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Acrylic resin, resin boards, transparent electrode boards for touch panels, touch panels, and processes for production of them

A manufacturing method and transparent electrode technology, applied in acrylic resin, resin plate, transparent electrode plate for touch panel, touch panel and their manufacturing fields, can solve problems such as plate cracking and plate cracking, prevent damage, improve durability Thermal performance, achieve lightweight effect

Inactive Publication Date: 2005-12-21
MITSUBISHI RAYON CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method has a problem in that if the peeling process is not carried out at a high temperature in the manufacturing process, cracks will occur.
However, this transparent substrate has a problem that the plate is easily cracked in the step of peeling from the cell after polymerization and curing.

Method used

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  • Acrylic resin, resin boards, transparent electrode boards for touch panels, touch panels, and processes for production of them
  • Acrylic resin, resin boards, transparent electrode boards for touch panels, touch panels, and processes for production of them
  • Acrylic resin, resin boards, transparent electrode boards for touch panels, touch panels, and processes for production of them

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0140] In 10 parts of isostearyl methacrylate ("NK ester S-1800M" manufactured by Shin Nakamura Chemical Industry Co., Ltd.), 10 parts of methyl methacrylate and bis (oxymethyl) tricyclo [5, 2, 1 ,0 2,6 ] In 100 parts of a mixture of 80 parts of decane dimethacrylate, 0.05 parts of 2,2'-azobis(2,4-dimethyl-4-methoxyvaleronitrile) as a polymerization initiator were mixed, 0.05 part of tert-butyl peroxy pivalate, 0.05 part of tert-hexyl peroxy isopropyl carbonate and 0.03 part of terpinolene as a polymerization regulator, and the resulting mixture is put into a suction filter bottle, stirred, and vacuum removed gas to obtain a polymerization mixture.

[0141] The polymerization mixture was poured into a mold formed by inserting a gasket between a pair of tempered glass sheets at a distance of 1.7mm, and air bubbles were removed, and then placed in a heating furnace, and polymerized at 55°C for 1 hour, then at 50°C for 1 hour, and then heated at 135°C Polymerized for 3 hours. ...

Embodiment 2~24

[0143] [Examples 2-24, Comparative Examples 1-9]

[0144] Except having used the raw material composition shown in Tables 1-6, it carried out similarly to Example 1, and produced the acrylic resin board. The evaluation results are shown in Tables 1-6.

Embodiment 25

[0146] In Example 1, 0.05 part of n-dodecyl mercaptan was further added as a chain transfer agent to the polymerization mixture, and the rest was carried out in the same manner as in Example 1 to produce an acrylic resin plate. The evaluation results are shown in Table 7. Moreover, bis(oxymethyl)tricyclo[5,2,1,0 2,6 ] The residual monomer amount of decane dimethacrylate was 2.09%.

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PUM

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Abstract

Disclosed is a method for producing an acrylic resin plate obtained by polymerizing and curing a polymerization mixture comprising, per 100 parts by mass, an alkyl methacrylate having an alkyl group having 1 to 4 carbon atoms and a polyfunctional (meth)acrylic acid A mixture of esters, containing 0.001 to 1 part by mass of a polymerization initiator with a 10-hour half-life temperature greater than or equal to 80°C, and 0.015 to 0.2 parts by mass of a polymerizable mixture of cyclohexadiene or terpenoids; containing 3 to 30 parts by mass % of alkyl methacrylate units having an alkyl group having 8 to 20 carbon atoms, 2 to 35% by mass of monovinyl methacrylate units containing an alkyl group having 1 to 4 carbon atoms Acrylic resin comprising unsaturated monomer unit and 35 to 95% by mass of polyfunctional (meth)acrylate unit; resin plate composed of the resin and method for producing the same; and transparent electrode plate for touch panel using the same and touch panels.

Description

technical field [0001] The present invention relates to an acrylic resin excellent in heat resistance, appearance, and shape stability, a resin plate made of the acrylic resin, and a transparent electrode for a touch panel having a transparent substrate excellent in heat resistance, transparency, and conductive film adhesion Plates, touch panels with the transparent electrode plates and their manufacturing methods. Background technique [0002] <Acrylic resin board> [0003] Acrylic resin sheets are used in lenses, automotive parts, lighting components, various electronic displays, etc. due to their excellent optical properties. However, when the acrylic resin plate is heat-treated at high temperature, it has a disadvantage of insufficient heat resistance. [0004] As a technique for improving the heat resistance of an acrylic resin sheet, there is a method of introducing a crosslinked structure by adding a polyfunctional monomer during polymerization of methyl metha...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J5/00C08F2/38C08F4/00C08F220/10C08F220/20
Inventor 菅本秀征川合治畠山宏毅
Owner MITSUBISHI RAYON CO LTD
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