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183results about How to "Promote charcoal" patented technology

Environmental protection based red mud combination modification synergism fire-retardant polyethylene

The invention relates to an environmental protection based red mud combination modification synergism fire-retardant polyethylene, and belongs to the technical field of compressive utilization and fire-retardant plastics. The fire-retardant polyethylene is suitable for fire safety protection in important public places in the fields of electric products, building materials and transportation. The fire-retardant polyethylene consists of the following components in percentage by weight: 30 to 35 percent of polyethylene, 34 to 39 percent of red mud, 6 to 13 percent of red phosphorus, 5 to 17 percent of zinc borate, 3 to 8 percent of ethylene-vinyl acetate copolymer, 2 to 7 percent of grafted polyethylene, and 2 to 8 percent of silicone oil. The preparation process comprises the following steps of: grinding and drying the red mud; blending the ground red mud with other raw materials according to the blending ratio; mixing the mixture with polyethylene resin by fully stirring at a high speed; fusing, co-mixing and processing the mixture; and preparing a sample. The processing conditions comprise that: the roll temperature of a double-roller mixing mill is between 140 and 150 DEG C; and the forming temperature of the flat vulcanizing machine sample is between 120 and 130 DEG C, the heating time is between 4 and 8 minutes, and the pressure is between 10 and 20MPa. The fire-retardant system meets the requirements of industrial application on mechanical property, and simultaneously has comprehensive properties such as good fire-retardant effect, low cost, environmental protection and the like; moreover, the application field of the red mud is widened, and the red mud product with high added value is prepared.
Owner:BEIJING INSTITUTE OF TECHNOLOGYGY

Flame-retardant composite material with DOPO (9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide) modified nano mesoporous molecular sieve

The invention discloses a flame-retardant composite material with DOPO (9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide) modified nano mesoporous molecular sieve, belongs to the fields of nano mesoporous molecular sieve flame-retardant synergists and halogen-free flame-retardant composite materials, and particularly relates to the preparation method of the DOPO modified nano mesoporous molecular sieve and the flame-retardant composite material with the DOPO modified nano mesoporous molecular sieve. The DOPO is of a hexahydric phosphorus-heterocyclic-ring structure, and is a novel flame retardant intermediate. The nano mesoporous molecular sieve is the flame-retardant synergist. The invention discloses the method for preparing the DOPO modified nano mesoporous molecular sieve and the flame-retardant composite material with the DOPO modified nano mesoporous molecular sieve. Since the compound flame-retardant synergist plays a role in phosphorus / silicon synergistic flame retardance, the obtained product has good expandable carbon forming property, the flame-retardant efficiency of the material is obviously increased, the remaining amount of the residual carbon and the compact degree of a carbon layer are increased, and further the flame redardancy of the composite material is improved to a greater degree.
Owner:SHENYANG INSTITUTE OF CHEMICAL TECHNOLOGY

Thermoplastic low-fume halogen-free high-flame retardance polyolefin insulation material and preparation method thereof

InactiveCN103059403AImprove heat resistanceImproved processability and elongation at breakPlastic/resin/waxes insulatorsInsulated cablesChemistrySmoke
The invention provides a thermoplastic low-fume halogen-free high-flame retardance polyolefin insulation material and a preparation method thereof. The thermoplastic low-fume halogen-free high-flame retardance polyolefin insulation material comprises the following principal components in parts by weight: 30-40 parts of ethylene-vinyl acetate copolymer resin, 30-40 parts of polyolefine elastomer resin, 20-30 parts of polyethylene resin, 10-20 parts of compatilizers, 200-250 parts of hydrate fire retardants, 5-10 parts of charring agents, 1-2 parts of flame-retardant synergists, 0.5 parts of antioxidants A, 0.5 parts of antioxidant B and 5-10 parts of lubricants. The preparation method comprises the following steps of: preparing the materials contained in a raw material formula in parts by weight respectively, and then feeding the materials into a milling machine for uniform mixing; then feeding the mixture into an extruder to extrude cut granules; then screening through a vibrating screen; and finally cooling and packaging to obtain a finished product. The thermoplastic low-fume halogen-free high-flame retardance polyolefin insulation material provided by the invention has the advantages of better heat-resistant property and processing property and flame-retardant grade enhancement. The preparation method of the thermoplastic low-fume halogen-free high-flame retardance polyolefin insulation material, which is provided by the invention, is reasonable in design and easy and convenient to operate.
Owner:天津市普立泰高分子科技有限公司

Halogen-free flame-retardant and cold-resistant PC material suitable for charging pile charging gun and preparation method thereof

