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A kind of preparation method of hydrotalcite hollow microsphere

The invention discloses a preparation method of a nano vacant-shell spherical hydrotalcite and belongs to the field of inorganic nano materials. The preparation method comprises steps of: first, preparing a silica microballoon and an alumina monohydrate sol; dipping the prepared silica microballoons in the alumina monohydrate sol for several times to obtain an alumina monohydrate wrapped silica composite microballoon with a core-shell structure; putting the obtained composite microballoon in a solution containing divalent metal salt, and crystallizing at a certain temperature to obtain the vacant-shell spherical hydrotalcite. The invention first realizes the preparation of a three-dimensional vacant-shell hydrotalcite and expands preparation method of the hydrotalcite materials. The prepared vacant-shell hydrotalcite has a controllable nano size, and an increased specific surface area due to the three-dimensional vacant-shell structure and the cavity.
Owner:BEIJING UNIV OF CHEM TECH

Hollow-structure carbon-coated tin dioxide nanofiber material as well as preparation method and application of hollow-structure carbon-coated tin dioxide nanofiber material

The invention discloses a hollow-structure carbon-coated tin dioxide nanofiber material, a preparation method and application of the hollow-structure carbon-coated tin dioxide nanofiber material in a super capacitor. The preparation method of the hollow-structure carbon-coated tin dioxide nanofiber material comprises the following steps: by taking polyacrylonitrile as an outer flow, dissolving tin metal salt or alkali in polymethyl methacrylate as an inner flow, carrying out pre-oxidization and carbonization by using a coaxial electrostatic spinning method to obtain the hollow-structure carbon-coated tin dioxide nanofiber; the outer diameter is 800-1000nm, the inner diameter is 500-700nm, a shell layer is a fiber layer with tin dioxide particles which have particle diameters being 3-15nm and are uniformly coated with carbon. The fiber material is prepared into a working electrode of the super capacitor, has high specific capacity and excellent cyclic stability, and is the electrode material of the super capacitor with excellent performance.
Owner:DALIAN JIAOTONG UNIVERSITY

Application of an electrocatalyst in the anode of proton exchange membrane fuel cell

The application of an electro-catalyst in an anode of a proton exchange membrane fuel cell is the application of the electro-catalyst in the anode of the proton exchange membrane fuel cell. The catalyst has the following characteristics: taking PdxPty alloy and the added one or more types of IIIB, IVB, VB, VIB, VIIB, VIII and IB group as active ingredient, wherein the content of the active ingredients accounts for 5%-70% of the weight of the catalyst, the rest is conductive carrier, the content of the Pd metal accounts for 50%-95% of the total weight of the metal. In the preparation method, a liquid phase reduction method is adopted, the main active ingredient Pd metal precursor is dissolved in a mixture solution of water and alcohol, ammonia water to be used as a complexing agent is added, and then other active ingredient precursors and conductive carriers are added; and the active ingredients can be reduced by a strong reducing agent and then the electro-catalyst is loaded on the conductive conductor.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Nitrogen-sulfur double-doped non-metallic carbon-based oxygen reduction catalyst with grading holes and preparation

ActiveCN109786764ACatalytic performance for efficient oxygen reduction reactionImprove stabilityCell electrodesSynthesis methodsCarbonization
The invention discloses a nitrogen-sulfur double-doped non-metallic carbon-based oxygen reduction catalyst with grading holes and preparation and belongs to the technical field of catalysts. An organic polymer with nitrogen, sulfur and carbon in uniform distribution is synthesized through a simple method, the organic polymer is further subject to high-temperature calcination, a carbonization process, a nitrogenization process and a sulfurization process are completed simultaneously, and then the nitrogen-sulfur double-doped grading hole carbon material is prepared. The material has a grading hole structure under the condition of not using a template, the specific surface area is large, the synthesis method is simple, the raw materials are easy to obtain, cost is low, and the material has efficient oxygen reduction reaction catalytic activity and good stability and has broad application prospects in the fields of metal-air cells, regenerative fuel cells, etc.
Owner:BEIJING UNIV OF CHEM TECH

