The invention discloses a preparation method of self-support
nitrogen-doped
porous graphene for a super-
capacitor, which is characterized by comprising the following steps: 1) dispersing nano
nickel powder into a
buffer solution of
dopamine /
Tris-HCl, carrying out
ultrasonic oscillation, and then carrying out mechanical stirring at
room temperature for reacting and heating; after paste is formed, pressing the paste into a sheet by using a roller press of which the roller
diameter is 50cm, so as to obtain a sheet-shaped
nitrogen-doped
porous graphene precursor; 2) by taking polydopamine in the sheet-shaped
nitrogen-doped
porous graphene precursor prepared in the step 1) as a
solid precursor and taking
nickel as a catalyst and a template, carrying out high temperature
sintering in an
inert gas
sintering furnace, and finally, cooling the
sintering product to
room temperature in the
inert gas, so as to obtain a
nickel powder coated sheet of a nitrogen-
doped graphene product; and 3) putting the nickel
powder coated sheet of the nitrogen-
doped graphene product, prepared in the step 2), into strong acid for
etching off the nano nickel powder template by the acid, and then, cleaning and
drying the sheet in ultra-pure water repeatedly, so as to obtain self-support nitrogen-doped porous
graphene. The used raw materials are non-toxic and cheap and are easy to obtain, the process is simple, the cost is low, and nitrogen-
doped graphene with a high specific surface area and high quality can be prepared.