The invention discloses a halogen-free flame-retardant and cold-resistant PC material suitable for a charging pile charging gun and a preparation method thereof. The material comprises the following components in percentage by weight: 92-94 percent of polycarbonate polydimethylsiloxane, 0.1-0.12 percent of a flame retardant, 4-6 parts of a toughening agent, 0.5-0.6 percent of an anti-dripping agent, 0.1-0.2 percent of a main antioxidant, 0.3-0.4 percent of an auxiliary antioxidant, 0.4-0.5 percent of a lubricating agent and 0.3-0.5 percent of a weather resistance agent. A polycarbonate polydimethylsiloxane block copolymer is excellent in low temperature resistance as a dimethylsiloxane segment is introduced; meanwhile, polydimethylsiloxane can promote PC carbon forming during combustion, has a good synergistic flame-retardant effect together with an additive type flame retardant agent and can effectively reduce the consumption of the additive type flame retardant agent. The halogen-free flame-retardant and cold-resistant PC material suitable for the charging pile charging gun is prepared by taking the polycarbonate polydimethylsiloxane as a main body and through the addition of the sulfonate flame retardant, the organic silicon type toughening agent, the anti-dripping agent, the antioxidant, the weather resistance agent, the lubricating agent and the melt blending of a double-screw extruder.
Owner:GUANGZHOU SUPER DRAGON ENG PLASTICS

Preparation method of microcapsule fire retardant

The invention relates to a preparation method of a microcapsule fire retardant, and belongs to the technical field of fire retardant. According to the preparation method, magnesium hydroxide, ammoniumpolyphosphate, and melamine phosphate are mixed for coating of zeolite molecular sieve, wherein melamine phosphate is capable of achieving flame resistance at a condensed phase and a gas phase, a large amount of latent heat is absorbed through sublimation, volatilization, and evaporation, inert gas is generated, and gas state substances such as MA steam, water vapor, N2, CO2, and NH4 are generated, the concentrations of oxygen and combustible gas at a combustion zone are reduced through dilution, and at the same time, coating of material surface is realized; charing is promoted, formation ofmolten drops from some polymers is promoted, so that a part heat energy is taken away, and combustion reaction is terminated; the zeolite molecular sieve is a crystal aluminosilicate formed by SiO4 and Al2O3 tetrahedrons through oxygen bridges; not only uniform pore structures, and large specific surface area, but also extremely high surface polarity is achieved. The zeolite molecular sieve possesses excellent absorption effect and certain catalyst effect, and flame resistance of the microcapsule fire retardant is improved.
Owner:黄旭东

Phosphorus-containing flame-retardant polyester ionomer/nanocomposite material and preparation method thereof

ActiveCN104045821AHigh crystallinityInfluence of Flame RetardancyFiberIn situ polymerization
The invention discloses a phosphorus-containing flame-retardant polyester ionomer / nanocomposite material and a preparation method thereof. The phosphorus-containing flame-retardant polyester ionomer / nanocomposite material is prepared by in-situ polymerization of terephthalic acid or dimethyl terephthalate, ethylene glycol, phosphorus-containing ion monomers (i) or phosphorus-containing ion monomers (ii), inorganic nanoparticles or / and organic modified inorganic nanoparticles. The numbers of phosphorus-containing ion group structure units in the composite material account for 2% to 5% of the numbers of structure units of the terephthalic acid or the dimethyl terephthalate in the composite material. The content of the inorganic nanoparticles or / and organic modified inorganic nanoparticles accounts for 0.5 to 10% of the total mass of the composite material. Meanwhile, the phosphorus-containing flame-retardant polyester ionomer / nanocomposite material is excellent in flame retardance, melt drip resistance and crystallization resistance. The intrinsic viscosity of the phosphorus-containing flame-retardant polyester ionomer / nanocomposite material can reach 0.6dL / g to 1.0dL / g. Thus, the phosphorus-containing flame-retardant polyester ionomer / nanocomposite material can be directly taken as a raw material used for preparing fibers, engineering plastics, thin films and the like.
Owner:SICHUAN UNIV

Benzene imide structure based high-temperature self-crosslinking copolyester with effects of flame retardancy, smoke suppression and melt drop resistance and preparation method of copolyester