Method for preparing SO42-/TiO2 through supercriticalo exsiccation

A process for preparing the catalyst SO4 / TiO2 by supercritical drying method includes slowly dropping the sulfuric acid-alcohol-water solution in butyl titanate-alcohol solution to obtain TiO2 sol, ageing to obtain wet gel, mixing it with alcohol, staying in inertial atmosphere and supercritical condition for 0.5-8 hr, cooling and calcining. Its adantages are high specific surface area and photocatalytic activity, and long service life.
Owner:SHANGHAI NORMAL UNIVERSITY

Preparation method of hydrotreating catalyst

The invention discloses a preparation method of a hydrotreating catalyst. The preparation method comprises the following steps: (1) pulping dry alumina glue, adding organic salt, uniformly mixing the pulped dry alumina glue and the organic salt, performing solid-liquid separation and drying on the mixture so as to obtain modified dry alumina glue powder; (2) pulping the modified dry alumina glue powder, adding the pulped modified dry alumina glue powder in a heteropoly phospho-molybdic acid (H2PMo12O40) solution, performing a reaction on the organic salt in the solution and heteropoly phospho-molybdic acid, and after reaction, performing solid-liquid separation, drying, extrusion molding and calcination on the mixture so as to obtain a catalyst precursor; (3) dipping the catalyst precursor in activated metal promoter, and drying and calcining the catalyst precursor so as to obtain a catalyst product. For the catalyst prepared by adopting the method disclosed by the invention, the active components are uniformly distributed in the catalyst, so that the catalyst is easy to vulcanize; the activated metal has high dispersity on the surface of the catalyst, so that the activity of the catalyst is improved, the use ratio of the activated metal is increased, and the service life of the catalyst is prolonged.
Owner:CHINA PETROLEUM & CHEM CORP +1

Hydrotreating catalyst intermediate, hydrotreating catalyst, and preparation methods of hydrotreating catalyst intermediate and hydrotreating catalyst

The present invention discloses a hydrotreating catalyst intermediate, a hydrotreating catalyst, and preparation methods of the hydrotreating catalyst intermediate and the hydrotreating catalyst. According to the present invention, the hydrotreating catalyst intermediate comprises a hydrogenation activity metal component, a carrier component and a specific organic compound, and can complete the vulcanization process without a hydrogen sulfide generation reaction and a vulcanization reaction between hydrogen sulfide and an active metal, such that the problem that the temperature increase is too rapid during the catalyst vulcanization process can be avoided; the hydrotreating catalyst is the vulcanization type hydrotreating catalyst having complete significance, and after the hydrotreating catalyst is loaded into the hydrogenation reaction device, the hydrogenation reaction temperature can be directly achieved so as to substantially shorten the startup time; and the catalyst has advantages of complete vulcanization, good metal dispersibility, and good hydrogenation property.
Owner:CHINA PETROLEUM & CHEM CORP +1

Molybdenum platinum porous composite material as well as preparation method and application thereof

The invention provides a molybdenum platinum porous composite material as well as a preparation method and application thereof. The preparation method comprises the following steps that a carbon nanotube is added into a solvent; turbid liquid is formed through ultrasound, and is then dripped on the surface of a pretreated glassy carbon electrode; a carbon nanotube thin layer is formed; a glassy carbon electrode is obtained; the glassy carbon electrode modified by the carbon nanotube is put into electroplating liquid to implement the electroplating; cleaning and natural drying are performed; then, the glassy carbon electrode containing a molybdenum sulfide carbon nanotube composite material is put into a sulfuric acid solution; pt is used as a counter electrode; a saturated calomel electrode is used as a reference electrode; under the certain condition, the glassy carbon electrode coated with a molybdenum platinum / carbon nanotube composite material is obtained; the glassy carbon electrode is cleaned by water and is naturally dried at normal temperature; the composite material is scrapped from the surface of the glassy carbon electrode to obtain a final product. The operation of themethod is simple; the prepared composite material has great advantages in the aspects of electrocatalysis hydrogen production, electrocatalysis oxygen evolution, electrocatalysis oxygen reduction andenergy conversion; the composite material can be applied to the fields of fuel battery and new energy source conversion.
Owner:WENZHOU UNIVERSITY

