The invention relates to a polyphenylene sulfide resin composition as well as a preparation method and an application thereof. The polyphenylene sulfide resin composition is prepared from the following components in percentage by weight: 20 to 65 percent of PPS resin, 3.0 to 20 percent of PA resin, 20 to 60 percent of glass fiber, 0.5 to 10 percent of a stress release agent, 0.3 to 3.0 percent ofan antioxidant, 0.3 to 2.0 percent of an anti-aging agent and 0.5 to 3.0 percent of a lubricating agent. Through the synergistic effect of the PA resin and the stress release agent, the synergistic effect of the PA resin and the anti-aging agent is achieved; according to the invention, the PPS engineering plastic is used as a raw material, the proportion of the components is optimized, the electroplatable material with excellent weather resistance is prepared, the electrical property, mechanical property, heat resistance, creep resistance, chemical resistance and aging resistance of the PPS engineering plastic are maintained, and the material is suitable for antenna oscillator base materials.