ActiveCN108359084APreserve thermoplastic processabilityIncrease melt viscosityStructural unitStructure based
The invention discloses a benzene imide structure based high-temperature self-crosslinking copolyester with effects of flame retardancy, smoke suppression and melt drop resistance. Copolyester is prepared from structural units represented by I, II and III or structural units represented by I, II and IV through random copolymerization, wherein the characteristic viscosity [eta] of copolyester is 0.41-1.12 dL / g, and the limit oxygen index is 24.2%-38.7%; the vertical combustion class is in a range from V-2 to V-0; the p-HRR (peak of heat release rate) in a cone calorimetry test is reduced by 7.1%-72.1% as compared with that of pure PET, and total smoke release is decreased by 2.0%-59.2% as compared with that of pure PET. The invention further discloses a preparation method of copolyester. Ahigh-temperature self-crosslinking group introduced in the preparation process is a benzene imide group, and prepared copolyeste cannot be subjected to crosslinking during processing and polymerization, so that thermoplastic processability of polyester is retained; meanwhile, due to the tackifying effect and high charring property brought by the self-crosslinking action at high temperature or during combustion, prepared copolyester has excellent flame retardancy, smoke suppression and melt drop resistance effects.
Owner:SICHUAN UNIV

Irradiation cross-linked thermoplastic polyester elastomer cable material and cable production method

The invention discloses an irradiation cross-linked thermoplastic polyester elastomer cable material. The irradiation cross-linked thermoplastic polyester elastomer cable material comprises, by weight, 100 parts of thermoplastic polyester elastomer (TPEE), 15-40 parts of ethylene-vinyl acetate copolymer (EVA), 50-80 parts of a fire retardant, 0.3-2 parts of a lubricant, 0.3-3 parts of an antioxidant and 0.1-1 part of an ultraviolet light stabilizer. The invention also discloses a method for producing cables through using the cable material. Cable products produced by using the cable material have excellent room temperature and high temperature mechanical performances; irradiation crosslinking realizes good flame retardation performance on the premise of meeting environmental protection, and also realizes cost reduction; and the cable material can reach 125DEG C temperature resistance level, has excellent scratch and wear resistance, and can be widely used in the fields of automobile wires and high and low temperature resistant cables.
Owner:SHENZHEN WOER HEAT SHRINKABLE MATERIAL +4

Monomer containing benzimide phenylacetylene structure, high temperature self-crosslinked copolyester and preparation method thereof

ActiveCN104592094AHigh self-crosslinking flame retardant efficiencyGood flame retardantOrganic chemistryPolymer scienceChemical reaction
The invention discloses a monomer containing a benzimide phenylacetylene structure. The monomer can enable self-crosslinking chemical reaction of a synthesized polymer under high temperature. The monomer containing a benzimide phenylacetylene structure and the structural units represented by I and II for synthesis of polyester can undergo random copolymerization to obtain high temperature self-crosslinked copolyester, and when the copolyester contains a PET structural unit, the characteristic viscosity number [eta] is 0.44-1.38dL/g, the vertical combustion UL-94 grade is from V-2 to V-0, the oxygen index LOI is 24.0-35.0%, and the cone calorimeter test peak heat release rate PHRR and the smoke release total amount are both lower than pure polyester. The invention also discloses a preparation method of the copolyester. The benzimide and phenylacetylene in the copolyester involved in the invention can generate synergistic cross-linking effect, so that the copolyester has very high flame-retardant and anti-dripping efficiency, and also the copolyester is endowed with excellent flame retardant, anti-dripping and smoke suppressing performance. The method provided by the invention is basically consistent with the synthesis method of conventional polyester, not only is mature in technology, and easy and convenient to operate, but also is easy to control and convenient for industrial production.
Owner:SICHUAN UNIV

Hybrid modified aluminum hypophosphite and preparation method thereof

The invention relates to hybrid modified aluminum hypophosphite and a preparation method thereof. The hybrid modified aluminum hypophosphite is prepared by hybrid modification of aluminum hypophosphite with cyanuric acid, melamine, a two-dimensional layered material and an organic coating material; the organic coating material is a coupling agent and/or silicone resin. The finally prepared hybridmodified aluminum hypophosphite is mainly composed of aluminum hypophosphite and a coating layer on the surface; the coating layer is a multi-layer organic-inorganic hybrid structure. The temperatureof the hybrid modified aluminum hypophosphite is more than or equal to 300 DEG C when the thermal weight loss is 1 wt%, the temperature is more than or equal to 345 DEG C when the thermal weight lossis 5 wt%, and the carbon residue rate at the temperature of 750 DEG C is more than or equal to 50 wt%; the smoke density of a high molecular material during combustion after the hybrid modified aluminum hypophosphite is added is decreased by 20% or more. The preparation method has the advantages of simple process and low cost; the prepared product has the advantage of excellent flame retardant performance, good thermal stability, low water solubility, no agglomeration phenomenon during addition, and great application prospect.
Owner:DONGHUA UNIV +1