Method of preparing nano catalyst for proton exchange film fuel cell

The method for preparing Nano electrocatalyst includes steps: using chloro platinic acid, sodium chloroplatinate, water solution of potassium chloroplatinate, or chloro platinic acid, sodium chloroplatinate, water solution of potassium chloroplatinate and ruthenium chloride as raw materials; adding active carbon into the said material to adsorb noble metals; adding ethanol, propanol or isopropyl alcohol to carry out decentralization effect; pH value of mixed liquor is adjusted through alkaline solution so as to obtain liquor of raw materials. Deoxidation liquor is prepared by using deionized water to blend reducing agent: sodium borohydride and potassium borohydride. Under carrying current of nitrogen gas or argon gas, liquor of raw materials through spraying pen is jetted to the deoxidation liquor to deoxidize noble metal ion, which then passes through filtering, washing and drying procedures.
Owner:CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI

Preparation method of electrocatalyst carrier for fuel cell

The present invention relates to a preparation method of an electrocatalyst carrier for fuel cells. The electrocatalyst carrier is prepared from raw materials of expanded graphite with BET surface area of no less than 100m<2> / g and average pore size of no less than 10 nm through high temperature calcination, hole plugging treatment and drying treatment; and the obtained carrier has BET specific surface area of no less than 120m<2> / g and average pore size of 8-16 nm. Compared with the traditional carbon materials, the electrocatalyst carrier has larger specific surface area, is easier to capture and uniformly disperse nano Pt particles, also has high better potential stability. The Pt / C electrocatalyst prepared by using the treated worm-shape expanded graphite as carrier preparation has the advantages of multiple active sites, high activity and stability.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Preparation method of porphyrin-based metal organic framework material sensitized oxide type catalyst

The invention relates to a preparation method of a porphyrin-based metal organic framework material sensitized oxide type catalyst. The porphyrin-based metal organic framework material sensitized oxide type catalyst is used for visible light catalytic degradation treatment of organic pollutants in water. A porphyrin-based metal organic framework material is used as a sensitizer, silver-cerium double-doped zinc oxide is used, and a sensitizing auxiliary agent is introduced, so that a photo-generated charge transmission channel is constructed, and the photocatalytic degradation performance undera visible light condition is enhanced. By investigating the degradation performance of the composite catalyst on a typical organic pollutant methylene blue in water under a visible light condition, the catalyst has good capacity of degrading organic matters in water under visible light.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Multi-duct transition metal phosphide carbon nanotube composite material and preparation method and application based on small molecule regulation

The invention provides a multi-duct transition metal phosphide carbon nanotube composite material and a preparation method and application based on small molecule regulation. A mixture of carbon nanotubes and small molecules is added into a solvent, ultrasound treatment is carried out to form turbid liquid to be dropwise added into a pretreated glassy carbon electrode surface, natural drying is carried out to form even carbon nanotube thin layers, and a glassy carbon electrode modified with the mixture of the carbon nanotubes and the small molecules is obtained; phosphate and transition metalsalt are added into deionized water, electrolyte is supported, sulfuric acid is used for adjusting pH to be 0-13, and electroplate liquid is obtained; and the glassy carbon electrode modified with themixture of the carbon nanotubes and the small molecules is placed into the electroplate liquid to be electroplated, washing with water is carried out, natural drying is carried out at the normal temperature, and a blade is used for scrapping a prepared composite material from the surface of the glassy carbon electrode, and the final product is obtained. The method is easy to operate, the preparedcomposite material has the great advantages in the aspects of catalytic hydrolysis separation and energy conversion, and the product and the preparation method can be applied to the field of electro-catalysis water decomposition hydrogen production and photovoltaic conversion.
Owner:WENZHOU UNIVERSITY

Catalyst for synthesizing cyclohexylamine by aniline hydrogenation and preparation method thereof

