer formed by spraying can be exposed outdoors for a long term.
Owner:吕林霖

Polycarboxylate superplasticizer and preparation method thereof

The invention discloses polycarboxylate superplasticizer and a peparation method thereoof. The polycarboxylate superplasticizer comprises following raw materials, by weight, 40 to 60 parts of alkylphenol ethoxylates, 25 to 35 parts of TPEG, 10 to 15 parts of cinnamic acid, 10 to 15 parts of Octenyl succinic anhydride, 5 to 10 parts of 2-Propenoic acid, 3-phenyl-, ethyl ester, 5 to 10 parts of methacrylic acid, 3 to 8 parts of isopropanol, 3 to 8 parts of sodium persulfate and 0.5 to 2 parts of ascorbic acid. The polycarboxylate superplasticizer has lower amount of mixture than other common polycarboxylate superplasticizer and has a high water-reducing rate under the circumstance of water-binder ratio. The polycarboxylate superplasticizer has the advantages of wider range of application, good anti-collapse of concrete, environmental protection. The polycarboxylate superplasticizer, prepared by this method, is capable of having wider adaption to concrete, making the system more stable, reducing usage of air entraining agent and making shrinkage ratio of concrete lower than common water reducer.
Owner:GUANGXI JINHONG CONCRETE CO LTD

Multi-action mode hydrophilic organic polymer monolithic column

The invention discloses a multi-action mode hydrophilic organic polymer monolithic column, which consists of a benzene-ring group-containing organic ionic monomer, an acrylate crosslinking agent, an initiator, and a pore-forming agent. The benzene-ring group-containing organic ionic monomer is N, N, N-trimethyl(vinylbenzyl)ammonium chloride, the crosslinking agent is 2-propenoic acid, (2,4,6-trioxo-1,3,5-triazine-1,3,5(2H,4H,6H)-triyl)tri-2,1-ethanediyl ester, the pore-forming agent is a mixture of methanol and dodecanol, and the initiator is azodiisobutyronitrile. The inventive capillary chromatographic column can provide hydrogen bonds and ion exchange interaction, but also can provide rich pi-pi interaction, and can meet the rapid separation requirements of neutral, acidic and alkaline polar substances.
Owner:FUZHOU UNIV

Efficient compatilizer for polyolefin-based wood-plastic composite

The invention discloses an efficient compatilizer for a polyolefin-based wood-plastic composite, and belongs to the field of efficient compatilizers. According to the efficient compatilizer for the polyolefin-based wood-plastic composite, in the EAA extruding process, a hydroxyl functional monomer, namely 2-propenoic acid-2-hydroxyl-3-phenoxypropyl ester, and another hydrophobic monomer, namely hexadecyl methacrylate, with the synergistic effect are added and subjected to a grafting reaction on EAA molecular chains under the effect of DCP, and thus an EAA graft polymer is formed. The preparedEAA graft polymer serves as the compatilizer for the polyolefin-based wood-plastic composite, thus compatibility and hydrophobic performance of waste plant fibers such as wood flour in polyolefin canbe greatly improved, an outer sheath with a display layer is arranged at the outer end of a screw rod, thus abrasion information is given to workers in time, thus workers replace the outer sheath conveniently, and the screw rod is protected against being prone to breaking.
Owner:JIANGSU HENGFENG CABLE

Process for preparation of dicyanocarboxylate derivatives

The present disclosure provides a process for preparing 2,3-dicyanopropionic acid ester of formula (I); said process comprising the following steps: i) treating an alkali metal cyanide dissolved in a solvent with a solution of 2-cyano-2-propenoic acid ester of formula (II) at a temperature ranging between 0° C. and 50° C. for a time period ranging between 2 hours and 15 hours followed by cooling below 20° C. to obtain a sodium salt of 2,3-dicyanopropionic acid ester of formula (I); andii) neutralizing the sodium salt of 2,3-dicyanopropionic acid ester using a neutralizing agent to obtain a 2,3-dicyanopropionic acid ester of formula (I).
Owner:GHARDA KEKI HORMUSJI

Fire retardant panel for decoration

The invention discloses a fire retardant panel for decoration. The fire retardant panel comprises a core material and fabric surfaces arranged on the two surfaces of the core material, the outer surface of each fabric surface is provided with a fire retardant layer, and each fire retardant layer is prepared from, by weight, 1-2 parts of sodium pyrophosphate, 3-4 parts of organic silicone oil, 2-3 parts of zinc sulfide, 1-2 parts of citric acid, 3-4 parts of 2-methyl-2-propenoic acid cyclohexyl ester, 2-3 parts of tellurium dioxide, 1-2 parts of barium sulfate, 3-4 parts of ammonium sulfate, 2-3 parts of pentachlorodiphenyl, 2-3 parts of magnesium hydrate and 3-4 parts of kieselguhr. The fire retardant panel for decoration has the advantages that the fire retardant panel has both good heat insulation performance and good fireproof performance, which effectively solves the problem that the heat insulation performance and the fireproof performance of the existing thermal materials cannot coexist; the fabric surfaces supply shock resistance, waterproof and anti-leakage performance and anti-cracking ability needed by the core material to the core material; the overall fireproof performance of a wall body thermal system is improved.
Owner:重庆市巴南区添福装饰工程有限公司

A process for preparation of dicyanocarboxylate derivatives

The present disclosure provides a process for preparing 2, 3-dicyanopropionic acid ester of formula (I); said process comprising the following steps: i) treating an alkali metal cyanide dissolved in a solvent with a solution of 2-cyano-2-propenoic acid ester of formula (II) at a temperature ranging between 0 °C and 50 °C for a time period ranging between 2 hours and 15 hours followed by cooling below 20 °C to obtain a sodium salt of 2, 3-dicyanopropionic acid ester of formula (I); and (II) ii) neutralizing the sodium salt of 2, 3-dicyanopropionic acid ester using a neutralizing agent to obtain a 2, 3-dicyanopropionic acid ester of formula (I), (I)
Owner:凯基·霍尔穆斯吉·加尔达

Enantioselective process for the preparation of zolmitriptan

An enantioselective process for preparing zolmitriptan, (S)-4-{[3-[2-(dimethylamine)ethyl]-1H-indol-5-yl]methyl}-2-oxazolidinone), by asymmetric hydrogenation of (Z)-2-(acetylamino)-3-{[3-N,N-(dimethylamine)ethyl)-1H-indol-5-yl]-2-propenoic acid methyl ester in the presence of hydrogen and an enantioselective chiral phosphine transition metal catalyst.
Owner:CHIRAL QUEST

Preparation and use of exo-2-fluoroalkyl(bicyclo[2.2.1] hept-5-enes)

There is disclosed a composition comprising a mixture of endo- and exo-2-(bicyclo[2.2.1]hept-5-en-2-yl)-2,2-fluoroalkyl-ethan-2-ol which is rich in the exo isomer, preferably the endo / exo concentration ratio is no greater than 5 / 95. The composition is useful for forming a repeat unit of a polymer which polymer may further comprise additional repeat units derived from tert-butyl acrylate, hydroxyadamantyl acrylate, protected or unprotected fluorinated olefins, 2-methyl-2-adamantyl acrylate, 2-propenoic acid, 2-hydroxy-1,1,2-trimethylpropyl ester. Polymers of this invention are useful as the binder component of a photoresist composition for microlithography.
Owner:EI DU PONT DE NEMOURS & CO
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