Rare-earth oxide and microencapsulated red phosphorus synergic flame retardance PA6 composite and preparation method thereof

ActiveCN106751778AImproved Density and ContinuityCondensed phase flame retardant effect is goodChemistryMass transfer
The invention provides a rare-earth oxide and microencapsulated red phosphorus synergic flame retardance PA6 composite and a preparation method thereof. The rare-earth oxide and microencapsulated red phosphorus synergic flame retardance PA6 composite is characterized by being prepared from PA6, microencapsulated red phosphorus and rare-earth oxide. Rare-earth oxide is introduced into a red phosphorus flame-resistant polymer material system, rare-earth oxide can catalyze dehydrated carbonization of red phosphorus, a more compact and continuous charcoal layer structure can be formed, the mass transfer process of volatile products generated by polymer degradation to a gas phase is blocked, feedback of heat generated by gas phase combustion to a condensed phase is also blocked, and flames are prevented from propagating and spreading.
Owner:NINGBO INST OF TECH ZHEJIANG UNIV ZHEJIANG

Fireproof type gypsum-based spraying material and preparation method thereof

The invention relates to the technical field of building materials and in particular relates to a fireproof type gypsum-based spraying material and a preparation method thereof. The fireproof type gypsum-based spraying material is prepared by grinding modified cellulose ether, a thixotropic lubricant, pearlite, a composite retarder, a flame retardant and a chlorine ion controlling agent until thegranularity is 0.6 to 1.0mm, and mixing powder with gypsum, sand and portland cement, so that the fireproof type gypsum-based spraying material provided by the invention has characteristics of convenience for working, water prevention and heat insulation, high temperature resistance, no hollowing, no cracking, strong binding power, good anti-sagging performance, bug and ant biting resistance, metal rusting prevention, greenness and environment protection and the like; furthermore, the flame retardant has the effect of keeping the average breaking strength of the gypsum-based spraying materialbeing 2.2MPa or more and the average compressive strength being 4.6MPa or more through a reasonable design and a dosage test of magnesium hydroxide, zinc borate and chitosan tetramethylene phosphine sulfate; the fireproof type gypsum-based spraying material keeps relatively good mechanical strength and also has the fireproof effect with the average fireproof degree of 560 DEG C or more.
Owner:深圳摩盾环保新材料有限公司

Preparation method of flame-retardant modified polyvinyl acetate used for expanded polystyrene beads

The invention discloses a preparation method of flame-retardant modified polyvinyl acetate used for expanded polystyrene beads. In an existing method, 6-(4-formylphenoxy) cyclotriphosphazene and DOPO are prepared into a compound comprising phosphazene and DOPO double-effect functional groups through a solution and a fusion method, wherein the nitrogen content of the compound is 1.9%, the nitrogen content is small, and flame retardance is low. According to the preparation method, 1-thiourea ethyl acrylate-6-aminophenoxy cyclotriphosphazene reacts with vinyl acetate and chloroform under the action of a catalyst and polar solvent to prepare 1-thiourea ethyl acrylate-6-aminophenoxy cyclotriphosphazene vinyl acetate comprising phosphazene and DOPO double-effect functional groups. The features that the product contains phosphate and nitrogen and is free of halogens, and compared with an existing double-effect functional group compound of the type, the nitrogen content is greatly increased and are utilized for sufficiently exerting the synergistic action of phosphate and nitrogen; the flame-retardant modified polyvinyl acetate is applied to preparing emulsion wrapping the polystyrene beads, and achieves the expected effects of higher flame-retardant efficiency and smaller toxin.
Owner:HANGZHOU FANGYUAN PLASTICS MASCH CO LTD

Environmental-friendly & flame-retardant polycarbonate composite material

The invention discloses an environmental-friendly & flame-retardant polycarbonate composite material, which comprises the following raw materials: polycarbonate, polyvinyl butyral, polypropylene, polyvinylidene fluoride, octafluoro-diphenyl diglycidylether, an ethylene / vinyl acetate copolymer, nano titanium dioxide, nano aluminium hydroxide, carbon nanofibers, montmorillonite, nano zinc oxide, a silane coupling agent KH-560, tri(2,4-diiso-butyl benzene) phosphate, hexaphenoxy cyclotriphosphazene, potassium perfluorobutanesulfonate, nano zinc stannate, ferrocene, molybdenum disulfide, a plasticizer and an antioxidant. The environmental-friendly & flame-retardant polycarbonate composite material provided by the invention is excellent in flame resistance, and can meet the requirements of many fields of television and computer and the like; and the material is good in comprehensive performance and long in service life.
Owner:ANHUI GUANGYUAN TECH DEV
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