The invention relates to a modified hydrotalcite-like derived cobalt catalyst, general formula being M / M1(O)-M2(O)-M3(O), wherein M represents Co, M1 represents an alkaline earth metal, M2 representsa rare earth metal, M3 represents Al, n(Co+M1) / n (Al+M2)=2-4, the molar ratio of Co to M1 is 0.5-1.5, and the molar ratio of M2 to Al is 0.005-0.05. The preparation method comprises the following steps: dissolving various metal salts and urea in water to form an aqueous solution, crystallizing the aqueous solution to obtain a solid-liquid mixture, filtering the solid-liquid mixture, respectively washing with water and a modifier, dispersing the mixture in the modifier, carrying out ultrasonic treatment, and filtering and drying the product to obtain a modified hydrotalcite-like precursor; androasting and reducing the precursor to obtain the catalyst. The catalyst is used for synthesizing cyclohexylamine through aniline hydrogenation, the aniline conversion rate can reach 98% or above, andthe dicyclohexylamine selectivity is 3% or below.
Owner:WANHUA CHEM GRP CO LTD

Second main group element modified cobalt-aluminum catalyst as well as preparation method and application thereof

The invention belongs to the technical field of catalysts, and particularly relates to a second main group element modified cobalt-aluminum catalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) dissolving a cobalt salt, a second main group element salt and an aluminum salt, and uniformly mixing to obtain a turbid liquid; (2) crystallizing the turbid liquid to obtain second main group element modified cobalt-aluminum hydrotalcite; and (3) calcining the obtained second main group element modified cobalt-aluminum hydrotalcite to obtain the catalyst. The cobalt-aluminum hydrotalcite modified by the second main group element is used as the precursor, so that the defects of trichloromethane, carbon tetrachloride and the like generated when the cobalt-aluminum hydrotalcite derived composite oxide is used for catalytic combustion of dichloromethane can be effectively controlled, the catalytic activity and stability on catalytic combustion of dichloromethane are very high, the initiation temperature is low, and the catalytic efficiency is high. The full conversion temperature is low.
Owner:HUAZHONG UNIV OF SCI & TECH

Synergistically modified composite electrocatalyst and application thereof in ethanol oxidation

The invention belongs to the field of electrocatalytic materials, and discloses a synergistically modified composite electrocatalyst and an application thereof in ethanol oxidation. The composite electrocatalyst is composed of an active noble metal phase and a basic carbonate matrix phase, wherein the active noble metal phase is dispersed and distributed on the surface of the basic carbonate matrix phase with a nanowire structure in the form of fine nanoparticles. The synergistic modified composite electrocatalyst provided by the invention optimizes intrinsic activity, the number of active sites and electrical conductivity at the same time. Based on synthesis of the matrix phase with a nanowire structure, the noble metal oxide phase is deposited on the surface of a nanowire through hydrolysis, and finally, the active metal phase is selectively reduced by regulating and controlling the heat treatment condition, so that the active metal phase is combined with the basic carbonate matrix to construct synergistic catalytic active sites, and the obtained composite electrocatalyst has high intrinsic activity, rich active sites and good electrical conductivity. And the electrochemical oxidation reaction of ethanol can be efficiently and stably catalyzed under an alkaline condition.
Owner:SOUTH CHINA UNIV OF TECH

Nitrogen-doped mesoporous carbon prepared by using calcium cyanamide as well as preparation method and application of nitrogen-doped mesoporous carbon

The invention discloses nitrogen-doped mesoporous carbon prepared by using calcium cyanamide as well as a preparation method and application of the nitrogen-doped mesoporous carbon. The preparation method concretely comprises the following steps: mixing a carbon source with the calcium cyanamide, then mechanically grinding the mixture, adding water and kneading for lumping, placing at the room temperature for 8-14 hours under the condition of ventilating, and carrying out pre-carbonizing treatment for 8-12h at 80-100 DEG C; placing the obtained pre-carbonized sample in a tube furnace, heatingup to 400-1000 DEG C under a flowing inert atmosphere, then carrying out heat preservation for 1-5h for deep carbonization treatment, and naturally cooling to obtain the nitrogen-doped mesoporous carbon having partial calcium ions on the surface. The preparation process is simple and easy to repeat, a nitrogen source does not need to be additionally added in a preparation process, and the subsequent steps of pore broadening and removing templates are omitted, so that the method is suitable for large-scale production; the obtained nitrogen-doped mesoporous carbon is used as a solid base catalyst or a catalyst carrier, and shows an excellent catalytic activity in preparation of long chain alkanes by means of condensation and hydrogenation of aldehydes and ketones.
Owner:ZHEJIANG UNIV OF TECH

Anticorrosive paint applied to ships and preparation method of anticorrosive paint

The invention belongs to the technical field of anticorrosive paint, and particularly relates to anticorrosive paint applied to ships and a preparation method of the anticorrosive paint. The anticorrosive paint applied to the ships is prepared from the following raw materials in parts by weight: 40-60 parts of epoxy resin, 5-15 parts of a modified basalt flake / carbon nitride composite material, 3-8 parts of a samarium and copper co-doped zinc oxide / graphene composite material, 10-18 parts of filler, 1.5-6 parts of an auxiliary agent and 20-30 parts of water. The anticorrosive paint applied to the ship can solve the practical problem that the ship needs bacteriostasis and corrosion prevention, has excellent adhesive force and good wear resistance, can bear high and low temperature and high salinity, can well resist bacterial corrosion, and achieves bacteriostasis and corrosion prevention effects.
Owner:QINGDAO ADVANCED MARINE MATERIAL TECH

Preparation method of graphite spherical shell sheet

PendingCN111943185AUnique crackUnique curved shapeCarbon compoundsPtru catalystCarbonization
The invention discloses a preparation method of a graphite spherical shell sheet, and belongs to the technical field of materials. According to the method, polystyrene spheres are used as a template,glucose is used as a carbon precursor, iron (or cobalt, nickel) is used as a graphitization catalyst, the template is removed through microwave heating, a glucose layer is partially carbonized, oxidized and broken, and then high-temperature carbonization and graphitization are performed to obtain the graphite sphere shell sheet. Compared with a hollow material, the prepared graphite ball shell sheet of the invention can fully expose the internal and external specific surface areas of the hollow graphite ball so as to improve the active site concentration and the material transmission performance, and the thickness of the graphite ball shell sheet can be controlled to be about 10 layers so as to achieve the category of graphene.
Owner:JIANGSU HUAXIA PAINT MAKING

Nitrogen-sulfur double-doped porous carbon material catalyst and preparation method thereof

The invention discloses a nitrogen-sulfur double-doped porous carbon material catalyst and a preparation method thereof, and relates to the technical field of carbon catalytic preparation. According to the nitrogen and sulfur double-doped porous carbon material catalyst and the preparation method thereof, the porous carbon material comprises a nitrogen and sulfur source and a carbon source with the mass ratio of 1%-50%, the carbon source is glucose, the nitrogen and sulfur source is cysteine, and a non-metal nitrogen and sulfur double-doped porous carbon material is prepared through a hydrothermal method and a high-temperature alkali activation method. The co-doping of nitrogen and sulfur not only ensures the catalytic stability of the catalyst, but also promotes the adsorption and catalytic degradation of antibiotic organic pollutants through the synergistic effect of nitrogen and sulfur, and the catalytic performance is better than that of a single element doped carbon material. The raw materials for preparing the catalyst are green, pollution-free and easy to purchase, the cost is low, the preparation process is simple, large-scale production is easy, and the catalyst can be applied to the fields of environmental organic polluted water treatment, drinking water deep purification treatment and the like.
Owner:WENZHOU UNIVERSITY

Preparation method of heavy oil hydrodemetallization catalyst

The invention discloses a preparation method of a heavy oil hydrodemetallization catalyst, and the method comprises the following steps: (1) pulverizing a waste hydrotreating catalyst, and roasting; (2) soaking the material obtained in the step (1) into an ammonium bicarbonate aqueous solution, carrying out sealed heat treatment, drying, soaking with a polyethylene glycol solution, and drying to obtain a pretreated material A; (3) performing high-temperature activation treatment on kaolin, then soaking into an ammonium bicarbonate aqueous solution, performing sealed heat treatment, and dryingthe material subjected to heat treatment to obtain a pretreated material B; and (4) kneading and molding pseudo-boehmite, the pretreated material A and the pretreated material B, drying and roasting the molded product to obtain a carrier, and loading a hydrogenation active component onto the carrier to obtain the catalyst. According to the method, the hydrodemetallization catalyst is prepared fromthe waste catalyst and kaolin, environmental pollution is reduced while the production cost is reduced, the content of macropores of the hydrodemetallization catalyst is appropriate, and the hydrodemetallization catalyst has high hydrodemetallization activity and hydrodesulfurization activity.
Owner:CHINA PETROLEUM & CHEM CORP +1

High-temperature flue gas desulfurizer and preparation method thereof

The invention discloses a high-temperature flue gas desulfurizer and a preparation method thereof. The preparation method comprises the steps: by taking divalent metal ion salt and water-soluble aluminum salt as raw materials, preparing a layered double-metal hydroxide precursor by adopting a coprecipitation method and a hydrothermal crystallization method in sequence; and embedding a salt solution of a catalytic active component into the layered double-metal hydroxide precursor through an exchange reaction, molding, and roasting to obtain the high-temperature flue gas desulfurizer. The desulfurizer prepared by the preparation method provided by the invention has the characteristics of large specific surface area, rich active sites and high dispersity, the sulfur capacity is up to 164 mg / g, the desulfurizer shows good desulfurization capacity, 100% regeneration can be realized after the desulfurizer is reduced by hydrogen for 10 minutes, and the desulfurizer has excellent regeneration capacity. Meanwhile, various oxides formed through high-temperature roasting are high in grain strength, the oxides with various crystal phase structures are uniformly distributed, the phenomena of grain sintering and structure collapse in a high-temperature environment can be effectively inhibited, and good high-temperature stability is achieved.
Owner:CHINA PETROLEUM & CHEM CORP +1

Preparation of supported platinum nano-cluster catalyst and application of supported platinum nano-cluster catalyst in alkane anaerobic dehydrogenation

The invention provides an application of a supported platinum nano-cluster catalyst in an alkane anaerobic dehydrogenation reaction. The catalyst takes an oxide as a carrier and platinum nano-clusters as an active component, the platinum nano-clusters are monodispersed on the oxide carrier, and the platinum nano-clusters are composed of ligands and platinum atoms; the ligand is at least one of organic phosphorus and mercaptan; the platinum atoms are diatoms or polyatoms. The preparation method of the catalyst comprises the following steps: (1) preparing a diatomic or polyatomic platinum nano-cluster; (2) loading the diatomic or polyatomic platinum nano-cluster on the carrier; and (3) post-treatment of the catalyst. The catalyst prepared by the method has high-dispersion nanoscale platinum nano-clusters, and has high selectivity to olefin in the anaerobic dehydrogenation reaction of alkane such as propane and the like.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Dual-channel Z-configuration photocatalytic decomposition water composite material and preparation method thereof

The invention relates to photocatalytic decomposition water materials and in particular relates to a dual-channel Z-configuration photocatalytic decomposition water composite material and a preparation method thereof. The preparation method disclosed by the invention comprises the following steps: with carbon nitride as a precursor material, adding sheet molybdenum disulfide to serve as a high-conductivity solid-state electron transport medium, enabling the two to perform effective assembly, and enabling nano-silver phosphate particles to uniformly grow on a composite matrix of carbon nitrideand sheet molybdenum disulfide by virtue of an ion exchange method, thereby obtaining a three-system composite material having the characteristics of being excellent visible light absorption, low in catalytic stability and high in photocatalytic efficiency. The defects that a composite catalyst prepared by a conventional method is weak in visible range response and slow in charge separation and migration and an ionic electron transport medium used in the traditional Z-configuration photocatalytic composite system easily causes side reactions and is low in material compounding uniformity are overcome.
Owner:JIANGSU UNIV

Preparation method of cobalt-based Fischer-Tropsch synthesis catalyst with controllable mono-dispersed particles

The invention belongs to the technical field of preparation methods of Fischer-Tropsch synthesis catalysts, and specifically discloses a preparation method of a cobalt-based Fischer-Tropsch synthesis catalyst with controllable mono-dispersed particles. The method is characterized in that an anhydrous ethanol, distilled water and carboxyl-containing organic matter mixed solvent combined according to a controlled ratio are used as a solvent to dissolve an active component with a meso-porous material with a special morphology as a carrier, the solvent is added to the meso-porous in a dropwise controlled manner, and the obtained material is dried and roasted to obtain the catalyst. The cobalt particles of the catalyst prepared in the invention have the characteristics of controllable size, mono-dispersion, and high dispersion because of the interaction of anhydrous ethanol, distilled water, the organic matter and a cobalt source, wherein the anhydrous ethanol, distilled water and the organic matter are indispensable. The catalyst prepared in the invention has the characteristics of high reaction activity, good stability, high selectivity of heavy hydrocarbons, low methane selectivity, difficult sintering and the like in the Fischer-Tropsch reaction, and the preparation method is obviously better than routine preparation methods.
Owner:SOUTH CENTRAL UNIVERSITY FOR NATIONALITIES

High-silicon Y zeolite and preparation method thereof

The invention relates to high-silicon Y zeolite and a preparation method thereof. The preparation method comprises the following steps of: adopting industrial high-silicon NaY zeolite as a growth carrier, adopting a silicon source, an aluminium source, a guiding agent and distilled water as reaction materials, without adding any template agent, carrying out hydrothermal crystallization reaction toprepare and obtain a zeolite material which uses 0.6-1.0mum single-crystal NaY zeolite particles as a core phase and uses polycrystal zeolite aggregate formed by 50-400nm nano Y zeolite particles asa shell layer. The high-silicon Y zeolite and the preparation method have the beneficial effects that the catalytic activity of the prepared high-silicon Y zeolite in macromolecular catalytic reactionis obviously improved, and in cracking of triisopropylbenzene, the conversion rate is increased by 20-55% compared with industrial high-silicon NaY zeolite.
Owner:TAIYUAN UNIV OF TECH

Regeneration and reactivation method of heavy distillate oil hydrotreatment catalyst

The invention relates to a regeneration and reactivation method of a heavy distillate oil hydrotreatment catalyst, which comprises the following steps: putting a regenerated catalyst into a solution containing an inorganic assistant and an organic chelating ligand assistant, and dipping under sound field conditions; airing an impregnated sample at room temperature; and carrying out two-step heat treatment to obtain the activated catalyst. According to the method, the effective specific surface area of the regenerated catalyst is increased, the dispersity of active components is improved, the catalyst treated and regenerated by the method is high in vulcanization degree, the number of active phases is increased, the reaction activity of the catalyst is improved, no ammonia nitrogen is discharged in the catalyst reactivation process, and the environment is not polluted.
Owner:湖北中超化工科技有限公司

Aromatic hydrocarbon methylation catalyst and a preparation method thereof

The invention relates to an aromatic hydrocarbon methylation catalyst and a preparation method thereof. A purpose of the present invention is mainly to solve the problems of poor stability, low reaction conversion rate, difficulty in preparation and the like of the aryl methylation catalyst in the prior art. According to the present invention, an ammonium type ZSM-5 nano-sheet catalyst is used, and comprises, by weight, a) 5-95 parts of an ammonium type ZSM-5 nano-sheet molecular sieve material, b) 95-5 parts of a binder, and c) the balance of a metal compound; and the catalyst can be used inthe industrial production of aromatic hydrocarbon methylation.
Owner:CHINA PETROLEUM & CHEM CORP +1

Method for regulating and controlling FeS2/reduced graphene oxide compact assembly structure

The invention relates to the field of composite material preparation, and provides a method for regulating and controlling a FeS2 / reduced graphene oxide compact assembly structure in order to solve the problem that introduction of a Faraday capacitor material into graphene limits rapid ion transmission and the like. The method comprises the following steps of: (1) synthesis of a Mil88 metal organic framework; (2) preparation of Mil88 / GO / S powder; and (3) preparation of compact FeS2 / reduced graphene oxide. The preparation method is efficient and stable in process, simple in flow and capable ofeffectively saving energy, preparation of a compact FeS2 / reduced graphene oxide electrode can be achieved, meanwhile, a channel for rapid transmission of sodium ions is also considered, and thereforethe volume desalination capacity of the material is greatly improved; and the prepared compact FeS2 / reduced graphene oxide composite material shows excellent electrochemical activity and stability ina capacitive deionization technology under conventional conditions.
Owner:ZHEJIANG UNIV OF TECH
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